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Resonant diffraction of synchrotron radiation in rubidium dihydrophosphate crystals

  • Diffraction and Scattering of Ionizing Radiations
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Abstract

Purely resonant Bragg reflections 006, 5\( \bar 5 \)0, and 666 in a rubidium dihydrophosphate (RbH2PO4) crystal at the K edge of rubidium have been experimentally and theoretically investigated. These reflections remain forbidden when the resonant dipole-dipole (E1E1) contribution to the resonant atomic factor is taken into account; they may be due to the dipole-quadrupole (E1E2) transitions as well as to the anisotropy atomic factor, which is caused by thermal atomic displacements (thermally induced contribution) and/or local jumps of hydrogen atoms. A numerical simulation showed that, at room temperature (experimental conditions), the thermally induced contribution to the “forbidden” reflections is dominant.

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Authors and Affiliations

  1. Russian Research Centre “Kurchatov Institute”, pl. Akademika Kurchatova 1, Moscow, 123182, Russia

    E. Kh. Mukhamedzhanov, M. V. Kovalchuk & M. M. Borisov

  2. Moscow State University, Moscow, 119992, Russia

    E. N. Ovchinnikova & E. V. Troshkov

  3. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiĭ pr. 59, Moscow, 119333, Russia

    M. V. Kovalchuk, E. V. Troshkov & V. E. Dmitrienko

Authors
  1. E. Kh. Mukhamedzhanov
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  2. M. V. Kovalchuk
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  3. M. M. Borisov
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  4. E. N. Ovchinnikova
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  5. E. V. Troshkov
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  6. V. E. Dmitrienko
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Correspondence to V. E. Dmitrienko.

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Original Russian Text © E. Kh. Mukhamedzhanov, M.V. Kovalchuk, M.M. Borisov, E.N. Ovchinnikova, E.V. Troshkov, V.E. Dmitrienko, 2010, published in Kristallografiya, 2010, Vol. 55, No. 2, pp. 187–195.

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Mukhamedzhanov, E.K., Kovalchuk, M.V., Borisov, M.M. et al. Resonant diffraction of synchrotron radiation in rubidium dihydrophosphate crystals. Crystallogr. Rep. 55, 174–181 (2010). https://doi.org/10.1134/S1063774510020021

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  • DOI: https://doi.org/10.1134/S1063774510020021

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