Abstract
The process of broadband KrCl laser λrad = 222 nm interaction with nitrogen dioxide in the atmosphere is considered. During the laser pulse, photofragmentation of NO2 occurs, followed by resonant excitation of several electronic vibrational levels of NO A2Ʃ – X2П, ν'ν''(2,2) and NO С2П – X2П, ν'ν''(0,4). The fluorescence intensity of NO A2Σ increases with increasing nitrogen pressure due to intermolecular nonradiative energy transfer from the metastable level of N2 A3Σ to the electronic level of NO A2Σ.
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Funding
Research on the laser source development was carried out with the financial support of the Ministry of Science and Higher Education of the Russian Federation for the purpose of the state assignment no. FWRM-2021-0014. The spectral analysis of the laser interaction with substance was supported by the development program of Tomsk State University (Priority-2030).
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Puchikin, A.V., Panchenko, Y.N., Konovalov, I.N. et al. Interaction of Nitrogen Dioxide by 222 nm Laser. Bull. Russ. Acad. Sci. Phys. 87 (Suppl 1), S77–S81 (2023). https://doi.org/10.1134/S1062873823704439
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DOI: https://doi.org/10.1134/S1062873823704439