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Graphene Quantum Dots Incorporated into β-cyclodextrin: a Novel Polymeric Nanocomposite for Non-Enzymatic Sensing of L-Tyrosine at Physiological pH

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Abstract

Graphene quantum dot-β-cyclodextrin modified glassy carbon electrode was used as a new nanosensor for determination of L-tyrosine (L-Tyr). It was found that graphene quantum dot-β-cyclodextrin has been stably electrodeposited on glassy carbon electrode modified by simple technique. The cyclic voltammograms of the modified electrode in an aqueous solution displayed a pair of well-defined, stable and irreversible reductive/oxidation redox systems. The apparent electron transfer rate constant (ks) and transfer coefficient (α) determined by cyclic voltammetry were approximately equal to 8.0 s–1 and 0.7, respectively. The modified electrode showed excellent catalytic activity towards the oxidation of L-Tyr at positive potential in buffer solution. The nanosensor also displayed fast response time, high sensitivity, low detection limit and a remarkably positive potential oxidation of L-Tyr that decreased the effect of interferences in analysis.

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Author information

Authors and Affiliations

  1. Department of Nanochemistry, Nano Technology Research Center, Urmia University, Urmia, 57154, Iran

    Nasrin Shadjou

  2. Department of Nano Technology, Faculty of Science, Urmia University, Urmia, 57154, Iran

    Nasrin Shadjou

  3. Drug Applied Research Center, Tabriz University of Medical Sciences, Tabriz, 51664, Iran

    Mohammad Hasanzadeh

  4. Pharmaceutical Analysis Research Center and Faculty of Pharmacy, Tabriz University of Medical Sciences, Tabriz, 51664, Iran

    Faeze Talebi

Authors
  1. Nasrin Shadjou
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  2. Mohammad Hasanzadeh
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  3. Faeze Talebi
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Correspondence to Mohammad Hasanzadeh.

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Shadjou, N., Hasanzadeh, M. & Talebi, F. Graphene Quantum Dots Incorporated into β-cyclodextrin: a Novel Polymeric Nanocomposite for Non-Enzymatic Sensing of L-Tyrosine at Physiological pH. J Anal Chem 73, 602–612 (2018). https://doi.org/10.1134/S1061934818060096

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  • DOI: https://doi.org/10.1134/S1061934818060096

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