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A study of the properties and composition of stearic acid monolayers on an aqueous subphase containing cadmium ions

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Abstract

Compression isotherms and chemical compositions of stearic acid (HSt) monolayers applied onto an aqueous subphase containing cadmium ions have been studied in a wide pH range. The data obtained have been used to calculate the dependences of surface elasticity E 2.5, change ΔA 2.5 in the surface area per molecule at a constant two-dimensional pressure in the monolayer of 2.5 mN/m, and change Δ|ζ| in the absolute value of the ζ potential of particles formed from the material of a monolayer collapsed on the surfaces of aqueous solutions with the same compositions on the pH of the subphase. The obtained data are in good agreement with each other and unambiguously attest to the dependences of the surface (E 2.5, ΔA 2.5) and electrosurface (Δ|ζ|) characteristics of the monolayers on their chemical composition. This leads us to make the reasonable suggestion that two alternative reactions may occur between cadmium ions and the HSt monolayer with the formation of two salts, CdSt2 and Cd(OH)St.

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References

  1. Science and Engineering of Oneand Zero-Dimensional Semiconductors, NATO ASI Ser., 1990, vol. 214.

  2. Ivanov, N.S., Kondrat’ev, Yu.V., Yanklovich, A.I., Sukhodolov, N.G., and Zhukov, A.N., Colloid J., 2015, vol. 77, p. 154.

    Article  CAS  Google Scholar 

  3. Ivanov, N.S., Khripun, V.D., Trofimov, M.A., Sukhodolov, N.G., and Pendin, A.A., Rev. Adv. Mater. Sci., 2014, vol. 39, p. 34.

    Google Scholar 

  4. Bagaev, E.A, Zhuravlev, K.S., Sveshnikova, L.L., and Shcheglov, D.V., Semiconductors, 2008, vol. 42, p. 702.

    Article  CAS  Google Scholar 

  5. Bagaev, E.A., Zhuravlev, K.S., and Sveshnikova, L.L., Semiconductors, 2006, vol. 40, p. 1188.

    Article  CAS  Google Scholar 

  6. Urquhart, R.S., Hoffmann, C.L., Furlong, D.N., Geddes, N.J., Rabolt, J.F., and Grieser, F., J. Phys. Chem., 1995, vol. 99, p. 15987.

    Article  CAS  Google Scholar 

  7. Bobrisheva, N.P., Ivanov, N.S., Selutin, A.A., Yanklovich, A.I., and Sukhodolov, N.G., Rev. Adv. Mater. Sci., 2014, vol. 37, p. 48.

    Google Scholar 

  8. Ji, X., Wang, C., Xu, J., Zheng, J., GattásAsfura, K.M., and Leblanc, R.M., Langmuir, 2005, vol. 21, p. 5377.

    Article  CAS  Google Scholar 

  9. Wang, M., Janout, V., and Regen, S.L., Acc. Chem. Res., 2013, vol. 46, p. 2743.

    Article  CAS  Google Scholar 

  10. Casford, M.T.L., Ge, A., Kett, P.J.N., Ye, S., and Davies, P.B., J. Phys. Chem. B, 2014, vol. 118, p. 3335.

    Article  CAS  Google Scholar 

  11. Ren, Y., Hossain, Md.M., Iimura, K., and Kato, T., J. Phys. Chem. B, 2001, vol. 105, p. 7723.

    Article  CAS  Google Scholar 

  12. Hasegawa, T., Kamata, T., Umemura, J., and Takenaka, T., Chem. Lett., 1990, vol. 19, p. 1543.

    Article  Google Scholar 

  13. Umemura, J., Takeda, S., Hasegawa, T., Kamata, T., and Takenaka, T., Spectrochim. Acta, Part A, 1994, vol. 50, p. 1563.

    Article  Google Scholar 

  14. Itoh, Y. and Hasegawa, T., J. Phys. Chem. A, 2012, vol. 116, p. 5560.

    Article  CAS  Google Scholar 

  15. Chi, L.F., Eng, L.M., Graf, K., and Fuchs, H., Langmuir, 1992, vol. 8, p. 2255.

    Article  CAS  Google Scholar 

  16. Viswanathan, R., Schwartz, D.K., Garnaes, J., and Zasadzinski, J.A.N., Langmuir, 1992, vol. 8, p. 1603.

    Article  CAS  Google Scholar 

  17. Peng, J.B., Ketterson, J.B., and Dutta, P., Langmuir, 1988, vol. 4, p. 1198.

    Article  CAS  Google Scholar 

  18. Petrov, I., Kulev, I., and Platikanov, D., God. Sof. Univ. Khim. Fak., 1983, vol. 73, p. 129.

    CAS  Google Scholar 

  19. Petrov, J.G., Kuleff, I., and Platikanov, D., J. Colloid Interface Sci., 1982, vol. 88, p. 29.

    Article  CAS  Google Scholar 

  20. Kobayashi, K. and Takaoka, K., Bull. Chem. Soc. Jpn., 1986, vol. 59, p. 933.

    Article  CAS  Google Scholar 

  21. Kurnaz, M.L. and Schwartz, D.K., J. Phys. Chem., 1996, vol. 100, p. 11113.

    Article  CAS  Google Scholar 

  22. Sukhodolov, N.G. and Yanklovich, M.A., Vestn. S.-Peterb. Univ., Ser. 4: Fiz., Khim., 2013, no. 4, p. 101.

    Google Scholar 

  23. Rozhkova, E.A., Sukhodolov, N.G., and Yanklovich, A.I., Vestn. S.-Peterb. Univ., Ser. 4: Fiz., Khim., 2012, no. 1, p. 102.

    Google Scholar 

  24. Sukhodolov, N.G., Levashova, L.G., Pavlov, S.Yu., and Yanklovich, A.I., Biol. Membr., 1990, vol. 7, p. 1323.

    CAS  Google Scholar 

  25. Nazarenko, V.A., Antonovich, V.N., and Nevskaya, E.M., Gidroliz ionov metallov v razbavlennykh rastvorakh (Metal Ionw Hydrolysis in Dilute Solutions), Moscow Atomizdat, 1979.

    Google Scholar 

  26. Analiticheskaya khimiya kadmiya (Cadmium Analytical Chemistry), Lur’e, Yu., Ed., Moscow Nauka, 1973.

  27. Chernoberezhskii, Yu.M., Yanklovich, A.I., Kuz’mina, T.A., and Astrakhantseva, N.P., Vestn. Leningr. Univ., Ser. 4: Fiz., Khim., 1972, no. 4, p. 112.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26, Petrodvorets, St. Petersburg, 198504, Russia

    M. A. Yanklovich, N. S. Ivanov, N. G. Sukhodolov & A. N. Zhukov

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  1. M. A. Yanklovich
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  2. N. S. Ivanov
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  3. N. G. Sukhodolov
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  4. A. N. Zhukov
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Correspondence to A. N. Zhukov.

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Original Russian Text © M.A. Yanklovich, N.S. Ivanov, N.G. Sukhodolov, A.N. Zhukov, 2016, published in Kolloidnyi Zhurnal, 2016, Vol. 78, No. 2, pp. 260–264.

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Yanklovich, M.A., Ivanov, N.S., Sukhodolov, N.G. et al. A study of the properties and composition of stearic acid monolayers on an aqueous subphase containing cadmium ions. Colloid J 78, 277–280 (2016). https://doi.org/10.1134/S1061933X16020162

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  • DOI: https://doi.org/10.1134/S1061933X16020162

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