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Preparation and Characterization of PLLA-Based Microporous Membranes with High CO2/O2 Selective Permeability for Food Packaging

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Abstract

To maintain CO2/O2 permselectivity of poly(lactic acid) (PLLA) microporous films for better preservation of fresh produce, Polytrifluoropropylmethylsiloxane (PTFPMS) was introduced into PLLA to prepare PLLA-PTFPMS-PLLA (PLTL) block copolymer. And PLTL-n% microporous films were prepared using varying ratios of chloroform/acetone blended solvents as the film-casting solution in this study. PTFPMS filled a portion of the micropores of the PLTL-n% film. While the micropores enhanced the O2 and CO2 dioxide permeability of the PLLA microporous film, PTFPMS maintained the CO2/O2 selective permeability of the film. In comparison to PLLA films, the CO2 permeability of mixed solvents-treated PLTL-20% film increased from 1.99 × 10–8 to 10.08 × 10–8 cm3 m/m2 h Pa, O2 permeability increased from 0.70 × 10–8 to 2.02 × 10–8 cm3 m/m2 h Pa, and CO2/O2 permselectivity increased from 2.9 to 5.0 at 5°C. In addition, PLTL-n% microporous films also have good flexibility and UV shielding properties.

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Funding

This work was financially supported by Youth Fund of the National Natural Science Fund Project (21805142); Excellent Youth Training program of College of Food Science and Engineering (SPYQ202101); Young innovative talent of grassland talent project of Inner Mongolia (2020) and Talent Development Fund of Inner Mongolia Autonomous Region (2021).

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Authors and Affiliations

  1. College of Food Science and Engineering, Inner Mongolia Agricultural University, 010018, Hohhot, Inner Mongolia, China

    Linze Liu, Yang Yang, Tungalag Dong & Xueyan Yun

  2. **amen Institute of Rare Earth Materials, Chinese Academy of Sciences, 361021, **amen, China

    Linze Liu & Lijun Song

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  1. Linze Liu
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  2. Yang Yang
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Correspondence to Xueyan Yun.

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Liu, L., Yang, Y., Dong, T. et al. Preparation and Characterization of PLLA-Based Microporous Membranes with High CO2/O2 Selective Permeability for Food Packaging. Polym. Sci. Ser. A (2024). https://doi.org/10.1134/S0965545X23600424

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