Log in

Electrochemical synthesis of poly(O-tolidine): Electrochemical and spectroscopic characterization

  • Structure and Properties
  • Published:
Polymer Science Series A Aims and scope Submit manuscript

Abstract

Polymerization of (O-tolidine), as ring substituted derivative of benzidine was achieved electro-chemically in organic solution containing Bu4NBF4 (0.2 M) in dichloromethane as supporting electrolyte. The film was obtained by electropolymerization in solution containing monomer in various ratio ((5 × 10−4)–(5 × 10−2) M). This polymer was characterized by cycling voltammetry, impedance measurement, UV-visible and FT-IR spectroscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. F. Diaz and J. A. Logan, J. Electroanal. Chem. 111, 111 (1980).

    Article  CAS  Google Scholar 

  2. N. Oyama, Y. Ohnuki, K. Chiba, and T. Ohsaka, Chem. Lett., 1759 (1983).

  3. T. Kobayashi, H. Yoneyama, and H. Tamura, J. Electroanal. Chem. 161, 419 (1984).

    Article  CAS  Google Scholar 

  4. E. A. Kitani and J. Izumi, Bull. Chem. Soc. Japan 57, 248 (1987).

    Google Scholar 

  5. K. Okabayashi, F. Goto, K. Abe, and T. Yoshida, Synth. Met. 18, 365 (1987).

    Article  CAS  Google Scholar 

  6. B. C. Sherman, W. B. Euler, and F. R. Ren, J. Chem. Educ. 71(4), A94 (1994).

    Article  CAS  Google Scholar 

  7. J. Yang, C. Zhao, D. Cui, J. Hou, M. Wan, and M. Xu, J. Appl. Polym. Sci. 56, 831 (1995).

    Article  CAS  Google Scholar 

  8. B. Sari and M. Talu, Synth. Met. 94, 221 (1998).

    Article  CAS  Google Scholar 

  9. Y. Huang, S. Xtao, and H. Tian, J. Funct. Polym. 11(3), 44 (1998).

    CAS  Google Scholar 

  10. G. J. Cruz, J. Morales, M. M. Castillo-Ortega, and R. Olayo, Synth. Met. 88, 213 (1997).

    Article  CAS  Google Scholar 

  11. S. Uemura, K. Teshima, S. Tokuda, N. Kobayashi, and R. Hirohashi, Synth. Met. 101, 701 (1999).

    Article  CAS  Google Scholar 

  12. E. M. Genies, A. Boyle, M. Lapkowski, and S. C. Tsintavis, Synth. Metal. 36, 139 (1990).

    Article  CAS  Google Scholar 

  13. X. G. Li, M. R. Huang, and W. Duan, Chem. Rev. 102, 2925 (2002).

    Article  CAS  Google Scholar 

  14. A. Buzarovska, I. Arsova, and Lj. Arsov, J. Serb. Chem. Soc. 66(1), 27 (2001).

    CAS  Google Scholar 

  15. F. D’Eramo, A. H. Arévalo, J. J. Silber, and L. Sereno, J. Braz. Chem. Soc. 5(3), 2213 (1998).

    Google Scholar 

  16. M. Naveen Kumar, M. Nagabhooshanam, M. Anand Rao, and M. Bhagvanth Rao, Cryst. Res. Technol. 36(3), 309 (2001).

    Article  Google Scholar 

  17. C. P. Andrieux, P. Audebert, P. Hapiot, and J. M. Savéant; J. Phys. Commun. 95, 10158 (1991).

    CAS  Google Scholar 

  18. M. S. Ureta-Zanartu, A. Alarcon, C. Berrios, G. I. Cardenas-Jiron, J. Zagal, and C. Gutierrez, J. Electroanal. Chem. 580, 94 (2005).

    Article  CAS  Google Scholar 

  19. R. K. Shervedani and S. A. Mozaffari, Surf. Coat. Technol. 198, 123 (2005).

    Article  CAS  Google Scholar 

  20. J. G. Killian, B. M. Coffey, F. Gao, T. O. Poehler, and P. C. Searson, J. Electrochem. Soc. 143, 936 (1996).

    Article  CAS  Google Scholar 

  21. J. Y. Lee and C. Q. Cui, J. Electroanal. Chem. 403, 109 (1996).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Guergouri.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Guergouri, M., Bencharif, L. Electrochemical synthesis of poly(O-tolidine): Electrochemical and spectroscopic characterization. Polym. Sci. Ser. A 53, 24–29 (2011). https://doi.org/10.1134/S0965545X11010020

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965545X11010020

Keywords

Navigation