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CoMo Sulfide Catalysts Supported on Natural Halloysite Nanotubes: Dealumination as an Effective Approach to Improve Catalytic Performance

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Abstract

–CoMo sulfide catalysts supported on aluminosilicate halloysite nanotubes (CoMoS/HNT) and on dealuminated halloysite nanotubes (CoMoS/HNT(deAl)) were synthesized by incipient wetness impregnation using pseudoboehmite as a binder. Both the supports and related catalysts were characterized by low-temperature nitrogen adsorption, energy dispersive X-ray fluorescence analysis, temperature-programmed reduction by hydrogen, FTIR spectroscopy of adsorbed pyridine, transmission electron microscopy, and X-ray photoelectron spectroscopy. The catalyst samples were further tested in hydrotreating of diesel feedstocks. Dealumination of halloysite was found to increase the area of Si-enriched surface segments, thus weakening interaction between the sulfide phase and the support and, hence, increasing the content of highly active sulfide particles. In the case of a mixed feedstock, CoMoS/HNT(deAl) + Al2O3 achieved a reaction rate constant of 0.605 ppm S–0.4/g(L–0.4 h) compared to 0.429 ppm S–0.4/g(L–0.4 h) for an alumina-supported sample.

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Funding

This study was funded by the Russian Science Foundation (project no. 19-79-10016, https://rscf.ru/project/19-79-10016).

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Authors and Affiliations

  1. Gubkin Russian State University of Oil and Gas (National Research University), 119991, Moscow, Russia

    N. A. Vinogradov, A. V. Vutolkina, A. A. Pimerzin & A. P. Glotov

  2. Samara State Technical University, 443100, Samara, Russia

    N. A. Vinogradov, V. I. Elizarova & A. A. Pimerzin

  3. Department of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russia

    A. V. Vutolkina

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  1. N. A. Vinogradov
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  2. V. I. Elizarova
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Vinogradov, N.A., Elizarova, V.I., Vutolkina, A.V. et al. CoMo Sulfide Catalysts Supported on Natural Halloysite Nanotubes: Dealumination as an Effective Approach to Improve Catalytic Performance. Pet. Chem. (2024). https://doi.org/10.1134/S0965544124030071

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