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Selective Hydrogenation of Phenol Using a Ni2P Catalyst Supported on Mesoporous Polymeric Nanospheres

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Abstract

The paper describes the synthesis of a Ni2P-NSMR catalyst based on nickel phosphides supported on a nanospherical mesoporous resorcinol–formaldehyde polymer. The catalyst was tested in the hydrogenation of phenol at 220, 270, and 320°C and at a hydrogen pressure of 6.0 MPa. The cyclohexanone selectivity and phenol conversion in the presence of Ni2P nanoparticles supported on the mesoporous polymer amounted to 92 and 17%, respectively, compared to 80 and 13% in the presence of unsupported Ni2P nanoparticles.

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Funding

The study was supported by the Russian Science Foundation (project no. 20-19-00380).

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Authors and Affiliations

  1. Faculty of Chemistry, Lomonosov Moscow State University, 119991, Moscow, Russia

    I. I. Shakirov, M. P. Boronoev, S. V. Kardashev, F. N. Putilin & E. A. Karakhanov

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  1. I. I. Shakirov
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  2. M. P. Boronoev
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  3. S. V. Kardashev
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  4. F. N. Putilin
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  5. E. A. Karakhanov
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Correspondence to I. I. Shakirov.

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E.A. Karakhanov is a member of the editorial board of the Neftekhimiya (Petroleum Chemistry) Journal. The other co-authors declare no conflict of interest requiring disclosure in this article.

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Shakirov, I.I., Boronoev, M.P., Kardashev, S.V. et al. Selective Hydrogenation of Phenol Using a Ni2P Catalyst Supported on Mesoporous Polymeric Nanospheres. Pet. Chem. 61, 1111–1117 (2021). https://doi.org/10.1134/S0965544121100042

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