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Ruthenium- and Palladium-Containing Catalysts Based on Mesoporous Polymer Nanospheres in Guaiacol Hydrogenation

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Abstract

Catalysts Pd-NSMR and Ru-NSMR based on palladium and ruthenium nanoparticles deposited on a nanospherical mesoporous resorcinol-formaldehyde polymer are synthesized. It is shown that the average size of polymer particles is 220–250 nm and the average size of palladium and ruthenium nanoparticles is 7.2 and 2.2 nm, respectively. The catalysts are tested in guaiacol hydrogenation at a temperature of 200°С and a hydrogen pressure of 4.0 MPa. It is demonstrated that the ruthenium catalyst shows higher activity in guaiacol hydrogenation.

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REFERENCES

  1. B. Bereiter, S. Eggleston, J. Schmitt, C. Nehrbass-Ahles, T. F. Stocker, H. Fischer, S. Kipfstuhl, and J. Chappellaz, Geophys. Res. Lett. 42 (2), 542 (2015). https://doi.org/10.1002/2014GL061957

    Article  Google Scholar 

  2. I. Ramli, Y. Taufiq-Yap, and E. Muhamad, Catalysts 9, 1 (2018). https://doi.org/10.3390/catal9010015

    Article  CAS  Google Scholar 

  3. V. O. Goncalves, S. Brunet, and F. Richard, Catal. Lett. 146 (8), 1562 (2016). https://doi.org/10.1007/s10562-016-1787-5

    Article  CAS  Google Scholar 

  4. Y. C. Lin, C. L. Li, H. P. Wan, H. T. Lee, and C. F. Liu, Energy Fuels 25 (3), 890 (2011). https://doi.org/10.1021/ie5032698

    Article  CAS  Google Scholar 

  5. W. Wang, K. Zhang, L. Li, K. Wu, P. Liu, and Y. Yang, Ind. Eng. Chem. Res. 53 (49), 19001 (2014).

    Article  CAS  Google Scholar 

  6. K. A. Resende, C. E. Hori, F. B. Noronha, H. Shi, O. Y. Gutierrez, D. M. Camaioni, and J. A. Lercher, Appl. Catal., A 548, 128 (2017). https://doi.org/10.1016/j.apcata.2017.08.005

  7. L. Dong, L. L. Yin, Q. **a, X. Liu, X. Q. Gong, and Y. Wang, Catal. Sci. Technol. 8 (3), 735 (2018). https://doi.org/10.1039/C7CY02014G

    Article  CAS  Google Scholar 

  8. Y. Peng, Z. Hu, Y. Gao, D. Yuan, Z. Kang, Y. Qian, N. Yan, and D. Zhao, ChemSusChem 8 (19), 3208 (2015). https://doi.org/10.1002/cssc.201500755

    Article  CAS  PubMed  Google Scholar 

  9. H. Chen, Y. He, L. D. Pfefferle, W. Pu, Y. Wu, and S. Qi, ChemCatChem 10 (12), 2558 (2018). https://doi.org/10.1002/cctc.201800211

    Article  CAS  Google Scholar 

  10. E. A. Karakhanov, M. P. Boronoev, T. Y. Filippova, and A. L. Maksimov, Pet. Chem. 58 (5), 407 (2018). https://doi.org/10.1134/S0965544118050080

    Article  CAS  Google Scholar 

  11. S. C. Shit, R. Singuru, S. Pollastri, B. Joseph, B. S. Rao, N. Lingaiah, and J. Mondal, Catal. Sci. Technol 8 (8), 2195 (2018). https://doi.org/10.1039/C8CY00325D

    Article  CAS  Google Scholar 

  12. M. P. Boronoev, I. I. Shakirov, V. I. Ignat’eva, A. L. Maximov, and E. A. Karakhanov, 59 (12), 1300 (2019). https://doi.org/10.1134/S096554411912003X

  13. X. Zhu, S. Wang, W. Huang, Y. Tian, and X. Wang, Carbon 105, 521 (2016). https://doi.org/10.1039/C5NR00331H

    Article  CAS  Google Scholar 

  14. T. Matthias, K. Katsumi, V. N. Alexander, P. O. James, R. R. Francisco, R. Jean, and S. W. S. Kenneth, IUPAC Inf. Bull 87 (10), 1051 (2015). https://doi.org/10.1515/pac-2014-1117

    Article  CAS  Google Scholar 

  15. N. B. McKeown, P. M. Budd, K. J. Msayib, B. S. Ghanem, H. J. Kingston, C. E. Tattershall, S. Makhseed, K. J. Reynolds, and D. Fritsch, Chem. Eur. J. 11 (9), 2610 (2005). https://doi.org/10.1002/chem.200400860

    Article  CAS  PubMed  Google Scholar 

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Funding

This study was supported by the Russian Foundation for Basic Research (project no. 18-33-20069).

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    I. I. Shakirov, M. P. Boronoev, A. V. Zolotukhina, A. L. Maximov & E. A. Karakhanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991, Moscow, Russia

    A. L. Maximov

Authors
  1. I. I. Shakirov
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  2. M. P. Boronoev
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  3. A. V. Zolotukhina
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  4. A. L. Maximov
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  5. E. A. Karakhanov
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Corresponding author

Correspondence to I. I. Shakirov.

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CONFLICT OF INTEREST

A.L. Maximov is the editor-in-chief of the journal Petroleum Chemistry and E.A. Karakhanov is the member of the editorial board of the journal Petroleum Chemistry. Other authors declare that there is no conflict of interest to be disclosed in this paper.

ADDITIONAL INFORMATION

I.I. Shakirov, ORCID: https://orcid.org/0000-0003-2029-693X

M.P. Boronoev, ORCID https://orcid.org/0000-0001-6129-598X

A.V. Zolotukhina, ORCID: https://orcid.org/0000-0002-0797-0611

A.L. Maximov ORCID: https://orcid.org/0000-0001-9297-4950

E.A. Karakhanov, ORCID: https://orcid.org/0000-0003-4727-954X

Additional information

Translated by T. Soboleva

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Shakirov, I.I., Boronoev, M.P., Zolotukhina, A.V. et al. Ruthenium- and Palladium-Containing Catalysts Based on Mesoporous Polymer Nanospheres in Guaiacol Hydrogenation. Pet. Chem. 60, 1136–1140 (2020). https://doi.org/10.1134/S0965544120100102

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