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Deep Purification of Vacuum Gas Oil by the Method of Oxidative Desulfurization

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Abstract

The possibility of using of the catalytic system based on formic acid and a transition metal salt in the presence of hydrogen peroxide for desulfurization of nonhydrotreated vacuum gas oil has been explored. Conditions for effective oxidation of organic sulfur compounds and maximal extraction of oxidized compounds from the feedstock have been selected. It has been shown that the catalysts based on tungsten salts are the most effective those for oxidative desulfurization of heavy feedstock. Under optimum conditions, the degree of desulfurization of vacuum gas oil was 89%.

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Funding

This work was supported by the Ministry of Education and Science of the Russian Federation under the Federal Target Program “Research and Elaboration on Priority Directions for Development of Science and Technical Complex of Russia for 2014—2020”, arrangement 1.3, grant agreement no. 14.607.21.0173 of Sept 26, 2017. Unique project identifier RFMEFI60717X0173.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. V. Akopyan, D. A. Plotnikov, P. D. Polikarpova, A. A. Kedalo, S. V. Egazar’yants, A. V. Anisimov & E. A. Karakhanov

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  1. A. V. Akopyan
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  2. D. A. Plotnikov
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  3. P. D. Polikarpova
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  4. A. A. Kedalo
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  5. S. V. Egazar’yants
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  6. A. V. Anisimov
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  7. E. A. Karakhanov
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Corresponding author

Correspondence to A. V. Akopyan.

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Translated by S. Lebedev

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Akopyan, A.V., Plotnikov, D.A., Polikarpova, P.D. et al. Deep Purification of Vacuum Gas Oil by the Method of Oxidative Desulfurization. Pet. Chem. 59, 975–978 (2019). https://doi.org/10.1134/S0965544119090019

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  • DOI: https://doi.org/10.1134/S0965544119090019

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