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Synthesis, Structure, and Catalytic Properties of Nanocomposites Based on Palladium, Copper(I) Oxide, and Magnetite Nanoparticles Embedded in a Nanocellulose Matrix

  • PHYSICAL CHEMISTRY OF NANOCLUSTERS, SUPRAMOLECULAR STRUCTURES, AND NANOMATERIALS
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Abstract

Nanocomposite materials based on palladium, copper(I) oxide, and magnetite nanoparticles embedded in a nanocellulose matrix by precipitation and coprecipitation methods were obtained in situ and ex situ from solutions of the salts of the corresponding metals. Studies of the characteristics of the resulting composites using Fourier transform IR spectroscopy, X-ray diffraction, SEM, and TEM showed that the encapsulated nanoparticles have an insignificant effect on the morphology and structure of nanofibrillar cellulose. The catalytic properties of the nanocomposites were tested in the hydrogenation of nitrobenzene.

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ACKNOWLEDGMENTS

The authors (L.M.K. and O.P.T.) are grateful to the Russian Science Foundation for financial support (grant no. 23-73-30007) regarding the study of catalytic properties.

Funding

This study was performed under the government contract no. 122032800155-9 at the Institute of Structural Macrokinetics and Materials Science. This work was performed in the part related to IR spectra measurements using equipment of the Center for Collective Use New Petrochemical Processes, Polymer Composites, and Adhesives (no. 77601).

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Authors and Affiliations

  1. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    E. G. Chepaikin, S. I. Pomogailo & V. N. Borshch

  2. All-Russian Institute of Scientific and Technical Information, Russian Academy of Sciences, 125190, Moscow, Russia

    S. I. Pomogailo

  3. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    O. P. Tkachenko, E. V. Shuvalova & L. M. Kustov

  4. Federal Research Center for Problems in Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432, Chernogolovka, Russia

    E. I. Knerel’man

  5. Lomonosov Moscow State University, 119991, Moscow, Russia

    L. M. Kustov & D. A. Pomogailo

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  1. E. G. Chepaikin
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  2. S. I. Pomogailo
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  4. E. V. Shuvalova
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  5. L. M. Kustov
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  6. V. N. Borshch
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  7. E. I. Knerel’man
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  8. D. A. Pomogailo
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Correspondence to E. G. Chepaikin.

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Chepaikin, E.G., Pomogailo, S.I., Tkachenko, O.P. et al. Synthesis, Structure, and Catalytic Properties of Nanocomposites Based on Palladium, Copper(I) Oxide, and Magnetite Nanoparticles Embedded in a Nanocellulose Matrix. Russ. J. Phys. Chem. (2024). https://doi.org/10.1134/S003602442470016X

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