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Thermodynamics of the Formation of Mixed Complexes of Nickel(II) Ions with Histidine and Diamines in an Aqueous Solution

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Abstract

Calorimetry, spectrophotometry, and pH measurements are used to study the formation of mixed ligand complexes with 1,10-phenanthroline (Phen) and ethylenediamine (En) in Ni(II)–His–Phen(En) systems. The formation of mixed complexes with different stoichiometries is found, and the thermodynamic parameters (\(\log K\), ΔrG0, ΔrH, ΔrS) of the reactions of their formation at 298.15 K and ionic strength I = 0.5 (KNO3) are calculated. The most likely form of the coordination of the amino acid residue in the composition of the mixed complexes is identified.

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REFERENCES

  1. D. S. Sigman, A. Mazumder, and D. M. Perrin, Chem. Rev. 93, 2295 (1993). https://doi.org/10.1021/cr00022a011

    Article  CAS  Google Scholar 

  2. P. P. Silva, W. Guerra, J. N. Silveira, et al., Inorg. Chem. 50, 6414 (2011). https://doi.org/10.1021/ic101791r

    Article  CAS  PubMed  Google Scholar 

  3. P. P. Silva, W. Guerra, G. Coelho dos Santos, et al., J. Inorg. Biochem. 132, 67 (2014). https://doi.org/10.1016/j.**orgbio.2013.09.014

    Article  CAS  PubMed  Google Scholar 

  4. B. E. Fischer and H. Sigel, J. Am. Chem. Soc. 102, 2998 (1980). https://doi.org/10.1021/ja00529a021

    Article  CAS  Google Scholar 

  5. G. S. Malik, S. P. Singh, and J. P. Tandon, Monatsh. Chem. 110, 149 (1979). https://doi.org/10.1007/BF00903758

    Article  CAS  Google Scholar 

  6. K. Kumar, D. R. Prasad, and P. C. Nigam, Monatsh. Chem. 115, 731 (1984). https://doi.org/10.1007/BF01120968

    Article  CAS  Google Scholar 

  7. V. K. Patel and P. K. Bhattacharya, Inorg. Chim. Acta 92, 199 (1984). https://doi.org/10.1016/S0020-1693(00)87759-2

    Article  CAS  Google Scholar 

  8. V. A. Borodin, V. P. Vasil’ev, and E. V. Kozlovskii, Mathematic Problems of Chemical Thermodynamics (Nauka, Novosibirsk, 1985), p. 219 [in Russian].

    Google Scholar 

  9. L. D. Pettit, Pure Appl. Chem. 56, 247 (1984). https://doi.org/10.1351/pac198456020247

    Article  Google Scholar 

  10. P. Paoletti, Pure Appl. Chem. 56, 491 (1984). https://doi.org/10.1351/pac198456040491

    Article  Google Scholar 

  11. G. Anderegg, Helvet. Chim. Acta 46, 2813 (1963). https://doi.org/10.1002/hlca.19630460740

    Article  CAS  Google Scholar 

  12. O. Yamauchi and A. Odani, J. Am. Chem. Soc. 107, 5938 (1985). https://doi.org/10.1021/ja00307a019

    Article  CAS  Google Scholar 

  13. O. Yamauchi, T. Sakurai, and A. Nakahara, J. Am. Chem. Soc. 101, 4164 (1979). https://doi.org/10.1021/ja00509a024

    Article  CAS  Google Scholar 

  14. O. Yamauchi and A. Odani, Inorg. Chim. Acta 100, 165 (1985). https://doi.org/10.1016/S0020-1693(00)88304-8

    Article  CAS  Google Scholar 

  15. O. Yamauchi and A. Odani, J. Chem. Soc., Dalton Trans., p. 3411 (2002). https://doi.org/10.1039/B202385G

  16. H. Masuda, T. Sugimori, O. Yamauchi, et al., Inorg. Chim. Acta 180, 73 (1991). https://doi.org/10.1016/S0020-1693(00)83068-6

    Article  CAS  Google Scholar 

  17. D. Inci and R. Aydın, J. Sol. Chem. 50, 128 (2021). https://doi.org/10.1007/s10953-020-01046-3

    Article  CAS  Google Scholar 

  18. E. V. Kozlovskii, D. F. Pyreu, and T. B. Khochenkova, Russ. J. Inorg. Chem. 53, 1158 (2008). https://doi.org/10.1134/S0036023608070309

    Article  Google Scholar 

  19. D. Pyreu and S. Gridchin, J. Therm. Anal. Calorim. 139, 1435 (2020). https://doi.org/10.1007/s10973-019-08453-9

    Article  CAS  Google Scholar 

  20. E. V. Kozlovskii, G. V. Chistyakova, and V. P. Vasil’ev, Zh. Neorg. Khim. 34, 853 (1989).

    CAS  Google Scholar 

Download references

Funding

This work was supported by the RF Ministry of Science and Higher Education as part of a State Task for Ivanovo State University, notice no. FZZM-2021-0002.

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Authors and Affiliations

  1. Ivanovo State University, 153025, Ivanovo, Russia

    D. F. Pyreu & M. G. Nikitina

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  1. D. F. Pyreu
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  2. M. G. Nikitina
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Correspondence to D. F. Pyreu.

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Translated by E. Boltukhina

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Pyreu, D.F., Nikitina, M.G. Thermodynamics of the Formation of Mixed Complexes of Nickel(II) Ions with Histidine and Diamines in an Aqueous Solution. Russ. J. Phys. Chem. 95, 2238–2245 (2021). https://doi.org/10.1134/S0036024421110169

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