Abstract
Ag nanoparticles (AgNPs) were used as adsorbent to remove trace iodide from acetic acid. Under identical conditions, AgNPs adsorbent with 0.5 wt % Ag has the same performance as commercial adsorbent with 10 wt % Ag+. In addition, Ag loss of AgNPs adsorbent is remarkably lower than that of commercial adsorbent. The Ag content in AgNPs adsorbent affects its adsorption performance, and the optimal content is 1.0 wt %. Saturated AgNPs adsorbent can be regenerated by hydrogen reduction and reused with satisfying performance. The properties of AgNPs adsorbent are based on surface effect of nanoparticles, differing from commercial Ag+ type adsorbents. In a word, AgNPs adsorbent is of high efficiency, low Ag loss and easy recycling, thus making it “green adsorbent” for removing iodide from acetic acid.
Similar content being viewed by others
References
H. R. Tang, W. N. Wang, Z. H. Li, W. L. Dai, K. N. Fan, and J. F. Deng, Surf. Sci. 450, 133 (2000).
C. Mathew, M. A. Majali, and S. A. Balakrishnan, Appl. Radiat. Isot. 57, 359 (2002).
E. Spohr, Chem. Phys. Lett. 207, 214 (1993).
B. V. Andryushechkin, G. M. Zhidomirov, K. N. Eltsov, Y. V. Hladchanka, and A. A. Korlyukov, Phys. Rev. B 80, 125409 (2009).
H. S. White, Langmuir 10, 486 (1994).
A. P. Zhang, X. Y. Tie, J. Z. Zhang, Y. W. An, and L. J. Li, Appl. Surf. Sci. 255, 3184 (2008).
M. S. Sibbald, G. Chumanov, and T. M. Cotton, J. Electroanal. Chem. 438, 179 (1997).
J. S. Hoskins, T. Karanfil, and S. M. Serkiz, Environ. Sci. Technol. 36, 784 (2002).
M. Sánchez-Polo, J. Rivera-Utrilla, E. Salhi, and U. von Gunten, J. Colloid Interface Sci. 300, 437 (2006).
M. Sánchez-Polo, J. Rivera-Utrilla, E. Salhi, and U. von Gunten, Water Res. 41, 1031 (2007).
M. Sánchez-Polo, J. Rivera-Utrilla, and V. von Gunten, J. Colloid Interface Sci. 306, 183 (2007).
P. M. Maitlis, A. Haynes, G. J. Sunley, and M. J. Howard, J. Chem. Soc., Dalton Trans., p. 2187 (1996).
D. Kumar, M. S. Chen, and D. W. Goodman, Catal. Today 123, 77 (2007).
B. B. Fish, W. D. Prince, and M. P. Spratt, US Patent No. 5561168 (1996); B. B. Fish, W. D. Prince, and M. P. Spratt, US Patent No. 5220058 (1993); Durland and J. Jonathan, US Patent No. 5139891 (1992); Hilton and B. Charles, US Patent No. 4615 806 (1986); M. D. Jones, US Patent No. 5227524 (1993); H. Miura, M. Kayajima, and T. Sato, US Patent No. 5801279 (1998); S. Kulphathipanja, B. C. Spehlmann, R. R. Willis, J. D. Sherman, and W. A. Leet, US Patent No. 5962735 (1999); S. Kulprathipanja, J. D. Sherman, A. Napolitano, and Markovs, US Patent No. 6380428 (2002); C. B. Hilton, US Patent No. 6 211408 (2001).
Q. Qian, S. Shao, F. Yan, and G. Yuan, J. Colloid Interface Sci. 328, 257 (2008).
N. Yoneda, S. Kusano, M. Yasui, P. Pujado, and S. Wilcher, Appl. Catal. A 221, 253 (2001).
M. D. Jones, D. J. Watson, and B. L. Williams, US Patent No. 5 344 976 (1994).
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Qian, Q., Shao, S., Yan, F. et al. Supported Ag nanoparticles as trace iodide adsorbent from acetic acid. Russ. J. Phys. Chem. 86, 1453–1457 (2012). https://doi.org/10.1134/S0036024412070229
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024412070229