Abstract
Cation mobility in Li3 − 2x Nb x In2 − x (PO4)3 complex phosphates was studied by impedance spectroscopy, calorimetry, and 7Li NMR spectroscopy. A phase transition at ≈273 K is suggested for compositions containing ≈1 mol lithium per formula unit.
Similar content being viewed by others
References
A. D. Robertson, A. R. West, and A. G. Ritchie, Solid State Ionics 104, 1 (1997).
A. A. Vashman and K. I. Petrov, Functional Inorganic Compounds of Lithium (Energoatomizdat, Moscow, 1996) [in Russian].
A. I. Orlova, D. V. Kemenov, V. I. Pet’kov, and M. V. Zharinova, High Temperature-High Pressure 34, 315 (2002).
A. K. Ivanov-Shits and I. V. Murin, Solid-State Ionics (Izd-vo Sankt-Peterburg. Univ., St. Petersburg, 2000), Vol. 1 [in Russian].
A. B. Yaroslavtsev and I. A. Stenina, Russ. J. Inorg. Chem. 51, 95 (2006).
F. J. Berry and M. Vithal, Polyhedron 14, 1113 (1995).
A. R. Shaikhlislamova and A. B. Yaroslavtsev, Neorg. Mater. 44(11), 1361 (2008).
B. S. Bokshtein and A. B. Yaroslavtsev, Ion and Atom Diffusion in Solids (Izd-vo MISIS, Moscow, 2005) [in Russian].
I. A. Stenina, Yu. A. Velikodnyi, V. A. Ketsko, and A. B. Yaroslavtsev, Neorg. Mater. 40(9), 1106 (2004).
S. P. Gabuda and R. N. Pletnev, NMR in Solid-State Chemistry. Inorganic Crystal Chemistry (Izd-vo “Ekaterinburg”, Yekaterinburg, 1996) [in Russian].
N. Bloembergen, E. M. Purcell, and R. V. Pound, Phys. Rev. 73, 679 (1948).
M. Catti and S. Stramare, Solid State Ionics 136–137, 489 (2000).
M. A. Paris, A. Martinez-Juarez, J. M. Rojo, and J. Sanz, J. Phys. Condens. Matter 8, 5355 (1996).
I. A. Stenina, M. N. Kislitsyn, I. Yu. Pinus, et al., Zh. Neorg. Khim. 50(6), 985 (2005) [Russ. J. Inorg. Chem. 50 (6), 906 (2005)].
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.R. Shaikhlislamova, I.A. Stenina, N.A. Zhuravlev, I.V. Arkhangel’skii, A.I. Rebrov, A.B. Yaroslavtsev, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 4, pp. 552–557.
Rights and permissions
About this article
Cite this article
Shaikhlislamova, A.R., Stenina, I.A., Zhuravlev, N.A. et al. Phase transformations and cation mobility in Li3 − 2x Nb x In2 − x (PO4)3 complex phosphates. Russ. J. Inorg. Chem. 54, 500–504 (2009). https://doi.org/10.1134/S0036023609040020
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023609040020