Abstract
Data on excited states of XeKr molecules in the energy range 78280–77600 cm−1 are obtained. Using the method of multiphoton laser photoionization of molecules in a supersonic jet, five vibrational progressions of XeKr molecules are obtained, which are attributed to five electronic-vibrational transitions from the ground state of the XeKr molecule of the symmetry 0+ to excited states of the symmetry Ω = 0+, 1, 2 with the dissociation limit Kr1 S 0 + Xe*6p[5/2]2 and of the symmetry Ω = 1, 2 with the dissociation limit Kr + Xe*6 p [5/2]3. The molecular constants of the corresponding excited states of the XeKr molecule are estimated.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
D. E. Freeman, K. Yoshino, and J. Tanaka, J. Chem. Phys. 67(8), 3462 (1977).
M. C. Castex, J. Chem. Phys. 66(9), 3854 (1977).
A. Balakrishnan, W. J. Iones, C. G. Manajan, and B. P. Stoicheff, Chem. Phys. Lett. 155(1), 43 (1989).
R. H. Lipson, S. S. Dimov, X. K. Hu, et al., J. Chem. Phys. 103(15), 6313 (1995).
S. T. Pratt, P. M. Dehmer, and J. L. Dehmer, J. Chem. Phys. 83(11), 5380 (1985).
K. Tang and J. P. Toennies, J. Chem. Phys. 118(11), 4976 (2003).
R. H. Lipson and R. W. Field, J. Chem. Phys. 110(22), 10653 (1999).
M. V. Bobetic and J. A. Barker, J. Chem. Phys. 64(6), 2367 (1976).
B. Jansik, B. Schimmelpfennig, and H. Agren, Phys. Rev. A 67, 042501 (2003).
M. A. Khodorkovskiĭ, A. A. Belyaeva, L. P. Rakcheeva, et al., Opt. Spektrosk. 100(4), 549 (2006) [Opt. Spektrosk. 100 (4), 497 (2006)].
G. Herzberg, Molecular Spectra and Molecular Structure, 2nd ed. (Krieger, Malabar, FL, 1989; Inostrannaya Literatura, Moscow, 1949).
H. Yoshi, T. Tanaka, Y. Morioka, and K. Ito, J. Chem. Phys. 111(23), 10595 (1999).
Author information
Authors and Affiliations
Additional information
Original Russian Text © M.A. Khodorkovskiĭ, A.A. Belyaeva, L.P. Rakcheeva, A.A. Pastor, P.Yu. Serdobintsev, N.A. Timofeev, I.A. Shevkunov, R. Hallin, K. Siegbahn, 2007, published in Optika i Spektroskopiya, 2007, Vol. 102, No. 6, pp. 908–915.
Rights and permissions
About this article
Cite this article
Khodorkovskiĭ, M.A., Belyaeva, A.A., Rakcheeva, L.P. et al. Multiphoton mass spectra of XeKr molecules in the range of excited Xe*6p[5/2]2, 3 atoms. Opt. Spectrosc. 102, 834–841 (2007). https://doi.org/10.1134/S0030400X07060069
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1134/S0030400X07060069