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Effects of Phosphorus Modifier and Support on the Properties of Palladium Catalysts in the Chemoselective Hydrogenation of Acetylenic Compounds

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Abstract

Efficient heterogeneous catalysts for chemoselective hydrogenation of terminal and disubstituted alkynes and alkynols to monoenes based on Pd–P particles have been proposed. The influence of a zeolite support (Na-ZSM-5, MSM-41) and a phosphorus modifier on the properties of palladium catalysts in the semihydrogenation of acetylenic compounds is considered. Promotion with phosphorus increases the activity of palladium catalysts in hydrogenation of various acetylenic compounds 2.5- to 30-fold without reducing the selectivity for monoenes. The high selectivity for monoenes is determined by both thermodynamic and kinetic factors. The possibility of changing the ratio of the rates of hydrogenation of triple and double bonds by varying the nature of the solvent and the structural order of the catalyst particles was demonstrated using hydrogenation of acetylenic alcohols as an example.

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Funding

The study was supported by the Ministry of Education and Science of Russia under the government contract (topic code: FZZE-2023-0006; agreement no. 075-03-2023-036). It was performed using the equipment of the Multiaccess Center of Analytical Equipment, Irkutsk State University (http://ckp-rf.ru/ckp/3264/); Multiaccess Center “Baikal Center for Nanotechnologies,” Irkutsk National Research Technical University (Tecnai G2 electron microscope); and Multiaccess Center for Isotope Geochemical Research (ELEMENT 2 high-resolution mass spectrometer).

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Authors and Affiliations

  1. Irkutsk State University, 664003, Irkutsk, Russia

    L. B. Belykh, T. P. Sterenchuk, N. I. Skripov, E. A. Milenkaya, T. A. Kornaukhova & F. K. Schmidt

  2. Irkutsk National Research Technical University, 664074, Irkutsk, Russia

    S. A. Skornikova & S. S. Kolesnikov

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  1. L. B. Belykh
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  2. T. P. Sterenchuk
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  3. N. I. Skripov
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  4. E. A. Milenkaya
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  5. T. A. Kornaukhova
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  6. S. A. Skornikova
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  7. S. S. Kolesnikov
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Correspondence to L. B. Belykh.

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Translated by L. Smolina

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Abbreviations: DMF is N,N-dimethylformamide; Pd(acac)2, palladium bis- (acetylacetonate); PA, phenylacetylene; MBA, 2-methylbutan-2-ol; MBE, 2-methyl-3-buten-2-ol; MBY, 2‑methyl-3-butyn-2-ol; BYD, 2-butyne-1,4-diol; BED, 2‑butene-1,4-diol; Ssp, specific surface area; Vtot, total pore volume; Vmicrop, micropore volume; dav, average pore size; a.b., absorption band; ICP MS, inductively coupled plasma mass spectrometry; TEM, transmission electron microscopy; XRD, X-ray diffraction analysis; GLC, gas-liquid chromatography; BET, Brunauer–Emmett–Teller method; CSR, coherent scattering region; TOF, turnover frequency; a, catalytic activity based on total palladium; DTEM, dispersion determined from TEM data; MPd, atomic mass of Pd; APd, surface area of the Pd atom; ρ, density of palladium; NA, Avogadro number; dTEM, average surface particle diameter; ni, number of particles with a diameter di.

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Belykh, L.B., Sterenchuk, T.P., Skripov, N.I. et al. Effects of Phosphorus Modifier and Support on the Properties of Palladium Catalysts in the Chemoselective Hydrogenation of Acetylenic Compounds. Kinet Catal 65, 17–29 (2024). https://doi.org/10.1134/S0023158424010014

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