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A Comparative Study of the Catalytic Activity of Sulfonic Acid Cation-Exchange Resins with a Macroporous and Gel Structure in Fatty Acid Esterification

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Abstract

The activity and stability of cation-exchange resins in fatty acid esterification with methyl alcohol have been studied. The cation-exchange resins have been characterized by IR spectroscopy, electron microscopy, and low-temperature nitrogen adsorption–desorption (BET method). It has been shown that, due to a developed surface and a larger pore volume, the reaction products are readily desorbed and thereby prevent the catalytic sites from blocking and the catalyst from losing activity. Of the studied cation-exchange resins, the best results have been obtained in the case of using the Lewatit MonoPlus SP 112 cation-exchange resin with a macroporous structure.

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Funding

This work was supported by the Tekhnoplatforma 2035 Research and Educational Center of the Nizhny Novgorod oblast (agreement no. 16-11-2021/51). Properties of the catalysts were studied under a state task in the field of scientific activity (subject no. FSWE-2020-0008).

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Authors and Affiliations

  1. Nizhny Novgorod State Technical University, 603950, Nizhny Novgorod, Russia

    K. V. Otopkova, A. L. Esipovich, E. A. Kanakov, T. A. Charykova, V. E. Baydachenko & T. A. Ryabova

  2. Lobachevsky State University of Nizhny Novgorod (National Research University), 603022, Nizhny Novgorod, Russia

    K. V. Otopkova & A. L. Esipovich

Authors
  1. K. V. Otopkova
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  2. A. L. Esipovich
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  3. E. A. Kanakov
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  4. T. A. Charykova
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  5. V. E. Baydachenko
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  6. T. A. Ryabova
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Correspondence to K. V. Otopkova.

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Translated by M. Timoshinina

Abbreviations and notation: FAMEs, fatty acid methyl esters; FFAs, free fatty acids; FAs, fatty acids; BET, Brunauer–Emmett–Teller method; SEM, scanning electron microscopy; AN, acid number; GPC, gel permeation chromatography; HPLC, high-performance liquid chromatography.

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Otopkova, K.V., Esipovich, A.L., Kanakov, E.A. et al. A Comparative Study of the Catalytic Activity of Sulfonic Acid Cation-Exchange Resins with a Macroporous and Gel Structure in Fatty Acid Esterification. Kinet Catal 63, 666–675 (2022). https://doi.org/10.1134/S002315842206009X

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