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N-Methylation of p-Anisidine on the Catalysts Based on Cu-Containing Layered Double Hydroxides

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Abstract

Cu-containing layered double hydroxides with different Cu : Al ratios are synthesized by co-precipitation using a mixture of hydroxide and sodium carbonate as a precipitation agent. The influence of the precipitation agent concentration on the formation of the hydrotalcite phase was studied by thermal analysis and X-ray diffraction. The surface of the obtained samples after calcination at 450°C and their subsequent reduction at 300°C in hydrogen, was characterized by X-ray photoelectron spectroscopy and transmission electron microscopy. The synthesized catalysts were tested in the reaction of N-methylation of p-anisidine with methanol in an autoclave reactor to produce N-methyl-p-anisidine. The influence of the Cu : Al ratio in them on the catalytic activity and selectivity was studied.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    M. V. Bukhtiyarova, A. L. Nuzhdin, T. Yu. Kardash, A. V. Bukhtiyarov, E. Yu. Gerasimov & A. V. Romanenko

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  1. M. V. Bukhtiyarova
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  2. A. L. Nuzhdin
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  3. T. Yu. Kardash
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  4. A. V. Bukhtiyarov
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  5. E. Yu. Gerasimov
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  6. A. V. Romanenko
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Correspondence to M. V. Bukhtiyarova.

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Translated by Andrey Zeigarnik

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Bukhtiyarova, M.V., Nuzhdin, A.L., Kardash, T.Y. et al. N-Methylation of p-Anisidine on the Catalysts Based on Cu-Containing Layered Double Hydroxides. Kinet Catal 60, 343–354 (2019). https://doi.org/10.1134/S0023158419030030

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  • DOI: https://doi.org/10.1134/S0023158419030030

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