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SYNTHESIS, CRYSTAL STRUCTURE, AND LUMINESCENT PROPERTY OF A NEW HETEROMETALLIC COMPOUND BASED ON A LARGE π-CONJUGATED DICARBOXYLATE LIGAND

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Abstract

Presented here is a new heterometallic compound with the formula of [CdCa(L)2(H2O)(DMF)]n (1, H2L = 5-(1-oxoisoindolin-2-yl)isophthalic acid, DMF = N,N′-dimethylformamide), which was synthesized under solvothermal conditions. Compound 1 crystallized in the orthorhombic Pna21 space group, and the unit cell parameters of 1 are a = 18.3689(11) Å, b = 14.2830(11) Å, c = 13.9233(11) Å, and α = 90°, β = 90°, γ = 90°, Z = 4. The heterometallic dinuclear [CdCa(COO)3] building subunits are connected by the L2– ligands into a 3D framework. Topological simplification for 1 represents a binodal (3,5)-connected topological network. The result of luminescence test revealed that compound 1 may be good candidate of blue luminescent material.

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Authors and Affiliations

  1. Analysis and Testing Center, Guangdong University of Petrochemical Technology, Maoming, People’s Republic of China

    Y. Tang

  2. School of Chemistry, Guangdong University of Petrochemical Technology, Maoming, People’s Republic of China

    X. -Q. Yao

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  1. Y. Tang
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  2. X. -Q. Yao
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Correspondence to X. -Q. Yao.

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Text © The Author(s), 2022, published in Zhurnal Strukturnoi Khimii, 2022, Vol. 63, No. 11, 102260.https://doi.org/10.26902/JSC_id102260

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Tang, Y., Yao, X.Q. SYNTHESIS, CRYSTAL STRUCTURE, AND LUMINESCENT PROPERTY OF A NEW HETEROMETALLIC COMPOUND BASED ON A LARGE π-CONJUGATED DICARBOXYLATE LIGAND. J Struct Chem 63, 1887–1893 (2022). https://doi.org/10.1134/S0022476622110191

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