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Electron spin resonance detection and identification of nitrogen centers in nanodiamonds

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Abstract

Individual nitrogen centers N0 and nitrogen pairs N +2 have been detected and identified in natural diamond nanocrystals by means of the high-frequency electron spin resonance method. The N0 nitrogen centers have been observed in synthetic diamond nanocrystallites with a size of less than 10 nm produced by high-temperature high-pressure sintering of detonation nanodiamonds. Thus, the possibility of the stable state of impurity nitrogen atoms in diamond nanoparticles has been demonstrated.

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References

  1. UltraNanocrystalline Diamond: Syntheses, Properties and Applications, Ed. by O. Shenderova and D. Gruen (William Andrew, New York, 2006).

    Google Scholar 

  2. S. C. Erwin, Lijun Zu, M. I. Haftel, et al., Nature 436, 91 (2005).

    Article  ADS  Google Scholar 

  3. A. S. Barnard and M. Sternberg, Diamond Relat. Mater. 16, 2078 (2007).

    Article  Google Scholar 

  4. G. D. Watkins, in Deep Centers in Semiconductors, Ed. by S. T. Pantelides (Gordon and Breach, New York, 1986), pp. 147–183.

    Google Scholar 

  5. Phys. Status Solidi A 154, 1–466 (1996).

  6. R. P. Messmer and G. D. Watkins, Phys. Rev. B 7, 2568 (1973), and references therein.

    Article  ADS  Google Scholar 

  7. W. V. Smith, P. P. Sorokin, I. L. Gelles, and G. J. Lasher, Phys. Rev. 115, 1546 (1959).

    Article  ADS  Google Scholar 

  8. L. A. Shulman, I. M. Zaritskii, and G. A. Podzyarei, Fiz. Tverd. Tela 8, 2307 (1966) [Sov. Phys. Solid State 8, 1842 (1967)].

    Google Scholar 

  9. R. J. Cook and D. H. Whiffen, Proc. Roy. Soc. (London) A 295, 99 (1966).

    Article  ADS  Google Scholar 

  10. C. F. O. Graeff, C. E. Nebel, M. Stutzmann, et al., J. Appl. Phys. 81, 234 (1997).

    Article  ADS  Google Scholar 

  11. J. H. N. Loubser and J. A. van Wyk, Pep. Prog. Phys. 41, 1201 (1978).

    Article  ADS  Google Scholar 

  12. A. Gruber, A. Drabenstedt, C. Tietz, et al., Science 276, 2012 (1997).

    Article  Google Scholar 

  13. P. Kok and B. W. Lovett, Nature 444, 49 (2006).

    Article  ADS  Google Scholar 

  14. N. R. Greiner, D. S. Phillips, J. D. Johnson, and F. Volk, Nature 333, 440 (1988).

    Article  ADS  Google Scholar 

  15. V. L. Kuznetsov, A. L. Chuvilin, E. M. Moroz, et al., Carbon 32, 873 (1994).

    Article  Google Scholar 

  16. M. Yoshikawa, Y. Mori, H. Obata, et al., Appl. Phys. Lett. 67, 694 (1995).

    Article  ADS  Google Scholar 

  17. M. Baidakova and A. Vul’, J. Phys. D: Appl. Phys. 40, 6300 (2007).

    Article  ADS  Google Scholar 

  18. F. M. Shakhov, Candidate’s Dissertation in Mathematical Physics (St. Peterburg, 2008).

  19. J. A. van Wyk and J. H. N. Loubser, J. Phys. C: Solid State Phys. 16, 1501 (1983).

    Article  ADS  Google Scholar 

  20. O. D. Tucker, M. E. Newton, and J. M. Baker, Phys. Rev. B 50, 15586 (1994).

    Article  ADS  Google Scholar 

  21. N. D. Samsonenko and E. V. Sobolev, Pis’ma Zh. Eksp. Teor. Fiz. 5, 304 (1967) [JETP Lett. 5, 250 (1967)].

    Google Scholar 

  22. A. I. Shames, A. M. Panich, W. Kempinski, et al., J. Phys. Chem. Solids 63, 1993 (2002).

    Article  ADS  Google Scholar 

  23. S. V. Kidalov, F. M. Shakhov, V. M. Davidenko, et al., Fiz. Tverd. Tela 50, 940 (2008) [Phys. Solid State 50, 981 (2008)].

    Google Scholar 

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Correspondence to P. G. Baranov.

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Original Russian Text © P.G. Baranov, I.V. Il’in, A.A. Soltamova, A.Ya. Vul’, S.V. Kidalov, F.M. Shakhov, G.V. Mamin, S.B. Orlinskii, M.Kh. Salakhov, 2009, published in Pis’ma v Zhurnal Éksperimental’noĭ i Teoreticheskoĭ Fiziki, 2009, Vol. 89, No. 8, pp. 473–477.

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Baranov, P.G., Il’in, I.V., Soltamova, A.A. et al. Electron spin resonance detection and identification of nitrogen centers in nanodiamonds. Jetp Lett. 89, 409–413 (2009). https://doi.org/10.1134/S0021364009080074

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  • DOI: https://doi.org/10.1134/S0021364009080074

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