Abstract—
X-ray diffraction has been used to study the phase composition and determine the lattice parameter of the β- and α-phases in foil of a Pd–Cu solid solution with a composition that ensures reversibility of the β \( \rightleftarrows \) α transformations: with the structure of the β- and α-phases and a two-phase structure. The thermal expansion coefficient of the Pd–Cu solid solution has been determined for the first time.
Similar content being viewed by others
Notes
Shared Research Facilities Center, federal state budget-funded educational institution of higher education Voronezh State University.
REFERENCES
Huang, P., Menon, S., and de Fontaine, D., On the Cu–Pd phase diagram, J. Phase Equilib., 1991, vol. 12, no. 1, pp. 3–5.
Volkov, A.Yu. and Kruglikov, N.A., Effect of plastic deformation on the kinetics of phase transformations in the Cu–47Pd alloy, Phys. Met. Metallogr., 2008, vol. 105, no. 2, pp. 202–211.
Volkov, A.Yu., Novikova, O.S., and Antonov, B.D., Formation of an ordered structure in the Cu–49 at % Pd alloy, Inorg. Mater., 2012, vol. 48, no. 12, pp. 1262–1267.
Hydrogen in Metals, Alefeld, G. and Volkl, J., Eds., Heidelberg: Springer, 1978, vol. 1.
Ievlev, V.M., Dontsov, A.I., Prizhimov, A.S., Serbin, O.V., Roshan, N.R., Gorbunov, S.V., Sinetskaya, D.A., and Solntsev, K.A., Flash lamp processing-activated structural transformations in foil of a Pd–Cu solid solution, Inorg. Mater., 2020, vol. 56, no. 6, pp. 594–599.https://doi.org/10.1134/S0020168520060060
Diagrammy sostoyaniya dvoinykh metallicheskikh sistem: Spravochnik (Phase Diagrams of Binary Metallic Systems: A Handbook), Lyakishev, N.P., Ed., Moscow: Mashinostroenie, 1997, vol. 2.
Burkhanov, G.S., Gorina, N.B., Kolchugina, N.B., Korenovskii, N.L., Roshan, N.R., Slovetskii, D.I., and Chistov, E.M., Palladium–rare earth alloys: promising materials for hydrogen energy generation, Tyazheloe Mashinostr., 2007, no. 11, pp. 17–20.
Burkhanov, G.S., Gorina, N.B., Kolchugina, N.B., Roshan, N.R., Slovetskii, D.I., and Chistov, E.M., Palladium-based alloy membranes for separation of high purity hydrogen from hydrogen-containing gas mixtures, Platinum Met. Rev., 2011, vol. 55, no. 1, pp. 3–12.
Gorbunov, S.V., Kannykin, S.V., Penkina, T.N., Roshan, N.R., Chistov, E.M., and Burkhanov, G.S., Palladium–lead alloys for hydrogen purification and hydrogen isolation from hydrogen-containing gas mixtures, Russ. Metall. (Engl. Transl.), 2017, no. 1, pp. 63–69.
Ievlev, V.M., Doncov, A.I., Novicov, V.I., Sinetskaya, D.A., Gorbunov, S.V., Roshan, N.R., and Burkhanov, G.S., Composite membranes based on Pd–Cu and Pd–Pb solid solutions, J. Russ. Metall., 2018, vol. 2018, no. 9, pp. 854–858.https://doi.org/10.1134/S0036029518090070
Ievlev, V.M., Doncov, A.I., Novicov, V.I., Sinetskaya, D.A., Gorbunov, S.V., Roshan, N.R., and Burkhanov, G.S., Composite membranes based on Pd–Cu and Pd–Pb solid solutions, Russ. Metall. (Engl. Transl.), 2018, no. 9, pp. 854–858.
Ievlev, V.M., Dontsov, A.I., Maksimenko, A.A., and Roshan, N.R., Reversibility of the β ↔ α phase transformations in a Pd–Cu solid solution, Inorg. Mater., 2017, vol. 53, no. 5, pp. 484–488.
Kenso Asaoka and Noriniko Kovayama, Temperature dependence of thermal expansion coefficient for palladium-based binary alloy, Dent. Mater. J., 1990, vol. 9, no. 1, pp. 47–57.
Opalka, S.M., Huang, W., Wang, D., Flanagan, T.B., Lovvik, O.M., Emerson, S.C., She, Y., and Vanderspurt, T.H., Hydrogen interactions with the PdCu ordered B2 alloy, J. Alloys Compd., 2007, vols. 446–447, pp. 583–587.
Ievlev, V.M., Solncev, K.A., Dontsov, A.I., Maksimenko, A.A., and Kannikin, S.V., Hydrogen permeability of thin condensed Pd–Cu foil: dependence on temperature and phase composition, J. Tech. Phys., 2016, vol. 61, no. 3, pp. 467–469.
Ievlev, V.M., Solntsev, K.A., Serbin, O.V., Dontsov, A.I., Sinetskaya, D.A., and Roshan, N.R., The effect of rapid photon treatment of the PdCu solid solution foil of near-equiatomic composition, Dokl. Chem., 2019, vol. 489, no. 1, pp. 275–278.
Funding
This work was supported by the Russian Science Foundation, project no. 19-19-00232.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Tsarev
Rights and permissions
About this article
Cite this article
Ievlev, V.M., Dontsov, A.I., Kannykin, S.V. et al. Thermal Expansion Coefficient of a Pd–Cu Solid Solution. Inorg Mater 56, 1225–1228 (2020). https://doi.org/10.1134/S0020168520120067
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168520120067