Log in

Synthesis and Luminescence of Sr1– x – yYbxEuyF2+ x + y Solid Solutions for Photonics

  • Published:
Inorganic Materials Aims and scope

Abstract—

Single-phase Sr1– x – yYbxEuyF2+ x + y solid solutions with an average particle size near 90 nm have been synthesized via co-precipitation from aqueous solutions, followed by high-temperature annealing. Efficient Yb3+ luminescence was observed upon excitation at a wavelength of 266 nm. The highest external quantum yield of ytterbium luminescence (2.5%) under pum** at a wavelength of 266 nm was reached for the SrF2:Yb(1.0 mol %),Eu(0.05 mol %) composition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Weber, E.R., Photovoltaics moving into the terawatt age, Proc. SPIE—Int. Soc. Opt. Eng., 2017, vol. 10368, paper 1 036 803. https://doi.org/10.1117/12.2277978

  2. Han, G., Zhang, S., Boix, P.P., Wong, L.H., Sun, L., and Lien, S.-Y., Towards high efficiency thin film solar cells, Prog. Mater. Sci., 2017, vol. 87, pp. 246–291. https://doi.org/10.1016/j.pmatsci.2017.02.003

    Article  CAS  Google Scholar 

  3. Huang, X., Han, S., Huang, W., and Liu, X., Enhancing solar cell efficiency: the search for luminescent materials as spectral converters, Chem. Soc. Rev., 2013, vol. 42, pp. 173–201. https://doi.org/10.1039/C2CS35288E

    Article  CAS  PubMed  Google Scholar 

  4. Fischer, S., Ivaturi, A., Jakob, P., Krämer, K.W., Martin-Rodriguez, R., Meijerink, A., Richards, B., and Goldschmidt, J.Ch., Upconversion solar cell measurements under real sunlight, Opt. Mater., 2018, vol. 84, pp. 389–395.

    Article  CAS  Google Scholar 

  5. Kuznetsov, S., Ermakova, Yu., Voronov, V., Fedorov, P., Busko, D., Howard, I.A., Richards, B.S., and Turshatov, A., Up-conversion quantum yield of SrF2:Yb3+,Er3+ sub-micron particles prepared by precipitation from aqueous solution, J. Mater. Chem. C, 2018, vol. 6, pp. 598–604. https://doi.org/10.1039/c7tc04913g

    Article  CAS  Google Scholar 

  6. Green, M.A. and Bremner, S.P., Energy conversion approaches and materials for high-efficiency photovoltaics, Nat. Mater., 2016, vol. 16, no. 1, pp. 23–34.

    Article  PubMed  Google Scholar 

  7. Im, J.-H., Lee, C.-R., Lee, J.-W., Park, S.-W., and Park, N.-G., 6.5% Efficient perovskite quantum-dot-sensitized solar cell, Nanoscale, 2011, vol. 3, no. 10, pp. 4088–4093.

    Article  CAS  PubMed  Google Scholar 

  8. Trupke, T., Green, M.A., and Würfel, P., Improving solar cell efficiencies by down-conversion of high-energy photons, J. Appl. Phys., 2002, vol. 92, no. 3, pp. 1668–1674.

    Article  CAS  Google Scholar 

  9. Yu, P., Yao, Y., Wu, J., Niu, X., Rogach, A.L., and Wang, Z., Effects of plasmonic metal core–dielectric shell nanoparticles on the broadband light absorption enhancement in thin film solar cells, Sci. Rep., 2017, vol. 7, no. 1, paper 7696.

  10. Fang, D., Zhang, X., Zhao, C., Liu, X., Shu, X., and Wang, J., Application of bidirectional (up and down)-conversion luminescence material (GdBO3:Yb3+/Tb3+) in CdSe0.4S0.6 quantum dot-sensitized solar cells, Opt. Mater., 2019, vol. 88, pp. 80–90 .

    Article  CAS  Google Scholar 

  11. Gu, H., Wang, J., Li, Y., Wang, Z., and Fu, Y., The core–shell-structured NaYF4:Er3+,Yb3+@NaYF4:Eu3+ nanocrystals as dual-mode and multifunctional luminescent mechanism for high-performance dye-sensitized solar cells, Mater. Res. Bull., 2018, vol. 108, pp. 219–225.

    Article  CAS  Google Scholar 

  12. Buarque, J.M.M., Manzani, D., Scarpari, S.L., Nalin, M., Ribeiro, S.J.L., Esbenshade, J., Schiavon, M.A., and Ferrari, J.L., SiO2–TiO2 doped with Er3+/Yb3+/Eu3+ photoluminescent material: a spectroscopy and structural study about potential application for improvement of the efficiency on solar cells, Mater. Res. Bull., 2018, vol. 107, pp. 295–307.

    Article  CAS  Google Scholar 

  13. Rajesh, D., Dousti, M.R., Amjad, R.J., and de Camargo, A.S.S., Quantum cutting and up-conversion investigations in Pr3+/Yb3+ co-doped oxyfluoro-tellurite glasses, J. Non-Cryst. Solids, 2016, vol. 450, pp. 149–155.

    Article  CAS  Google Scholar 

  14. Balabhadra, S., Debasu, M.L., Brites, C.D.S., Ferreira, R.A.S., and Carlos, L.D., A cost-effective quantum yield measurement setup for upconverting nanoparticles, J. Lumin., 2017, vol. 189, pp. 64–70.

    Article  CAS  Google Scholar 

  15. Kuznetsov, S.V., Proydakova, V.Yu., Morozov, O.A., Gorieva, V.G., Marisov, M.A., Voronov, V.V., Yapryntsev, A.D., Ivanov, V.K., Nizamutdinov, A.S., Semashko, V.V., and Fedorov, P.P., Synthesis and quantum yield investigations of the Sr1 – x – yPrxYbyF2 + x + y luminophores for photonics, Nanosystems: Phys., Chem., Math., 2018, vol. 9, no. 5, pp. 663–668. https://doi.org/10.17586/22208054201895663668

    Article  Google Scholar 

  16. Rozhnova, Yu.A., Luginina, A.A., Voronov, V.V., Ermakov, R.P., Kuznetsov, S.V., Ryabova, A.V., Pominova, D.V., Arbenina, V.V., Osiko, V.V., and Fedorov, P.P., White light luminophores based on Yb3+/Er3+/Tm3+-coactivated strontium fluoride powders, Mater. Chem. Phys., 2014, vol. 148, pp. 201–207.

    Article  CAS  Google Scholar 

  17. Fedorov, P.P., Kuznetsov, S.V., Mayakova, M.N., Voronov, V.V., Ermakov, R.P., Baranchikov, A.E., and Osiko, V.V. Coprecipitation from aqueous solutions to prepare binary fluorides, Russ. J. Inorg. Chem., 2011, vol. 56, no. 10, pp. 1525–1531.

    Article  CAS  Google Scholar 

  18. Mayakova, M.N., Luginina, A.A., Kuznetsov, S.V., Voronov, V.V., Ermakov, R.P., Baranchikov, A.E., Ivanov, V.K., Karban’, O.V., and Fedorov, P.P., Synthesis of SrF2–YF3 nanopowders by co-precipitation from aqueous solutions, Mendeleev Commun., 2014, vol. 24, no. 6, pp. 360–362.

    Article  CAS  Google Scholar 

  19. Yasyrkina, D.S., Kuznetsov, S.V., Ryabova, A.V., Pominova, D.V., Voronov, V.V., Ermakov, R.P., and Fedorov, P.P., Dependence of quantum yield of up-conversion luminescence on the composition of fluorite-type solid solution NaY1 – x – yYbxEryF4, Nanosystems: Phys., Chem., Math., 2013, vol. 4, no. 5, pp. 648–656.

    CAS  Google Scholar 

  20. Fedorov, P.P. and Sobolev, B.P., Concentration dependence of parameters of elementary nuclei of M1 – xRxF2 + x phases with the fluorite structure, Kristallografiya, 1992, vol. 37, no. 5, pp. 651–656.

  21. Chen, X.P., Huang, X.Y., and Zhang, Q.Y., Concentration-Dependent Near-Infrared Quantum Cutting in NaYF4:Pr3+,Yb3+ Phosphor, J. Appl. Phys., 2009, vol. 106, paper 063 518. https://doi.org/10.1063/1.3224906

  22. Binnemans, K., A comparative spectroscopic study of Eu3+ in crystalline host matrices, Bull. Soc. Chim. Belg., 1996, vol. 105, no. 12, pp. 793–798.

    CAS  Google Scholar 

  23. Gruber, J.B., Valiev, U.V., Burdick, G.W., Rakhimov, Sh.A., Pokhrel, M., and Sardar, D.K., Spectra, Energy Levels, and Symmetry Assignments for Stark Components of Eu3+(4 F 6) in Gadolinium Gallium Garnet (Gd3Ga5O12), J. Lumin., 2011, vol. 131, no. 9, pp. 1945–1952.

    Article  CAS  Google Scholar 

  24. Qiao, X., Tsuboi, T., and Seo, H.J., Correlation among the cooperative luminescence, cooperative energy transferred Eu3+-emission, and near-infrared Yb3+ emission of Eu3+-doped LiYb(MoO4)2, J. Alloys Compd., 2016, vol. 687, pp. 179–187.

    Article  CAS  Google Scholar 

  25. Yu, P., Wang, W., Zhou, L., Xu, H., **a, Q., Liu, Li., Liu, X., and Li, L., F–Eu3+ charge transfer energy and local crystal environment in Eu3+ doped calcium fluoride, Ceram. Int., 2017, vol. 43, pp. 13089–13093.

    Article  Google Scholar 

  26. Van der Voort, D., Dirksen, G.J., and Blasse, G., Luminescence study of Eu3+–O2– associates in fluorides: CaF2, RbCdF3, and RbCaF3, J. Phys. Chem. Solids, 1992, vol. 53, no. 2, pp. 219–225.

    Article  CAS  Google Scholar 

  27. Johnston, M.V. and Wright, J.C., Trace analysis of nonfluorescent ions by associative clustering with a fluorescent probe, Anal. Chem., 1979, vol. 51, no. 11, pp. 1774–1780.

    Article  CAS  Google Scholar 

  28. Kuznetsov, S.V., Morozov, O.A., Gorieva, V.G., Mayakova, M.N., Marisov, M.A., Voronov, V.V., Yapryntsev, A.D., Ivanov, V.K., Nizamutdinov, A.S., Semashko, V.V., and Fedorov, P.P., Synthesis and luminescence studies of CaF2:Yb:Pr solid solutions powders for photonics, J. Fluorine Chem., 2018, vol. 211, pp. 70–75.

    Article  CAS  Google Scholar 

  29. Wei, X., Zhao, J., Zhang, W., Li, Y., and Yin, M., Cooperative energy transfer in Eu3+, Yb3+ codoped Y2O3 phosphor, J. Rare Earths, 2010, vol. 28, no. 2, pp. 166–170.

    Article  CAS  Google Scholar 

  30. Maciel, G.S., Biswas, A., and Prasad, P.N., Infrared-to-visible Eu3+ energy upconversion due to cooperative energy transfer from an Yb3+ ion pair in a sol–gel processed multi-component silica glass, Opt. Commun., 2000, vol. 178, pp. 65–69.

    Article  CAS  Google Scholar 

  31. Vilejshikova, E.V., Loiko, P.A., Rachkovskaya, G.E., Zakharevich, G.B., and Yumashev, K.V., Spectral and luminescent properties of oxyfluoride glasses codoped with (Yb3+, Eu3+) and (Yb3+, Tb3+), J. Appl. Spectrosc., 2016, vol. 83, no. 4, pp. 548–554.

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Russian Science Foundation, grant no. 17-73-20352.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. V. Kuznetsov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kuznetsov, S.V., Nizamutdinov, A.S., Proydakova, V.Y. et al. Synthesis and Luminescence of Sr1– x – yYbxEuyF2+ x + y Solid Solutions for Photonics. Inorg Mater 55, 1031–1038 (2019). https://doi.org/10.1134/S002016851910008X

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002016851910008X

Keywords:

Navigation