Abstract
Changes in the molecular-weight distributions of low-molecular-weight and alkali cellulose after the processes of γ-irradiation and mercerization of cellulose have been studied. The features of the dissolution of irradiated cellulose in an alkaline solution during mercerization have been revealed. It has found that the alkali cellulose produced from the irradiated polymer has increased homogeneity of the molecular-weight distribution. The γ-irradiation of cellulose before mercerization leads to an increase in the reactivity of the polymer in the xanthogenation reaction by 30–50%. An optimum range of absorbed doses for the radiation pretreatment of cellulose prior to a viscose production process has been determined.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018143919010065/MediaObjects/10733_2019_8024_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018143919010065/MediaObjects/10733_2019_8024_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018143919010065/MediaObjects/10733_2019_8024_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS0018143919010065/MediaObjects/10733_2019_8024_Fig4_HTML.gif)
Similar content being viewed by others
REFERENCES
Ershov, B.G., Usp. Khim., 1998, vol. 68, no. 4, p. 353.
Komarov, V.B., Samuilova, S.D., Kirsanova, L.S., Morozov, V.A., Kuleshova, T.M., Smirnov, A.G., and Ershov, B.G., Zh. Prikl. Khim., 1993, vol. 66, no. 2, p. 393.
Nikitin, V.M., Obolenskaya, A.V., Shchegolev, V.P., Akim, G.L., and Akim, E.L., Prakticheskie raboty po khimii drevesiny i tsellyulozy (Laboratory Works on Wood and Cellulose Chemistry), Nikitin, V.M., Ed., Moscow: Lesnaya Promyshlennost’, 1965.
Rogovin, Z.A., Osnovy khimii i tekhnologii khimicheskikh volokon (Fundamentals of Chemistry and Technology of Chemical Fibers), Moscow: Khimiya, 1974, vol. 1.
Nikitin, V.M., Obolenskaya, A.V., and Shchegolev, V.P., Khimiya drevesiny i tsellyulozy (Chemistry of Wood and Cellulose), Moscow: Lesnaya Promyshlennost’, 1978.
Matukhin, E.L, Valishina, Z.T., Garifzyanov, G.G., Grigorenko, A.A., and Nusinovich, D.S., Abstracts of Papers, Vsesoyuznaya konferentsiya Khimiya i reaktsionnaya sposobnost' tsellyulozy i ee proizvodnykh (Kinetika i mekhanizm) (All-Union Conference on Chemistry and Reactivity of Cellulose and Its Derivatives (Kinetics and Mechanism), Chernogolovka: Institut khimicheskoi fiziki, 1991, p. 124.
Belasheva, T.P., Butkova, N.T., Gorskaya, A.P., Dibrova, A.K., Ioffe, A.Z., Kozelkina, Z.V., Matveev, V.S., Mironov, Yu.G., Nosolyuk, G.N., Panova, L.N., Primkulov, M.T., Tokareva, L.G., Kharitonova, I.M., Chamaev, V.N., Shimko, I.G., and Yartseva, N.G., Analiticheskii kontrol' proizvodstva iskusstvennykh volokon (Analytical Control in Production of Manmade Fibers), Dibrova, A.K. and Matveev, V.S., Eds., Moscow: Khimiya, 1986.
Kostikova, E.B., Mogilevskii, E.M., and Ginzburg, M.A., Khim. Volokna, 1968, no. 6, p. 31.
Bolotnikova, L.S., Danilov, S.N., and Samsonova, T.I., Zh. Prikl. Khim., 1964, vol. 6, p. 176.
Shatenshtein, A.I., Vyrskii, Yu.P., Pravikova, N.A., Alikhanov, P.P., Zhdanova, K.I., and Izyumni-kov, A.L., Prakticheskoe rukovodstvo po opredeleniyu molekulyarnykh vesov i molekulyarno-vesovogo raspredeleniya polimerov (Practical Guide to Determination of Molecular Weights and Molecular-Weight Distributions for Polymers), Moscow: Khimiya, 1964.
Grassie, N., Chemistry of High Polymer Degradation Processes, London: Butterworths, 1956.
Sobolev, S.E. and Nikitin, V.M., Khim. Drev., 1977, no. 3, p. 74.
Bykova, T.O., A liquid-chromatography study of molecular-mass and chemical inhomogeneity of nitrates of technical-grade wood celluloses, Extended Abstract of Cand. Sci. (Chem.) Dissertation, Riga, Inst. of Wood Chemistry, 1991.
Mal’chevskii, V.A., Babekina, L.Z., Shcherbakov, A.I., Ershov, B.G., Samuilova, S.D., and Komarov, V.B., Materialy 1 Vsesoyuznoi konferentsii “Khimiya i reaktsionnaya sposobnost' tsellyulozy i ee proizvodnykh” (Proceedings of the 1st All-Union Conference on Chemistry and Reactivitry of Cellulose and Its Derivatives), Frunze: Ilim, 1991, p. 85.
Fischer, K., Goldberg, W., and Wilke, M., Lenzinger Ber., 1985, vol. 59, p. 33.
Eremeeva, T.E., Bykova, T.O., Ershov, B.G., and Komarov, V.B., Abstracts of Papers, 6 Vsesoyuznaya konferentsiya po khimii i fizike tsellyulozy (The 6th All-Union Conference on Cellulose Chemistry and Physics), Minsk: Institut fiziki im. B.I. Stepanova AN BSSR, 1990, p. 195.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by V. Makhlyarchuk
Rights and permissions
About this article
Cite this article
Komarov, V.B., Seliverstov, A.F., Lagunova, Y.O. et al. Changes in the Physicochemical Characteristics of Cellulose upon Its γ-Irradiation and the Subsequent Mercerization. High Energy Chem 53, 66–70 (2019). https://doi.org/10.1134/S0018143919010065
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0018143919010065