Log in

Geochemistry of Hydrocarbons-Biomarkers and Carbon Isotopes of Organic Matter in the Domanik Deposits of the Timan–Pechora Basin

  • Published:
Geochemistry International Aims and scope Submit manuscript

Abstract—It has been established that the average values of some hydrocarbons biomarker coefficients of bitumens from the Domanik deposits and oils from the Domanik–Tournaisian complex coincide. These are the proportions of C27–C29 steranes, tri-/pentacyclanes ratio, and coefficients 2 × С1716 + С18 and 2 × С2726 + С28 calculated from n-alkane composition. Such indicators as the Pr/Ph, (Pr + Ph)/(n‑C17 + n‑C18), dia-/reg-steranes, and the sterane/hopane ratios in oils are slightly lower than in the bitumen. The average values of δ13C in asphaltene, resin, aromatic hydrocarbons, and aliphatic hydrocarbons fractions from oils of the Domanik genotype and in the studied bitumens are similar. The carbon isotope composition of asphaltenes in oils is depleted in 13С compared to those of resins and aromatic hydrocarbons, and vice versa in bitumens. A heterogeneous composition of the bacterial flora in the sediments of the Domanik Sea is suggested. In some places, species with high concentrations of diplopterol or hexafunctional bacteriohopanes likely dominated over bacteriohopantetrol.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

REFERENCES

  1. L. A. Anishchenko, S. A. Danilevskii, Yu. M. Trifachev, et al., Report on the Study of Geochemical Tendencies in the Distribution of Large Oil Windows in the Timan–Pechora Province (TPO VNIGRI, Ukhta, 1984) [in Russian].

  2. T. K. Bazhenova, V. K. Shimanskii, V. F. Vasileva, A. I. Shapiro, L. A. Yakovleva, and L. I. Klimova, Organic Geochemistry of the Timan–Pechora Basin (VNIGRI, St. Petersburg, 2008) [in Russian].

    Google Scholar 

  3. N. S. Burdelnaya and D. A. Bushnev, “A new indicator of the maturity of organic matter from Domanik deposits,” Russ. Geol. Geophys. 62 (2), 149–156 (2021).

    Article  Google Scholar 

  4. D. A. Bushnev, “The composition of biomarkers in bitumen and pyrolysis products of kerogen from the Pechora–Basin Upper Devonian deposits,” Petrol. Chem. 42 (5), 291–305 (2002).

    Google Scholar 

  5. D. A. Bushnev, “Organic matter of the Ukhta Domanik,” Dokl. Earth Sci. 426 (4), 677–680 (2009).

    Article  Google Scholar 

  6. D. A. Bushnev and N. S. Burdelnaya, “Modeling of oil generation by Domanik carbonaceous shale,” Petrol. Chem. 53 (3), 145–151 (2013).

    Article  Google Scholar 

  7. D. A. Bushnev and N. S. Burdelnaya, “Crude oils and organic matter of Late Devonian deposits of the Timan–Pechora Basin: comparison by molecular and isotopic data,” Petrol. Chem. 55 (5), 522–529 (2015).

    Article  Google Scholar 

  8. D. A. Bushnev, N. S. Burdel’naya, and A. V. Zhuravlev, “Organic matter in Upper Devonian deposits of the Chernyshev Ridge,” Geochem. Int. 55 (6), 548–558 (2017a).

    Article  Google Scholar 

  9. D. A. Bushnev, N. S. Burdelnaya, O. V. Valyaeva, and A. A. Derevesnikova, “Geochemistry of Late Devonan oils of the Timan–Pechora Basin,” Russ. Geol. Geophys. 58 (3–4), 332–342 (2017b).

    Article  Google Scholar 

  10. D. A. Bushnev, N. S. Burdelnaya, A. N. Shadrin, N. P. Fadeeva, and M. B. Smirnov, “Organic matter of Domanik deposits of the Timan-Pechora basin: the oil window conditions,” Russ. Geol. Geophys. 62 (8), 859–865 (2021).

    Article  Google Scholar 

  11. J. Connan and A. M. Cassow, “Properties of gases and liquids derived from terristrial kerogen at various maturation levels,” Geochim. Cosmochim. Acta 44 (1), 1–23 (1980).

    Article  Google Scholar 

  12. J. Connan, J. Bouroullec, D. Dessort, and P. Albrecht, “The microbial input in carbonate-anhydrite facies of a sabkha palaeoenviroment from Guatemala: a molecular approach,” Org. Geochem. 10, 29–50 (1986).

    Article  Google Scholar 

  13. S. A. Danilevskii, Z. P. Sklyarova, and Yu. M. Trifachev, Geofluid Systems of the Timano–Pechora Province. Atlas (Ukhta, 2001).

    Google Scholar 

  14. P. Farrimond and N. Telnæs, “Three series of rearranged hopanes in Toarcian sediments (northern Italy),” Org. Geochem. 25 (3/4), 165–177 (1996).

    Article  Google Scholar 

  15. P. Farrimond, I. M. Head, and H. E. Innes, “Environmental influence on the biohopanoid composition of recent sediments,” Geochim. Cosmochim. Acta. 64 (17), 2985–2992 (2000).

    Article  Google Scholar 

  16. E. M. Galimov, “Isotope organic geochemistry,” Org. Geochem. 37, 1200–1260 (2006).

    Article  Google Scholar 

  17. E. M. Galimov and M. G. Frik, “Isotope method of diagnostics of oil-source deposits,” Geokhimiya, No. 10, 1474–1484 (1985).

    Google Scholar 

  18. A. N. Guseva and T. A. Kiryukhina, “Distribution and Conditions of formation of heavy oils of the Timan–Pechora petroleum basin,” Distribution and Conditions of Formation of Heavy and Sulfur Crude Oil (Nauka, Moscow, 1985), pp. 83–89 [in Russian].

    Google Scholar 

  19. S. Hanisch, D. Ariztegui, and W. Püttmann, “The biomarker record of Lake Albano, central Italy–implications for Holocene aquatic system response to environmental change,” Org. Geochem. 34, 1223–1235 (2003).

    Article  Google Scholar 

  20. W.-Y. Huang and W. G. Meinschein, “Sterols as ecological indicators,” Geochim. Cosmochim. Acta. 43, 739–745 (1979).

    Article  Google Scholar 

  21. A. I. Kamaleeva, L. A. Kodina, L. N. Vlasova, M. P. Bogacheva, and E. M. Galimov, “Anomalous” oils of Tatarstan: genetic correlations and possible origin,” Dokl. Earth Sci. 458 (1), 1132–1135 (2014).

    Article  Google Scholar 

  22. T. A. Kiryukhina, “Oil types of the Timan–Pechora Basin,” Vestn. Mosk. Univ. Ser. 4. Geol., No. 2, 39–49 (1995).

  23. T. A. Kiryukhina, N. P. Fadeeva, A. V. Stupakova, E. N. Poludetkina, and R. S. Sautkin, “Domanik deposits of the Timan–Pechora and Volga–Ural basins,” Geol. Nefti Gaza, No. 3, 76–87 (2013).

    Google Scholar 

  24. T. A. Kiryukhina, M. A. Bolshakova, A. V. Stupakova, N. I. Korobkova, N. V. Pronina, R. S. Sautkin, A. A. Suslova, et al., “Litological-geochemical characteristics of the Domanik deposits of the Timan–Pechora Basin,” Georesursy 2 (61), 87–100 (2015).

    Article  Google Scholar 

  25. M. P. Koopmans, W. Irene C. Rijpstra, J. W. de Leeuw, and M. D. Lewan, and J. S. Sinninghe Damste, “Artificial maturation of an immature sulfur- and organic matter-rich limestone from the Ghareb Formation, Jordan,” Org. Geochem. 28 (7–8), 503–521 (1998).

    Article  Google Scholar 

  26. I. S. Kotik, O. V. Valyaeva, D. A. Bushnev, and A. V. Zhuravlev, “Geochemistry of organic matter of the Domanik deposits of the Pyvmashor River, Chernyshev Swell Range (Timan–Pechora Basin),” Vestn. IG Komi NTs UrO RAN, No. 9, 10–16 (2019).

    Google Scholar 

  27. I. S. Kotik, A. V. Zhuravlev, T. V. Maydl, D. A. Bushnev, and I. V. Smoleva, “Early–Middle Frasnian (Late Devonian) carbon isotope event in the Timan–Pechora Basin (Chernyshev Swell, Pymvashor River section, North Cis-Urals, Russia),” Geologica Acta 19, 1–17 (2021).

    Article  Google Scholar 

  28. J. M. Moldowan, W. K. Siefert, and E. J. Gallegos, “Relationship between petroleum composition and depositional environment of petroleum source rocks,” Am. Ass. Petrol. Geol. Bull. 69, 1255–1268 (1985).

    Google Scholar 

  29. J. M. Moldowan, F. J. Fago, R. M.K. Carlson, D. C. Young, Duyne G. Van, J. Clardy, M. Schoell, C. T. Pillinger, and D. S. Watts, “Rearranged hopanes in sediments and petroleum,” Geochim. Cosmochim. Acta 55, 3333–3353 (1991).

    Article  Google Scholar 

  30. S. G. Neruchev, E. A. Rogozina, G. M. Parparova, et al., “Petroleum Generation in the Domanik-Type Deposits,” Ed. by S. G. Nerucheva (Nedra, Moscow, 1986) [in Russian].

    Google Scholar 

  31. K. E. Peters and J. M. Moldowan, The Biomarker Guide. Interpreting Molecular fossils in Petroleum and Ancient Sediments (Prentice–Hall, 1993).

    Google Scholar 

  32. K. E. Peters, C. W. Walters, and J. M. Moldowan, The Biomarker Guide (Cambridge University Press, Cambridge, 2005).

    Google Scholar 

  33. O. M. Prishchepa, T. K. Bazhenova, and V. I. Bogatskii, “Petroleum systems of the Timan–Pechora sedimentary basin (including the offshore Pechora Sea),” Russ. Geol. Geophys. 52 (8), 885–905 (2011).

    Google Scholar 

  34. M. Rohmer, P. Bouvier-Navez, and G. Ourisson, “Distribution of hopanoid triterpenes in prokaryotes,” J. General Microbiol. 130, 1137–1150 (1984).

    Google Scholar 

  35. I. A. Sannikova, M. A. Bolshakova, A. V. Stupakova, R. S. Sautkin, A. A. Suslova, and E. V. Kozlova, “Modeling of generation scales of the hydrocarbon fluids of the Domanik oil-source sequences of the Timan–Pechora Basin using different kinetic spectra of destruction of organic matter,” Geores. Sp. Issue, No. 1, 65–79 (2017).

    Google Scholar 

  36. W. K. Siefert and J. M. Moldowan, “Applications of steranes, terpanes and monoaromatics to the maturation, migration and source of crude oils,” Geochim. Cosmochim. Acta. 42, 77–95 (1978).

    Article  Google Scholar 

  37. O. Sieskind, G. Joly, and P. Albrecht, “Simulation of the geochemical transformations of sterols: superacid effect of clay minerals,” Geochim. Cosmochim. Acta 43, 1675–1679 (1979).

    Article  Google Scholar 

  38. G. W. Van Graas, “Biomarker maturity parameters for high maturities: calibration of the working range up to the oil/condensate threshold,” Org. Geochem. 16, 1025–1032 (1990).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to D. A. Bushnev, N. S. Burdelnaya or M. A. Bolshakova.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by M. Bogina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bushnev, D.A., Burdelnaya, N.S. & Bolshakova, M.A. Geochemistry of Hydrocarbons-Biomarkers and Carbon Isotopes of Organic Matter in the Domanik Deposits of the Timan–Pechora Basin. Geochem. Int. 61, 127–136 (2023). https://doi.org/10.1134/S0016702923020039

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0016702923020039

Keywords:

Navigation