References
Minerals (A Reference Book), Simple Oxides (Nauka, Moscow, 1965), Vol. II [in Russian].
L. Wohler and N. Jochum, “Thermochemische Messungen An Den Oxyden Des Kupfers, Rhodiums, Palladiums and Iridiums,” Z. Phys. Chem., No. 167, 167–179 (1935).
I. Barin, O. Knacke, and O. Kubaschewski, Thermochemical Properties of Inorganic Substances (Springer-Verlag, 1977).
D. C. Sassani and E. L. Shock, “Solubility and Transport of Platinum-Group Elements in Supercritical Fluids: Summary and Estimates of Thermodynamic Properties for Ruthenium, Rhodium, Palladium, and Platinum Solids, Aqueous Ions and Complexes to 1000°C and 5 Kbar,” Geochim. Cosmochim. Acta, 62, 2643–2671 (1998).
K. K. Kelley, “Contributions to the Data on Theoretical Metallurgy. XIII. High Temperature Heat Content, Heat Capacity, and Entropy Data for the Elements and Inorganic Compounds,” U.S. Bur. Mines Bull., No. 584, 232 (1960).
J. Nell and H. St. C. O’Neill, “Gibbs Free Energy of Formation and Heat Capacity of PdO: A New Calibration of the Pd-PdO Buffer To High Temperatures and Pressures,” Geochim. Cosmochim. Acta 60(14), 2487–2493 (1996).
I. L. Khodakovskii, N. A. Polotnyanko, and A. V. Kristavchuk, “Thermodynamic Properties of Pd2+(aq), RdO(c), and Pd(OH)2(am) at 25°C,” Vestn Otd. Nauk Zemle (Electron. Nauchn.-Inform. Zh. Ross. Akad. Nauk, 2007, No. 1 (2005).
V. M. Malyshev, G. A. Mil’ner, E. L. Sorkin, and V. F. Shibakin, “Automated Low-Pressure Calorimeter,” Prib. Tekh. Eksp. 6, 195 (1985).
N. N. Smirnova, T. A. Bykova, N. A. Polotnyanko, et al., “Low-Temperature Heat Capacity and Standard Entropy of PdO(cr.),” in Zh. Fiz. Khim. 84(11), 2030–2035 (2010) [Russ. J. Phys. Chem. A. 84 (11), 1851–1855 (2010)].
Thermal Constants of Substances, Ed. by V. P. Glushko (AN SSSR, Moscow, 1972) [in Russian].
W. Zachariasen, “Uber Die Kristallstruktur Des Palladiumoxyds (PdO),” Z. Phys. Chem., No. 128, 412–416 (1927).
W. J. Moore and L. Pauling, “The Crystal Structures of the Tetragonal Monoxides of Lead, Tin, Palladium and Platinum,” J. Am. Chem. Soc. 63(5), 1392–1394 (1941).
J. Waser, “The Structure of PdO,” Acta Crystallogr. 6, 661–663 (1953).
O. Glemser and G. Peuschel, “Beitrag Zur Kenntins Des Systems PdO/H2O,” Z. Anorg. Chem. 281, 44–53 (1955).
W. M. Latimer, Oxidation Potentials (Prentice-Hall, 1952).
G. B. Naumov, B. N. Ryzhenko, and I. L. Khodakovskii, A Reference Book on Thermodynamic Values (Moscow, 1971) [in Russian].
L. B. Pankratz, “Thermodynamic Properties of Elements and Oxides,” U.S. Bur. Mines Bull., No. 672, 509 (1982).
H. Kleykamp, “Freie Bildungsenthalpie Von Palladiumoxid,” Z. Physik. Chem. (Frankfurt), No. 71, 142–148 (1970).
J. Fouletier, G. Vitter, and M. Kleitz, “Measurement and Regulation of Oxygen Content in Gases Using Solid Electrolyte Cells,” J. Appl. Electrochem. 5, 111 (1975).
V. A. Levitskii, P. B. Narchuk, M. L. Kovba, and Yu. Ya. Skolis, “Solid Electrolytes in Thermodynamic Studies. Thermodynamic Properties of PdO,” Zh. Fiz. Khim. 56(10), 2405–2411 (1982).
H. J. De Bruin and S. P. S. Badwal, “Free Energy of Formation of PdO by Impedance Dispersion Analysis,” J. Solid State Chem. 34, 133–135 (1980).
C. Mallika, O. M. Sreedharan, and J. B. Granamoorthy, “Determination of the Standard Free Energy of Formation of PdO(s) from the Solid Oxide Electrolyte E.M.F.,” J. Less-Common Met. 95(2), 213–220 (1983).
N. G. Schmahl and E. Minzl, “Die Untersuchung Der (CuO, PdO)-Mischkristallbildung Und Ihre Beteiligung An Den Gleichwichten Des Systems Cu-Pd-O,” Z. Physik. Chem. (Frankfurt), 34, 142–163 (1965).
W. E. Bell, R. E. Inyard, and M. Tagami, “Dissociation of Palladium Oxide,” J. Phys. Chem. 70(11), 3735–3736 (1966).
J. S. Warner, “The Free Energy of Formation of Palladium Oxide,” J. Electrochem. Soc. 114(1), 68–71 (1967).
G. Bajer and H. G. Wiedemann, “Formation, Dissociation and Expansion Behavior of Platinum Group Metal Oxides (PdO, RuO2, IrO2),” Thermochim. Acta 11(1), 79 (1975).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © I.L. Khodakovskii, N.N. Smirnova, T.A. Bykova, N.A. Polotnyanko, A.V. Kristavchuk, N.D. Shikina, O.V. Karimova, A.V. Mokhov, V.A. Volchenkova, 2011, published in Geokhimiya, 2011, Vol. 49, No. 5, pp. 550–555.
Rights and permissions
About this article
Cite this article
Khodakovskii, I.L., Smirnova, N.N., Bykova, T.A. et al. High-temperature heat capacity of palladinite PdO(c). Geochem. Int. 49, 525–530 (2011). https://doi.org/10.1134/S0016702911050053
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0016702911050053