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Neutron diffraction study of phase transitions in the superionic conductor Li0.25Cu1.75Se

  • Lattice Dynamics and Phase Transitions
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Abstract

Neutron diffraction studies of the superionic conductor Li0.25Cu1.75Se are reported. It is shown that gradual disordering in the cation sublattice with an increase in temperature leads to changes in the symmetry of the crystal lattice at 400 and 500 K. At temperatures close to these values, anomalies in the temperature dependence of both ionic and electron conductivity are observed.

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Authors and Affiliations

  1. Sterlitamak State Pedagogical Institute, Sterlitamak, pr. Lenina 49, 453103, Bashkortostan, Russia

    N. N. Bikkulova & G. N. Asylguzhina

  2. Hahn-Meitner-Institut, SF2, Glienicker Str. 100, Berlin, D-14109, Germany

    S. A. Danilkin

  3. Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, ul. Joliot-Curie, Dubna, Moscow oblast, 141980, Russia

    A. I. Beskrovnyi & E. L. Yadrovskii

  4. Institute of Physics and Power Engineering, pl. Bondarenko 1, Obninsk, Kaluzhskaya oblast, 249020, Russia

    V. A. Semenov

  5. Bashkortostan State University, ul. Frunze 32, Ufa, 450074 Bashkortostan, Russia

    G. N. Asylguzhina, M. Kh. Balapanov, M. B. Sagdatkireeva & U. Kh. Mukhamed’yanov

Authors
  1. N. N. Bikkulova
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  2. S. A. Danilkin
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  3. A. I. Beskrovnyi
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  4. E. L. Yadrovskii
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  5. V. A. Semenov
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  6. G. N. Asylguzhina
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  7. M. Kh. Balapanov
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  8. M. B. Sagdatkireeva
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  9. U. Kh. Mukhamed’yanov
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__________

Translated from Kristallografiya, Vol. 48, No. 3, 2003, pp. 502–505. p ]Original Russian Text Copyright © 2003 by Bikkulova, Danilkin, Beskrovny\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \), Yadrovski\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \), Semenov, Asylguzhina, Balapanov, Sagdatkireeva, Mukhamed’yanov.

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Bikkulova, N.N., Danilkin, S.A., Beskrovnyi, A.I. et al. Neutron diffraction study of phase transitions in the superionic conductor Li0.25Cu1.75Se. Crystallogr. Rep. 48, 457–460 (2003). https://doi.org/10.1134/1.1578131

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  • DOI: https://doi.org/10.1134/1.1578131

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