Abstract
PARTITION and adsorption chromatography can be successfully applied for separation of mixtures of substances which differ in type and number of functional groups, or for separation of members of a homologous series. Less success was attained in separation of isomers. We therefore sought for a process which would be selective as regards the shape and size rather than the chemical properties of molecules.
Similar content being viewed by others
References
Powell, H. M., J. Chem. Soc., 61 (1948).
Kramer, F. D., Rev. Pure App. Chem., 5, 143 (1955).
Hofman, K. A., Z. anorg. Chem., 15, 204 (1897).
Powell, H. M., and Rayner, J. H., Nature, 163, 566 (1949).
Schaeffer, W. D., Dorsey, W. S., Skinner, D. A., and Christian, C. G., J. Amer. Chem. Soc., 71, 5870 (1957).
Kemula, W., Roczniki Chemii, 26, 261 (1952); Przemysl Chem., 33, 453 (1954).
Kemula, W., and Sybilska, D., Chemia Anal. (Warsaw), 4, 123 (1959).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
KEMULA, W., SYBILSKA, D. Clathrate Compounds in Chromatography. Nature 185, 237–238 (1960). https://doi.org/10.1038/185237b0
Issue Date:
DOI: https://doi.org/10.1038/185237b0
- Springer Nature Limited
This article is cited by
-
Stoichiometry of clathrates
Journal of Structural Chemistry (1995)
-
Peculiarities of the crystal structure and packing of the host and guest molecules in the [M(4-McPy)4(NCS)2]�0.67(4-McPy)�0.33 H2O Clathrates (M = Cu(II), Mn(II); 4-MePy = 4-Methylpyridine)
Journal of Inclusion Phenomena and Molecular Recognition in Chemistry (1992)
-
Crystal structure of the inclusion compound of trans-bis (Isothiocyanato)-tetrakis-4-methylpyridinecadmium (II) with 4-methylpyridine and water, Cd(4-MePy)4(NCS)2? 0.67 (4-MePy)?0.33H2O
Journal of Structural Chemistry (1986)
-
Inclusion compounds ?Past, present, and future
Journal of Inclusion Phenomena (1983)
-
Die Verwendung von Klathraten der Komplexsalze vom Typ Ni(SCN)2(4-MePy)4 zur Trennung vonCis-Trans-Azobenzolgemischen
Monatshefte f�r Chemie (1972)