Abstract
Electronic structures of exohedral palladium complexes of [60]- and [70]-fullerenes with diphenylphosphinoferrocenyl, diphenylphosphinoruthenocenyl, and diphenylphosphinocymantrenyl ligands were studied by cyclic voltammetry and semiempirical quantum-chemical calculations. Probable sites of localization of electronic changes in the molecules of these complexes under electrochemical oxidation and reduction were determined.
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Magdesieva, T.V., Bashilov, V.V., Kravchuk, D.N. et al. Comparison of electrochemical behavior of exohedral palladium complexes with [60]- and [70]-fullerenes and metallocene ligands. Russian Chemical Bulletin 53, 795–799 (2004). https://doi.org/10.1023/B:RUCB.0000037844.93864.3c
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DOI: https://doi.org/10.1023/B:RUCB.0000037844.93864.3c