Abstract
The chelating interaction between metal ions and 4,4′-disubstituted-2,2′-bipyridyl-containing high-performance polymeric ligands prepared from 2,2′-bipyridyl-4,4′-dicarboxylic acid and a series of primary aromatic diamines was investigated by optical spectroscopy. Optical spectroscopic studies of the chelation of ruthenium ions by the 2,2′-bipyridyl-containing polyamides revealed the formation of distinct ruthenium(II) complexes [RuII(poly)L4] (λ max=530 nm), [RuII(poly)2L2] (λ max=584 nm), and [RuII(poly)3]2+ (λ max=476 nm), while iron(II) ions formed only one complex (λ max=569 nm). The diverse functional features of the polymer repeat unit directly influences the chelation of metal ions.
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REFERENCES
A. J. Bard and G. M. Whitesides, WO Patent 8602734 A1 860509 (1986).
J. L. Reddinger and J. R. Reynold, Polym. Prepr. 38(2), 321 (1997).
S. Kelch and M. Rehahn, Macromolecules 30(20), 6185 (1997). (b) M. Rehahn, Macromolecules 29, 478 (1996).
J. L. Serrano and L. Oriol, Polym. Prepr. 37(1), 56 (1996).
J. A. Puertolas, E. Carod, R. Diaz-Calleja, P. Cerrada, L. Oriol, M. Piñol, and J. L. Serrano, Macromolecules 30(4), 773 (1997).
S. L. Kwolek, U.S. Patent 3,671,542 (1972).
F. E. Sloan and J. B. Talbot, Science 48, 830 (1992).
F. E. Sloan and J. B. Talbot, Science 48, 1020 (1992).
W. C. Tucker and R. Brown, J. Comp. Mater. 23, 389 (1989).
W. C. Tucker, R. Brown, and L. Russell, J. Comp. Mater. 24, 92 (1990).
J.-K. Lee, H. Mattoussi, D. Yoo, A. Wu, and M. F. Rubner, Polym. Prepr. 38(1), 351 (1997).
F. H. Burstall and R. S. Nyholm, J. Chem. Soc. 3570 (1952).
T. J. Meyer, R. W. Murray, L. D. Margerum, and C. D. Ellis, Inorg. Chem. 22, 1283 (1983).
O. N. Petzold and I. I. Harruna, J. Inorg. Organomet. Polym. 10, 231-248 (2000).
(a) B. Kratochvil and M. C. White, Anal. Chim. Acta 31(6), 528 (1964). (b) W. W. Brandt and G. F. Smith, Anal. Chem. 21, 1313 (1949).
(a) K. Yamasaki, Bull. Chem. Soc. Japan 12, 390 (1937). (b) K. Yamasaki, Bull. Chem. Soc. Japan 15, 461 (1940).
P. Denisevich, H. D. Abruña, C. R. Leinder, T. J. Meyer, and R. W. Murray, Inorg. Chem. 21(6), 2153 (1982).
V. Balzani, S. Campagna, G. Denti, A. Juris, S. Serroni, and M. Venturi, Acc. Chem. Res. 31, 26 (1998).
Y. Sun and M. K. DeArmond, J. Phys. Chem. 97(33), 8549 (1993).
C. Ng and C. L. Fraser, Polym. Mat. Sci. Eng. 80, 84 (1999).
D. F. Shriver, P. Atkins, and C. H. Langford, Inorganic Chemistry, 2nd ed., pp. 262-266, 596-598.
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Petzold, O.N., Harruna, I.I. High-Performance Directional Metallopolyamides. II. Optical Spectroscopic Studies of Metal Chelation. Journal of Inorganic and Organometallic Polymers 10, 249–264 (2000). https://doi.org/10.1023/A:1016646907899
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DOI: https://doi.org/10.1023/A:1016646907899