Abstract
A dinuclear copper(II) [(LCu)(MeOH)Cu(phen)(MeOH)]ClO4·NO3 macrocyclic complex (where H2L = 2,3-dioxo-5,6:15,16-dibenzo-1,4,8,13-tetraazacyclo-pentadeca-7,13-diene; phen = 1,10-phenanthroline) has been synthesized and characterized by means of elemental analysis and its i.r. spectrum. Its crystal structure has been determined by single-crystal X-ray diffraction. In the complex, both the copper ions are penta-coordinated and have a distorted square pyramid configuration. Magnetic susceptibility measurements show antiferromagnetic exchange interactions (J = −207.64 cm−1) between the copper(II) ions.
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Wang, Sb., Yang, Gm., Yu, Lh. et al. Synthesis, crystal structure and magnetic properties of [(LCu)(MeOH)Cu(phen)-(MeOH)]ClO4·NO3 (H2L = 2,3-dioxo-5,6:15,16-dibenzo-1,4,8,13-tetraazacyclo-pentadeca-7,13-diene). Transition Metal Chemistry 28, 632–634 (2003). https://doi.org/10.1023/A:1025437517541
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DOI: https://doi.org/10.1023/A:1025437517541