Abstract
The preparation, magnetic properties, and crystal structure of [(salen)Cu]4[(salen)Fe(H2O)2]2(ClO4)2 via hydrogen bonding are described [salen=N,N′-ethylenebis (salicylideneiminate)]. Crystals are triclinic, of space group \(\rm P\bar 1\), with cell constants a=12.853(3), b=13.921(3), c=14.251(3) Å, α=68.68(3)°, β=87.86(3)°, γ=86.82(3)°, and Z=1. The structure was solved and refined to R=0.064 and R′=0.068. The structure comprises the hexanuclear units which result from the linking of four mononuclear fragments [(salen)Cu] and two mononuclear fragment [(salen)Fe(H2O)]+, through Cu -O ⋯ H -O -Fe -O -H ⋯ O -Cu hydrogen bonds of coordinating H2O. In this complex, FeIII ions are in almost square-planar surroundings. The temperature dependences of the magnetic susceptibilities of the complex have been studied in the 4.2–300 K range, indicating the presence of an antiferromagnetic interactions between metal ions.
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REFERENCES
J. A. Gerlt and P. G. Gassman (1993). J. Am. Chem. Soc. 115, 11552.
P. A. Frey, S. A. Whitt, and J. B. Tobin (1994). Science 264, 1927.
B. Schwartz and D. G. Drueckhammer (1995). J. Am. Chem. Soc. 117, 11902.
J. A. Bertrand, T. D. Black, P. G. Eller, F. T. Helm, and R. Mahmood (1976). Inorg. Chem. 15, 2965.
H. Muhonen (1986). Inorg. Chem. 25, 4692.
P. A. Goodson, J. Glerup, D. J. Hodgson, K. Michelsen, and U. Rychlewska (1994). Inorg. Chem. 33, 359.
M. C. Moron, F. Palacio, J. Pons, J. Casabo, X. Solans, K. E. Merabet, D. Huang, X. Shi, B. K. Teo, and R. L. Carhin (1994). Inorg. Chem. 33, 746.
U. Bossek, K. Wieghardt, B. Nuber, and J. Weiss (1990). Angew. Chem. Int. Ed. Eng. 29, 1055.
J. M. Moreno, J. Ruiz, J. M. D. Vera, and E. Colacio (1993). Inorg. Chim. Acta 208, 111.
E. Colaio, J. P. Costes, R. Kivekas, J. P. Laurent, J. Ruiz, and M. Sundberg (1991). Inorg Chem. 30, 1475.
J. Cirujeda, M. Mas, E. Molins, F. L. de Panthou, J. Laugier, J. C. Park, C. Paulsen, P. Rey, C. Rovira, and J. Veciana (1995). J. Chem. Soc. Chem. Commun. 709.
G. R. Desiraju (1996). Acc. Chem. Res. 26, 441, and references therein.
H. Yoneda and S. Kida (1960). J. Am. Chem. Soc. 82, 2139.
F. Lloret, M. Julve, M. Miquel, I. Castro, J. Latorre, J. Faus, X. Solans, and I. M. Badarau (1989). J. Chem. Soc. Dalton Trans. 729.
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Yang, GM., Cheng, P., Liao, DZ. et al. The First New Hydrogen-Bonded Heterohexanuclear Complex [(salen)Cu]4[(salen)Fe(H2O)2]2(ClO4)2: Molecular and Crystal Structure and Magnetic Properties. Journal of Cluster Science 9, 465–471 (1998). https://doi.org/10.1023/A:1021990516837
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DOI: https://doi.org/10.1023/A:1021990516837