Abstract
A low-thermal-expansion ceramic with the composition Al0.8Mg0.6Ti1.6O5 that is isostructural to aluminium titanate Al2TiO5, was prepared by solid-state reaction of a mixture of α-Al2O3, MgO and TiO2-rutile. The synthesized material does not decompose after annealing for 250 h in the temperature range of 900–1175°C. The ceramic sintered at 1350°C has a 97% relative density, a grain size of ≈5 μm and an average thermal expansion coefficient between 80 and 1000°C of ≈2×10−6 K−1. Materials with the same composition, but obtained by reaction sintering, have a higher thermal expansion coefficient (4×10−6 K−1) and showed the presence of secondary phases.
Similar content being viewed by others
References
G. BAYER, J. Less-Common Metals 24 (1971) 129.
J. J. CLEVELAND and R. C. BRADT, J. Amer. Ceram. Soc. 61 (1978) 478.
Y. OHYA, Z. NAKAGAWA and K. HAMANO, ibid. 70 (1987) C184.
F. J. PARKER and R. W. RICE, ibid. 72 (1989) 2364.
D. P. H. HASSELMAN, K. Y. DONALDSON, E. M. ANDERSON and T. A. JOHNSON, ibid. 76 (1993) 2180.
P. STINGL, J. HEINRICH and J. HUBER in Proceedings of the 2nd International Symposium on Ceramic Materials and Components for Engines, Lübeck-Travemünde, Germany, April 1986, edited by W. Bunk and H. Hausner, (DKG, Bad Honnef, 1986) p. 369.
H. MORISHIMA, Z. KATO, K. UEMATSU, K. SAITO, T. YANO and N. OOTSUKA, J. Mater. Sci. Lett. 6 (1987) 389.
F. J. PARKER, J. Amer. Ceram. Soc. 73 (1990) 929.
H. WOHLFROMM, J. S. MOYA and P. PENA, J. Mater. Sci. 25 (1990) 3753.
E. KATO, K. DAIMON and J. TAKAHASHI, J. Amer. Ceram. Soc. 63 (1980) 355.
M. ISHITSUKA, T. SATO, T. ENDO and M. SHIMADA, ibid. 70 (1987) 69.
G. TILLOCA, J. Mater. Sci. 26 (1991) 2809.
T. KAMEYAMA and T. YAMAGUCHI, J. Ceram. Soc. Jpn. 84 (1976) 589.
E. KATO, K. DAIMON and Y. KOBAYASHI, ibid. 86 (1978) 626.
V. BUSCAGLIA, G. BATTILANA, M. LEONI and P. NANNI, J. Mater. Sci. 31 (1996) 5009.
D. B. WILES and R. A. YOUNG, J. Appl. Cryst. 14 (1981) 149.
E. M. LEVIN and H. F. Mc MURDIE, “Phase diagrams for ceramists, 1975 supplement,” (The American Ceramic Society, Columbus, OH, 1975).
O. KNACKE, O. KUBASCHEWSKI and K. HESSELMANN, “Thermochemical properties of inorganic substances”, (Springer, Berlin, 1991).
B. FREUDENBERG and A. MOCELLIN, J. Amer. Ceram. Soc. 71 (1988) 22.
V. BUSCAGLIA, M. ALVAZZI DELFRATE, M. LEONI, C. BOTTINO and P. NANNI, J. Mater. Sci. 31 (1996) 1715.
V. BUSCAGLIA, M. ALVAZZI DELFRATE, P. NANNI, M. LEONI and C. BOTTINO, in Proceedings of the 8th CIMTEC (World Ceramic Congress), Firenze, Italy, 28 June–4 July 1994, edited by P. Vincenzini, (Faenza Editrice, Faenza, 1995) p. 1867.
Y. OHYA and Z. NAKAGAWA, J. Mater. Sci. 31 (1996) 1555.
Y. OHYA, Y. TAKAHASHI and Z. NAKAGAWA, ibid. 31 (1996) 1361.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Buscaglia, V., Caracciolo, F., Leoni, M. et al. Synthesis, sintering and expansion of Al0.8Mg0.6Ti1.6O5: a low-thermal-expansion material resistant to thermal decomposition. Journal of Materials Science 32, 6525–6531 (1997). https://doi.org/10.1023/A:1018611311015
Published:
Issue Date:
DOI: https://doi.org/10.1023/A:1018611311015