Abstract
Kinetics of the monoethanolamine vapor adsorption on the surface of silica previously deposited onto quartz plate was examined by the piezoelectric microweighing. With the assumptions which are in accord with the experimental data, the kinetic equation of the process was obtained and thus the adsorption and desorption constants were found. The structure of the possible adsorption complexes was studied in the framework of the quantum-chemical MNDO method and the conclusion was made that the two-center adsorption of the monoethanolamine on the silica surface proceeds as a two-stage process with the participation of both functional groups. The bonding is mainly effected owing to the proton-acceptor properties of amine groups.
Similar content being viewed by others
REFERENCES
G. Z. Sauerbrey, Z. Phys., 155 (1959) 206.
R. Conti, S. Rusponi, D. Pagnotta, C. Boragno and U. Valbusa, Vacuum, 48 (1997) 639.
V. Ferrari, D. Marioli and A. Taroni, Measurement Sci. and Techn., 8 (1997) 42.
D. T. Read, J. Testing and Evaluation, 26 (1998) 255.
J. S. Hundal and R. Nath, J. Physics: D, 31 (1998) 482.
G. L. Ghiringhelli, P. Masarati and P. Mantegazza, J. Intel. Mater. Syst. Struct., 8 (1997) 842.
W. Kowbel, X. **a and J. C. Withens, Ferroelec. Thin Films, 493 (1998) 433.
L. Dong and J. Mistry, Composite Structures, 40 (1997) 149.
D. Lines, Insight, 40 (1998) 573.
M. L. Ericson and H. Lindberg, Polymer, 38 (1997) 4485.
A. W. Warner and C. D. Stockbridge, The Measurement of Mass using Quartz Crystal Resonators, Symposium on Vacuum Microbalance Techniques, Los Angeles 1962.
G. G. Guilbault and J. M. Jordan, Anal. Chem., 19 (1988) 1.
M. W. Frechette, J. L. Fasching and D. M. Rosie, Anal. Chem., 45 (1973) 1765.
E. T. Zeller, N. Hassold, R. W. Whit and S.M. Rappaport, Anal. Chem., 62 (1990) 1222.
A. Yu. Fadeev, A. L. Filatov and G. V. Lisichkin, Dokl. Akad. Nauk RAN, 336 (1994) 786.
A. Yu. Fadeev, A. A. El'tsov and U. K. Aleshin, Zhurn. Fiz. Khimii, 68 (1994) 139.
M. J. S. Dewar and W. Thiel, J. Amer. Chem. Soc., 99 (1977) 4899.
V. V. Lobanov, Yu. I. Gorlov, A. A. Chuiko, V. M. Pinchuk, U. S. Sinekop and U. I. Yakimenko, The Role of Electrostatic Interactions in Adsorption on Solid Oxide Surfaces, Vek, Kyiv 1999 (in Russian).
A. A. Chuiko, V. A. Tertykh, E. A. Chuiko and I. E. Neimark, Dokl. Akad. Nauk SSSR, 186 (1969) 385.
A. A. Chuiko, E. A. Chuiko and V. A. Tertykh, Ukr. Khim. Zhurn., 37 (1971) 35.
A. V. Kiselev, V. I. Lygin and I. N. Solomonova, Zhurn. Fiz. Khimii, 48 (1971) 1249.
A. A. Chuiko, Yu. I. Gorlov, G. Ya. Guba and M. I. Terets, Ukr. Khim. Zhurn., 61 (1995) 25.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lobanov, V.V., Chuiko, A.A., Burlaenko, N.A. et al. Gravimetric And Quantum-chemical Study of Interaction of Monoethanolamine Vapor With Silica Surface. Journal of Thermal Analysis and Calorimetry 62, 381–387 (2000). https://doi.org/10.1023/A:1010109309014
Issue Date:
DOI: https://doi.org/10.1023/A:1010109309014