SpringerLink
Log in

Preparation, characterization and crystal structure of an intermolecular compound based on H3PMo12O40·nH2O and diethylamine

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

An intermolecular compound, H3PMo12O40·5(CH3CH2)2NH·H2O, between the heteropolymolybdate α-H3PMo12O40 and the organic substrate diethylamine, has been synthesized and characterized. Light yellow crystals of the title compound were crystallized from a mixed solvent of water and acetonitrile with formula H3PMo12O40·5(CH3CH2)2NH·H2O. Spectroscopic data support the presence of a sizable electronic interaction between the organic substrate and the inorganic anion in the solid state. The single crystal x-ray structure analysis of the title compound revealed that it crystallized in the triclinic system, space group P\(\overline 1\) with a = 12.0786(13), b = 12.102(5), c = 21.416(3) Å, α = 94.87(2), β = 94.755(9), γ = 113.81(2)°, V = 2830.3(13) Å3, and Z = 2.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (France)

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Williamson, M.M.; Bouchard, D.A.; Hill, C.L. Inorg. Chem. 1987, 26, 1436.

    Google Scholar 

  2. Attanasio, D.; Bonamico, M.; Fares, V.; Imperatori, P.; Suber, L. J. Chem. Soc. Dalton Trans. 1990, 3221.

  3. **g-Yang Niu; **ao-Zeng You; Chun-Ying Duan; Hoong-Kun Fun; Zhong-Yuan Zhou. Inorg. Chem. 1996, 14, 4211.

    Google Scholar 

  4. Claud, R.-D.; Michael, F.; Raymonde, F.; Rene, T. Inorg. Chem. 1983, 22, 207.

    Google Scholar 

  5. Sheldric, G.M. SHELXTL-PC. Structure determination software Programs. Siemes Analytical X-ray Instruments Inc. Madison, WI, 1990b.

    Google Scholar 

  6. Keggin, J.F. Nature 1933, 131, 908.

    Google Scholar 

  7. Amour, H.D.; Allmann, R.; Z. Krist. 1976, 143, 1.

    Google Scholar 

  8. Brown, D.; Altermatt, D. Acta Crystallogr. 1985, B41, 2440.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475003, P.R. China

    **g-Yang Niu, **g-** Wang, Bo Yan & Dong-Bin Dang

  2. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, P.R. China

    Zhong-Yuan Zhou

Authors
  1. **g-Yang Niu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. **g-** Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Bo Yan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Dong-Bin Dang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Zhong-Yuan Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Niu, JY., Wang, JP., Yan, B. et al. Preparation, characterization and crystal structure of an intermolecular compound based on H3PMo12O40·nH2O and diethylamine. Journal of Chemical Crystallography 30, 43–48 (2000). https://doi.org/10.1023/A:1009546132511

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1009546132511

Search

Navigation