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Corrosion resistance of BN–ZrO2 ceramics with different additives by molten steel

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Abstract

BN–ZrO2 ceramics with different additives such as SiC, Al2O3 and MgAl2O4 were fabricated by hot pressing sintering process to study sintering properties and corrosion resistance by the rotary immersion molten steel test. The results showed that SiC, Al2O3 and MgAl2O4 can improve the sintering properties of BN–ZrO2 ceramics; especially, the introduction of SiC can significantly improve the hardness of the material; thus, the above compounds will help to improve the wear resistance of BN–ZrO2 ceramics. The exposed oxide layer is in contact with molten steel and forms liquid phase after BN oxidation and B2O3 volatilization, additives can significantly affect the properties of liquid phase, and m-ZrO2 grains are sintered and grown by dissolution–precipitation mechanism by liquid phase. Consequently, Al2O3 and MgAl2O4 are more conducive to the formation of working layer with solid skeleton, which determines the corrosion resistance of BN–ZrO2 ceramics.

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Acknowledgements

The authors gratefully acknowledge the support of National Natural Science Foundation of China (51932008 and 51772277) and Central China Thousand Talents Project (204200510011).

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Authors and Affiliations

  1. State Key Laboratory of Advanced Refractories, Sinosteel Luoyang Institute of Refractories Research Co., Ltd., Luoyang, 471039, Henan, China

    Fan Qian, Wen-gang Yang, Guo-qi Liu & Hong-xia Li

  2. Institute of Research of Iron and Steel, Shasteel, Zhangjiagang, 215625, Jiangsu, China

    Hua-long Li & Hai-rong Guo

  3. School of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, China

    Bei-yue Ma

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  1. Fan Qian
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  2. Hua-long Li
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  3. Wen-gang Yang
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  5. Guo-qi Liu
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  6. Hong-xia Li
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Correspondence to Hong-xia Li or Bei-yue Ma.

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Qian, F., Li, Hl., Yang, Wg. et al. Corrosion resistance of BN–ZrO2 ceramics with different additives by molten steel. J. Iron Steel Res. Int. 29, 1101–1109 (2022). https://doi.org/10.1007/s42243-021-00696-x

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  • DOI: https://doi.org/10.1007/s42243-021-00696-x

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