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Temperature Effect on Early Oxidation Behavior of NiCoCrAlY Coatings: Microstructure and Phase Transformation

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Acta Metallurgica Sinica (English Letters) Aims and scope

Abstract

Initial oxidation behavior of NiCoCrAlY coating prepared by arc-ion plating has been studied in air at 900, 1000 and 1100 °C. The results showed that phase transformation from transient θ-Al2O3 to α-Al2O3 was highly related to the temperature and oxidation time. The oxide scale in the initial stage was mainly composed of θ-Al2O3 at 900 °C. Instead, more amount of α-Al2O3 emerged out with increasing oxidation temperature. The elemental distribution after oxidation confirmed that faster chromium diffusion to the oxide scale played an important role in the speedy transformation from θ-Al2O3 to α-Al2O3. Y segregation at scale/coating interface resulted in less cavity formation and hence improved the oxide scale adherence.

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Acknowledgements

This project was sponsored by the R&D Program in Key Fields of Guangdong Province (No. 2019B010936001) and the National Natural Science Foundation of China (Grant No. 51671202). This work was also partly supported by the National Engineering Laboratory for Marine and Ocean Engineering Power System—Laboratory for Ocean Engineering Gas Turbine.

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Correspondence to Z. B. Bao or Y. F. Yang.

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Ullah, A., Khan, A., Bao, Z.B. et al. Temperature Effect on Early Oxidation Behavior of NiCoCrAlY Coatings: Microstructure and Phase Transformation. Acta Metall. Sin. (Engl. Lett.) 35, 975–984 (2022). https://doi.org/10.1007/s40195-021-01310-5

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