Abstract
We performed an ellipsometric study of TiN films on Si substrate to determine optimal conditions for TiN deposition, which is one of main processes in the memory device fabrication. To analyze structural changes of TiN films during the growth including nucleation, merging, and uniform growth, we applied an effective medium approximation model and calculated uneven characteristics of the growing layer. This result is expected to be widely applied for the TiN deposition process optimization and in-line process monitoring according to the decreasing size of the semiconductor devices for further integration in the future.
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References
K. Kim, Technology for sub-50nm DRAM and NAND flash manufacturing. IEDM (2005). https://doi.org/10.1109/IEDM.2005.1609340
J.M. Park et al., 20 nm DRAM: a new beginning of another revolution. IEDM (2015). https://doi.org/10.1109/IEDM.2015.7409774
H.J. Cho et al., Solid-State Electron 51, 1529 (2007)
D. Zhou et al., J Appl Phys 108, 124104 (2010)
D. Panda, T.-Y. Tseng, Thin Solid Films 531, 1 (2013)
D. Martin et al., J. Appl. Phys. 113, 194103 (2013)
F. Fillot, T. Morel, S. Minoret, I. Matko, S. Maîtrejean, B. Guillaumot, B. Chenevier, T. Billon, Microelectron. Eng. 82, 248 (2005)
G.S. Chen, J.J. Guo, C.K. Lin, C.-S. Hsu, L.C. Yang, J.S. Fang, J. Vac. Sci. Technol. A. 20, 479 (2002)
E. Langereis, S.B.S. Heil, M.C.M. van de Sanden et al., J. Appl. Phys. 113, 194103 (2013)
R.W. Collins, B.Y. Yang, J. Vac. Sci. Technol. B 7, 1155 (1989)
R.W. Collins, in Advances in amorphous semiconductors. ed. by H. Fritzsche (World Scientific, Singapore, 1989), p. 1003
A.M. Antoine, B. Drevillon, J. Non-Cryst. Solids. 1403, 97–98 (1987)
D.E. Aspnes, J.B. Theeten, F. Hottier, Phys. Rev. B 20, 3292 (1979)
J.W. Elam, M. Schuisky, J.D. Ferguson, S.M. George, Thin Solid Films 436, 145 (2003)
T. Suntola, Antson, J. Method for producing compound thin films US Patent 4058430 (1974)
H. Kim, J. Vac. Sci. Technol. B 21, 2231 (2003)
T. Lichtenstein, Handbook of thin film materials (University of Rochester, Rochester, 1979)
C.M. Herzinger, B. Johs, W.A. McGahan, J.A. Woollam, J. Appl. Phys. 83, 3323 (1998)
See Supplemental Material at https://www.jawoollam.com/resources/ellipsometry-tutorial/light-and-materials/attachment/tio2-optical-properties-uv-to-ir. Accessed 30 Dec 2021
K. Uetani, H. Kajiyama, A. Kato, A. Takagi, I. Tokomoto, Y. Koizumi, K. Nose, Y. Ihara, K. Onisawa, T. Minemura, Mater. Trans. 42, 411 (2001)
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Jung, Y.W., Lee, R.S., Kim, J.H. et al. Study on TiN film growth mechanism using spectroscopic ellipsometry. J. Korean Phys. Soc. 80, 185–189 (2022). https://doi.org/10.1007/s40042-021-00395-6
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DOI: https://doi.org/10.1007/s40042-021-00395-6