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Trace element geochemistry in topsoil from East China

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Abstract

The concentrations of 23 trace elements in 50 topsoil samples collected from sites ranging between 18°19′N and 49°13′N in East China were analyzed. Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, and Ta have mean contents more than two times higher than in the continental upper crust. Three elements, Rb, Sr, and Ba, are present at lower concentrations than in the continental upper crust. Finally, a group of elements consisting of Ge, Y, Zr, Nb, Sc, Hf, Pb, Th, and U are present at concentrations 1–2 times higher than in the continental upper crust. However, concentrations of trace elements are mainly affected by parent rock. The contents of Sc, Ti, V, Cr, Mn, Co, and Cu for 29 soils from basalt were found to increase from north to south, whereas Rb, Sr, and Ba contents were found to decrease. In addition, element concentration shows a close relationship with annual average temperature (AAT) as well as annual average precipitation (AAP). Since the 29 soils are all from basalt, the trends of the elemental contents should reflect the influence of climate, which determines the intensity of weathering. These elemental trends suggest that the content of certain elements may indicate the intensity of basalt weathering. Ba/Nb and Sr/Nb ratios were both found to have good correlations with AAT and AAP in this study, which means that these ratios can also indicate the intensity of chemical weathering of basalt.

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References

  • Braun JJ, Pagel M, Muller JP, Michard A, Guillet B (1990) Cerium anomalies in lateritic profiles. Geochim Cosmochim Acta 54:781–795. doi:10.1016/0016-7037(90)90373-S

    Article  Google Scholar 

  • Braun JJ, Pagel M, Herbillon A, Rosin C (1993) Mobilization and redistribution of REEs and Thorium in a syenitic lateritic profile: a mass-balance study. Geochim Cosmochim Acta 57:4419–4434. doi:10.1016/0016-7037(93)90492-F

    Article  Google Scholar 

  • Butt CRM, Zeegers H. (1992) Climate, geomorphological environment and geochemical dispersion models. In: Handbook of exploration geochemistry, regolith exploration geochemistry in tropical and subtropical terrains, vol 4. Rotterdam, Elsevier, pp 3–24

  • Cullers RL (1988) Mineralogical and chemical changes of soil and stream sediment formed by intense weathering of the Danburg granite, Georgia, USA. Lithos 21:301–314. doi:10.1016/0024-4937(88)90035-7

    Article  Google Scholar 

  • Cullers RL, Barrett T, Carlson R, Robinson B (1987) Rare earth element and mineralogic changes in Holocene soil and stream sediment: a case study in the Wet Mountains, Colorado, USA. Chem Geol 63:275–297. doi:10.1016/0009-2541(87)90167-7

    Article  Google Scholar 

  • Duddy LR (1980) Redistribution and fractionation of rare-earth and other elements in a weathering profile. Chem Geol 30:363–381. doi:10.1016/0009-2541(80)90102-3

    Article  Google Scholar 

  • Hill IG, Worden RH, Meighan IG (2000) Yttrium: the immobility–mobility transition during basaltic weathering. Geology 28:923–926. doi:10.1130/0091-7613(2000)28<923:YTITDB>2.0.CO;2

    Article  Google Scholar 

  • Huang CM, Gong ZT (2002) Study on genesis of soils derived from basalt in northern Hainan Island III Element geochemistry. Acta Petrol Sin 39:643–652

    Google Scholar 

  • Johnsson MJ, Stallard RF, Meade RH (1988) First-cycle quartz arenites in the Orinoco River basin, Venezuela and Colombia. J Geol 96:263–277

    Article  Google Scholar 

  • Kurtz AC, Derry LA, Chadwick OA, Alfano MJ (2000) Refractory element mobility in volcanic soils. Geology 28:683–686. doi:10.1130/0091-7613(2000)28<683:REMIVS>2.0.CO;2

    Article  Google Scholar 

  • Li XH, Liu Y, Tu XL, Hu GQ, Zeng W (2002) Precise ICP-MS. determination of chemical compositions in silicate rocks using ICP-AES. A comparative study of sample digestion techniques of alkali fusion and acid dissolution. Geochimica 31:289–294 (in Chinese with English abstract)

    Google Scholar 

  • Liu Y, Liu HC, Li XH (1996) Simultaneous and precise determination of 40 trace elements in rock samples using ICP-MS. Geochimica 25:552–558 (in Chinese with English abstract)

    Google Scholar 

  • Ma JL, Wei GJ, Xu YG, Long WG, Sun WD (2007) Mobilization and re-distribution of major and trace elements during extreme weathering of basalt in Hainan Island, South China. Geochim Cosmochim Acta 71:3223–3237. doi:10.1016/j.gca.2007.03.035

    Article  Google Scholar 

  • Marques JJ, Schulze DG, Curi N, Mertzman SA (2004) Trace element geochemistry in Brazilian Cerrado soils. Geoderma 121:31–43. doi:10.1016/j.geoderma.2003.10.003

    Article  Google Scholar 

  • Moore CL (1998) Evaluation of regolith development and element mobility during weathering using isocon technique. Geol Soc Aust Spec Publ 20:141–147

    Google Scholar 

  • Nesbitt HW (1979) Mobility and fractionation of rare earth elements during weathering of granodiorite. Nature 279:206–210. doi:10.1038/279206a0

    Article  Google Scholar 

  • Nesbitt HW, Wilson RE (1992) Recent chemical-weathering of basalts. Am J Sci 292:740–777

    Google Scholar 

  • Patino LC, Velbel MA, Price JR, Wade JA (2003) Trace element mobility during spheroidal weathering of basalts and andesites in Hawaii and Guatemala. Chem Geol 202:343–364. doi:10.1016/j.chemgeo.2003.01.002

    Article  Google Scholar 

  • Schwertmann U, Pfab G (1996) Structural vanadium and chromium in lateric iron oxides: genetic implications. Geochim Cosmochim Acta 60:4279–4283. doi:10.1016/S0016-7037(96)00259-1

    Article  Google Scholar 

  • Suttner LJ, Basu A, Mack GH (1981) Climate and the origin of quartz arenites. J Sediment Petrol 51:1235–1246

    Google Scholar 

  • Temgoua E, Pfeifer HR, Biton D (2003) Trace element differentiation in ferruginous accumulation soil patterns under tropical rainforest of southern Cameroon, the role of climatic change. Sci Total Environ 303:203–214. doi:10.1016/S0048-9697(02)00401-1

    Article  Google Scholar 

  • Wedepohl KH (1995) The composition of the continental crust. Geochim Cosmochim Acta 59:1217–1232. doi:10.1016/0016-7037(95)00038-2

    Article  Google Scholar 

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Acknowledgments

This study is supported by Knowledge Innovation Project of Chinese Academy of Sciences (Grant No. KZCX3-SW-152), National Basic Research Program of China (Grant No. 2004CB720204), and Natural Science Foundation of China (Grant Nos. 40672121 and 40331009).

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Correspondence to Zhaoyu Zhu.

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Yang, T., Zhu, Z., Gao, Q. et al. Trace element geochemistry in topsoil from East China. Environ Earth Sci 60, 623–631 (2010). https://doi.org/10.1007/s12665-009-0202-6

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