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Evaluation of Different Parameters on Production of Zr2Cu by Mechanical Alloying

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Abstract

Intermetallic compounds because of their high melting point temperature, good mechanical properties, and high corrosion resistance are attractive. The Zr2Cu intermetallic compound can be produced by a mechanical alloying method. In this study, alloying was carried out by using the pure copper and zirconium powders under argon atmosphere at different time durations from 30 to 120 minutes. Milling speed was chosen as 220, 250, and 280 rpm. Mechanical alloying was done with five different balls to powder ratios (BPR) of 1:10, 1:15, 1:20, 1:25, 1:50. Prepared powders were studied by X-Ray Diffraction (XRD). XRD results showed that with increasing milling time and ball to powder ratio, the amount of amorphous phase increases, however, particle size reduces. By increasing the ball to powder ratio, speed and time of milling crystallite size decreases, but lattice strain increases.

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References

  1. Sauthoff G (2003) Intermetallics, Ali Haerian Ardekani, Mohammad Hossein Hemmati. publication No.381. Ferdowsi University of Mashhad, Mashhad, Iran

    Google Scholar 

  2. Wang N, Li C. h., Du Z. h., Wang F, Zhang W (2006) The thermodynamic re-assessment of the Cu–Zr system. Comput Coupling Phase Diagr Thermochemistry 31:461–469

    Article  Google Scholar 

  3. Tu JP, Qi WX, Zhng YZ (2002) Effect of aging treatment on the electrical sliding wear behavior of Cu–Cr–ZrAlloy. Wear 249:1112–1127

    Google Scholar 

  4. Liu P, Kang BX, Kao XG, Huang JL (1999) Aging precipitation and recrystallization of rapidly solidified Cu–CrZr–Mg alloy. Mater Sci Eng A 265:262–267

    Article  Google Scholar 

  5. Su JH, Dong QM, Liu P, Li HJ, Kang BX (2005) Research on aging precipitation in a Cu–Cr–Zr–Mg alloy. Mater Sci Eng A 392:422–426

    Article  Google Scholar 

  6. Li Z, Shen J, Cao F, Li Q (2003) A high strength and high conductivity copper alloy prepared by spray forming. Mater Process Technol 137:61–66

    Google Scholar 

  7. Glimois JL, Forey P, Feron JL (1985) Structural and physical studies of copper-rich alloys in the Cu-Zr system. Less-Common Met 113:213–224

    Article  CAS  Google Scholar 

  8. Forey P, Glimois JL, Feron JL (1986) Structural study of ternary (Ni1-xCux)5Zr alloys. Less-Common Met 124:21–27

    Article  CAS  Google Scholar 

  9. Donachie M. J. Jr (1986) Investigation of copper-rich portion of copper-zircomiun phase diagram by electron-probe microanalysis. Inst Met 113:181

    Google Scholar 

  10. Yang H, Wang JQ, Li Y (2006) Glass formation in the ternary Zr–Zr2Cu–Zr2Ni system. J Non-Cryst Solids 352:832–836

    Article  CAS  Google Scholar 

  11. Sandhage KH (2010) Near net-shape, ultra high melting, erosion resistant carbide/metal composites with tailordfibrillar microstructures via the DCP process. School of Materials and Engineering, Georgia Institute of Technology, Atlanta

    Google Scholar 

  12. Zhao YW, Wang YJ, Peng HX, Zhou Y (2012) Dense sub-micron-sized ZrC–W composite produced by reactive melt infiltration at 1200 C. J Refract Met Hard Mater 30:196–199

    Article  CAS  Google Scholar 

  13. Zhao YW, Wang YJ, Peng HX, Zhou Y, Song GM (2011) Ternary phase ZrxCuyCz in reactively infiltrated ZrC/W composite. J Amer Ceram Soc 94([10]):3178–3180

    Article  CAS  Google Scholar 

  14. Neogy S, Mukherjee A, Ashwini B, Srivastava D, Savalia RT, Dey GK, Venkatraman N, De PK (2004) Zirconium based bulk metallic glass/tungten fiber composite- fabrication and characterization. International Symposium of Research Students on Materials Science and Engineering December, pp 20–22

  15. Dickerson M, Sandhage KH (2001) Low-temperature reaction casting of dense, near net-shaped carbide/refractory metal composite. Rev Latinoam Metal Mater 21

  16. Suryanarayana C (2014) Mechanical alloying and milling, 1st edn. Marcel Dekker, New York

    Google Scholar 

  17. Williamson GK, Hall WH (1953) Acta Metall 1:22–31

    Article  CAS  Google Scholar 

  18. Azimi A, Shokuhfar A, Zolriasatein A (2014) Nanostructured Al–Zn–Mg–Cu–Zr alloy prepared by mechanical alloying followed by hot pressing. Mater Sci Eng A 595:124–130

    Article  CAS  Google Scholar 

  19. Ohshiro H, Arakawa T (1994) Thermal behaviour of amorphous Cux Zr1−x powders synthesized by mechanical alloying. J Alloys Compd 215(1–2):251–255

    Article  CAS  Google Scholar 

  20. Azimi M, Akbari GH (2013) Characterization of nano-structured Cu–6 wt.% Zr alloy produced by mechanical alloying and annealing methods. J Alloys Compd 555:112–116

    Article  CAS  Google Scholar 

  21. Azimi M, Akbari GH (2011) Development of nano-structure Cu–Zr alloys by the mechanical alloying process. J Alloys Compd 509:27–32

    Article  CAS  Google Scholar 

  22. Sivasankaran S, Sivaprasad K, Narayanasamy R, Iyer VK (2010) An investigation on flowability and compressibility of AA 606110 x-x wt.% TiO2 micro and nanocomposite powder prepared by blending and mechanical alloying. Powder Technollogy 201:70–82

    Article  CAS  Google Scholar 

  23. Fogagnolo JB, Ruiz-Navas EM, Robert MH, Torralba JM (2003) Effect of mechanical alloying on the morphology, microstructure and properties of aluminum matrix composite powders. Mater Sci Eng A 342:131–143

    Article  Google Scholar 

  24. RazaviTousi SS, Yazdani Rad R, Salahi E, Mobasherpour I, Razavi M (2009) Production of Al-20 wt.% Al2O3 composite powder using high energy milling. Powder Technollogy 192:46–51

    Google Scholar 

  25. Kursun C, Gogebakan M (2015) Characterization of nanostructured Mg–Cu–Ni powders prepared by mechanical alloying. J Alloys Compd 619:138–144

    Article  CAS  Google Scholar 

  26. Meyers MA, Mishra A, Benson DJ (2006) Mechanical properties of nanocrystalline materials. Progress Mater Sci 51:427–556

    Article  CAS  Google Scholar 

  27. Gamal GA, AbouZied M, Ebnalwaled AA (2012) Microstructural and electronic properties of In3Te4 single crystals. J Comput Eng Sci 5:175–188

    Google Scholar 

  28. Pourghahramani P, Forssberg E (2006) Microstructure characterization of mechanically activated hematite using XRD line broadening. J Mineral Process 79:106–119

    Article  CAS  Google Scholar 

  29. Ghosh J, Chattopadhayay SK, Meikap AK, Chatterjee SK (2008) Microstructure characterization of titanium-base aluminium alloys by X-ray diffraction using Warren-Averbach and Rietveld method. J Alloys Compd 453:131–137

    Article  CAS  Google Scholar 

  30. Abdoli H, Farnoush H, Salahi E, Pourazrang K (2008) Study of the densification of a nanostructured composite powder. Part 1: Effect of compaction pressure and reinforcement addition. Mater Sci Eng A 486:580–584

    Article  Google Scholar 

  31. Parvin N, Assadifard R, Safarzadeh P, Sheibani S, Marashi P (2008) Preparation and mechanical properties of SiC-reinforced Al6061 composite by mechanical alloying. Mater Sci Eng A 492(1–2):134–140

    Article  Google Scholar 

  32. Yazdian N, Karimzadeh F, Tavoosi M (2010) Microstructural evolution of nanostructure 7075 aluminum alloy during isothermal annealing. J Alloys Compd 493:137–141

    Article  CAS  Google Scholar 

Download references

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Correspondence to Rezvan Yavari.

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Noori, A.M., Yavari, R., Baharvandi, H. et al. Evaluation of Different Parameters on Production of Zr2Cu by Mechanical Alloying. Silicon 10, 1161–1169 (2018). https://doi.org/10.1007/s12633-017-9588-z

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  • DOI: https://doi.org/10.1007/s12633-017-9588-z

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