Log in

Synthesis of SnO2/Fe2O3 thin films for efficient photocatalytic degradation of methylene blue under sunlight

  • Research Article
  • Published:
Journal of Optics Aims and scope Submit manuscript

Abstract

This study discusses the surface effect of SnO2 and SnO2/α-Fe2O3 thin films prepared using the spray pyrolysis technique on the photocatalytic degradation of methylene blue MB under sunlight irradiation for different times. These layers were examined using X-ray diffraction (XRD), Raman spectroscopy and scanning electron microscopy (SEM) to determine their structural composition and morphological characteristics. X-ray diffraction shows that SnO2 thin films crystallize in a tetragonal structure with a preferential orientation along to (110), while SnO2/α-Fe2O3 multilayer crystallizes in a rhombohedral structure of α-Fe2O3, with the presence of some pick of the tetragonal SnO2. In addition, the grain size decreases from 48 nm for SnO2 thin films to 42 nm for SnO2/α-Fe2O3. It was also discovered that SnO2/α-Fe2O3 exhibits much improved photocatalytic performance with the degradation rate compared to SnO2 thin layer, which can be related to the surface roughness and crystallite size evaluated by XRD and SEM.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. A. Arfaoui, A. Mhamdi, N. Besrour, S. Touihri, H.I. Ouzari, Z.A. Alrowaili, M. Amlouk, Investigations into the physical properties of SnO2/MoO3 and SnO2/WO3 bi-layered structures along with photocatalytic and antibacterial applications. Thin Solid Films 648(9), 12–20 (2018)

    Article  ADS  Google Scholar 

  2. R. Han, Y. Yan, Electronic structure and magnetic properties of oxygen deficient low-index surfaces of SnO2. Surf. Sci. 649(8), 112–119 (2016)

    Article  ADS  Google Scholar 

  3. M. Batmunkh, M. Dadkhah, C.J. Shearer, M.J. Biggs, J.G. Shapter, Incorporation of graphene into SnO2 photoanodes for dye-sensitized solar cells. Appl. Surf. Sci. 387(8), 690–697 (2016)

    Article  ADS  Google Scholar 

  4. V.S. Anitha, S.S. Lekshmy, K. Joy, Effect of Mn do** on the structural, magnetic, optical and electrical properties of ZrO2–SnO2 thin films prepared by sol-gel method. J. Alloys Compd. 675(10), 331–340 (2016)

    Article  Google Scholar 

  5. X. Qian, X. Zhang, Y. Bai, T. Li, X. Tang, E. Wang et al., Photoelectrochemical characteristics of α-Fe2O3 nanocrystalline semiconductor thin film. J. Nanopart. Res. 2(8), 191–198 (2000)

    Article  ADS  Google Scholar 

  6. A.S.C. Brown, J.S.J. Hargreaves, B. Rijniersce, A Study of the structural and catalytic effects of sulfation on iron oxide catalysts prepared from goethite and ferrihydrite precursors for methane oxidation. Catal. Lett. 53(7), 7–13 (1998)

    Article  Google Scholar 

  7. Z. Dai, C.-S. Lee, Y. Tian, I.-D. Kim, J.-H. Lee, Highly reversible switching from P- to N-type NO2 sensing in a monolayer Fe2O3 inverse opal film and the associated P-N transition phase diagram. J. Mater. Chem. A Mater. 7(10), 3372–3381 (2015)

    Article  Google Scholar 

  8. N.V. Long, Y. Yang, M. Yuasa, C.M. Thi, Y. Cao, T. Nann et al., Gas-sensing properties of p-type α-Fe2O3 polyhedral particles synthesized via a modified polyol method. RSC Adv. 4(16), 8250 (2014)

    Article  ADS  Google Scholar 

  9. J. Ji, Y. Jia, Wu. Wenguo, L. Bai, L. Gea, Gu. Zhongze, A layer-by-layer self-assembled Fe2O3 nanorod-based composite multilayer film on ITO anode in microbial fuel cell. Colloids Surf A Physicochem Eng Asp 390(6), 56–61 (2011)

    Article  Google Scholar 

  10. T. Yuan, Y. Jiang, Y. Li, D. Zhang, Mi. Yan, Enhanced lithium storage performance in three-dimensional porous SnO2–Fe2O3 composite anode films. Electrochim. Acta 136(6), 27–32 (2014)

    Article  Google Scholar 

  11. M. Nasiri, P. Sangpour, S. Yousefzadeh, M. Bagheri, Elevated temperature annealed α-Fe2O3/reduced graphene oxide nanocomposite photoanode for photoelectrochemical water oxidation. J. Environ. Chem. Eng. 7(2), 102999 (2019)

    Article  Google Scholar 

  12. Z. Zhang, C. Gao, Y. Li, W. Han, Fu. Wenbin, Y. He, E. **e, Enhanced charge separation and transfer through Fe2O3/ITO nanowire arrays wrapped with reduced graphene oxide for water-splitting. Nano Energy 30(8), 892–899 (2016)

    Article  Google Scholar 

  13. M.M. Rahman, S.B. Khan, A. Jamal, M. Faisal, A.M. Asiri, Fabrication of a methanol chemical sensor based on hydrothermally prepared α-Fe2O3 codoped SnO2 nanocubes. Talanta 95, 18–24 (2012)

    Article  Google Scholar 

  14. B. Salah, A.I. Ayesh, Fabrication of H2S sensitive gas sensors formed of SnO2–Fe2O3 composite nanoparticles. Mater. Chem. Phys. 266, 124597 (2021)

    Article  Google Scholar 

  15. A. Arfaoui, S. Touihri, A. Mhamdi, A. Labidi, T. Manoubi, Structural, morphological, gas sensing and photocatalytic characterization of MoO3 and WO3 thin films prepared by the thermal vacuum evaporation technique. Appl. Surf. Sci. 357(8), 1089–1096 (2015)

    Article  ADS  Google Scholar 

  16. I. Riahi, B. Khalfallah, F. Chaabouni, Effect of deposition time on the photocatalytic activity of sputtered mixed ZnO–SnO2 thin films under visible light irradiation. Solid State Commun. 340, 114487 (2021)

    Article  Google Scholar 

  17. X. Cheng, J. Ding, Wu. Yangjiang, H. Liu, G. Dawson, The photocathodic properties of a Fe2O3 wrapped CuFeO2 layer on ITO glass for water splitting. Chem. Phys. 513(5), 241–245 (2018)

    Article  Google Scholar 

Download references

Acknowledgements

The authors extend their appreciation to the deanship of scientific research at Shaqra University for funding this research work through the project number (SU-ANN-202306).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Mhamdi.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mhamdi, A., Arfaoui, A. Synthesis of SnO2/Fe2O3 thin films for efficient photocatalytic degradation of methylene blue under sunlight. J Opt (2023). https://doi.org/10.1007/s12596-023-01555-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12596-023-01555-6

Keywords

Navigation