Log in

Recent progress in synthesis of antifogging agents and their application to agricultural films: a review

  • Review Paper
  • Published:
Journal of Coatings Technology and Research Aims and scope Submit manuscript

Abstract

Antifogging agents are very important for use on agricultural films. Fogging reduces crop yield and causes other negative effects. To overcome fogging problems on agricultural films, several approaches including surface coating and reactive extrusion methods have been used. To date, researchers have designed a variety of agents to prepare antifogging films. The mechanism and rules for the composition of such agents have also been reported. However, reported antifogging films do not exhibit satisfactory results. Therefore, antifogging methods require further improvement. In this review, different preparation methods for antifogging agents and films are summarized, along with the advantages and disadvantages of each method. Moreover, test methods for antifogging performance are introduced.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (France)

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Reproduced with permission from Royal Society of Chemistry

Fig. 8

Reproduced with permission from Royal Society of Chemistry

Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. Erbil, HY, “Contact Angle of Liquid Drops on Solids.” In: Moore, K (ed.) Surface Chemistry, pp. 308–337. Blackwell, Oxford (2009)

    Google Scholar 

  2. Pallas, NR, Harrison, Y, “An Automated Drop Shape Apparatus and the Surface Tension of Pure Water.” Colloids Surf., 43 169–194 (1990)

    Article  Google Scholar 

  3. Starkweather, HW, “The Surface Tension of Polyethylene.” Polym. Eng. Sci., 5 5–6 (1965)

    Article  Google Scholar 

  4. Tettey, KE, Dafinone, MI, Lee, D, “Progress in Superhydrophilic Surface Development.” Mater. Express, 1 89–104 (2011)

    Article  Google Scholar 

  5. Gao, X, Yan, X, Yao, X, Xu, L, Zhang, K, Zhang, J, Yang, B, Jiang, L, “The Dry-Style Antifogging Properties of Mosquito Compound Eyes and Artificial Analogues Prepared by Soft Lithography.” Adv. Mater., 19 2213–2217 (2007)

    Article  Google Scholar 

  6. Lee, H, Alcaraz, ML, Rubner, MF, Cohen, RE, “Zwitter–Wettability and Antifogging Coatings with Frost-Resisting Capabilities.” ACS Nano, 7 2172 (2013)

    Article  Google Scholar 

  7. Tang, XH, Wu, C, Li, C, Li, B, “Characteristics and Application of Fatty Alcohol Polyoxyethylene Ether.” Deterg. Cosmet., 35 22–24 (2012)

    Google Scholar 

  8. Wu, ZQ, “Applied Technique of Alkyl-Phenol-Ethoxylate.” Chem. Mater. Constr., 6 252–253 (1996)

    Google Scholar 

  9. Pasquali, RC, Helguera, GF, ““True” Hydrophilic-Lipophilic Balance of Polyoxyethylene Fatty Acid Esters Nonionic Surfactants.” J. Dispers. Sci. Technol., 34 716–721 (2013)

    Article  Google Scholar 

  10. Wang, F, Jia, LH, Wang, QB, Guo, XF, “Surface Activity of Mixed System Polyoxyethylene Alkylamine and Sodium Dodecylbenzene Sulfonat.” J. Qiqihar Univ., 3 11–13 (2012)

    Google Scholar 

  11. Giacometti, J, Milin, C, Wolf, N, Giacometti, F, “Process of Preparing Nonionic Surfactant Sorbitan Fatty Acid Esters with and Without Previous Sorbitol Cyclization.” J. Agric. Food Chem., 44 3950–3954 (1997)

    Article  Google Scholar 

  12. Li, M, Cao, C, **ong, K, Du, F, “Effect of Hydrophobic Chain Length on the Interfacial Dilational Rheological Properties of Polyoxyethylene Sorbitan Fatty Acid Ester.” Acta Phys. Chim. Sin., 31 322–328 (2015)

    Google Scholar 

  13. Zhou, L, “Effect of Polyglycerol Fatty Acid Ester on Antifogging Property of Agricultural Films.” Mod. Plast. Process. Appl., 21 40–42 (2009)

    Google Scholar 

  14. Zhou, LG, Zhang, JY, Wang, YB, Liu, XY, “Synthesis and Antifogging Property of Polyglycerol Ester of Perfluorocaprylic Acid.” China Surfactant Deterg. Cosmet., 39 234–237 (2009)

    Google Scholar 

  15. **ao, H, Li, G, Sui, H, Jiao, F, “The Synthesis, Characteristics and Application of New Silicone Surfactants.” J. **an Univ., 4 65–71 (1998)

    Google Scholar 

  16. Liu, XY, “Study on Antifogging Property of Polyglycerol Ester with Gemini Stearic Acid.” J. Anhui Agric. Sci., 38 7564–7565 (2010)

    Google Scholar 

  17. Zhou, LG, Wang, JY, Zhang, WJ, “Effect of Compound Surfactant on Dripless Capability of Plastics Film.” China Plast. Ind., 36 207–209 (2008)

    Google Scholar 

  18. Cao, Y, “Research Progress of Antifogging Technologies for Plastics Films.” China Plast., 10 11–14 (2000)

    Google Scholar 

  19. Li, J, “Effect of PVA on Anti Fogging Property of Anti Fogging PE Film.” China Plast. Ind., 27 41–42 (1999)

    Google Scholar 

  20. Lu, G, Li, S, “Study on Anti-fog Films of Polyethylene Modified with Inorganic Nano-powders.” China Synth. Resin Plast., 21 51–54 (2004)

    Google Scholar 

  21. Shlosman, K, Ran, YS, Rosen-Kligvasser, J, Tchoudakov, R, Zelikman, E, Semiat, R, Narkis, M, “Controlled Migration of Antifog Additives from LLDPE Compatibilized with LLDPE Grafted Maleic Anhydride.” Polym. Adv. Technol., 25 1484–1491 (2014)

    Article  Google Scholar 

  22. Rosen-Kligvasser, J, Ran, YS, Tchoudakov, R, Narkis, M, “A Novel Methodology for Controlled Migration of Antifog from Thin Polyolefin Films.” Polym. Eng. Sci., 54 2023–2028 (2013)

    Article  Google Scholar 

  23. Gao, N, Liu, T, “Development Research on Plastic Anti-fogging Agents.” New Technol. New Process, 4 98–101 (2014)

    Google Scholar 

  24. Wang, J, “The Study on the Antifogging Performances of Compound Antifogging Agents.” Unpublished master dissertation, Shandong Polytechnic University, 2008

  25. Park, S, Park, S, Jang, DH, Lee, HS, Park, CH, “Anti-fogging Behavior of Water-Absorbing Polymer Films Derived from Isosorbide-Based Epoxy Resin.” Mater. Lett., 180 81–84 (2016)

    Article  Google Scholar 

  26. Cai, MJ, Li, QQ, Chen, XM, “Synthesis, Surface Activity, and Antifogging Property of Triethanolamine Monolaurate Ester.” Chin. J. Chem. Phys., 28 223–229 (2015)

    Article  Google Scholar 

  27. Zhang, W, Zhou, L, Ding, Z, “Synthesis and Performance of Nonionic Gemini Surfactant Di-Glycerol 2,9-Dihexyldecanedioate.” J. Dispers. Sci. Technol., 30 1161–1166 (2009)

    Article  Google Scholar 

  28. Fu, Z, Liu, M, Xu, J, Wang, Q, Fan, Z, “Surface Modification of Linear Low-Density Polyethylene Film by Amphiphilic Graft Copolymers Based on Poly(higher α-Olefin)-Graft-Poly(Ethylene Glycol).” J. Appl. Polym. Sci., 119 1111–1121 (2011)

    Article  Google Scholar 

  29. Liu, M, Fu, Z, Wang, Q, Xu, J, Fan, Z, “Study of Amphiphilic Poly(1-dodecene-co-para-methylstyrene)-graft-poly (ethylene glycol). Part I: Preparation of poly(1-dodecene-co-para-methylstyrene) Copolymer and Its Molecular Weight Regulation.” Eur. Polym. J., 44 3239–3245 (2008)

    Article  Google Scholar 

  30. Liu, M, Fu, Z, Wang, Q, Xu, J, Fan, Z, “Study of Amphiphilic Poly(1-dodecene-co-para-methylstyrene)-graft-poly (ethylene glycol)Part II: Preparation and Micellization Behavior of the Amphiphilic Copolymers.” Eur. Polym. J., 44 4122–4128 (2008)

    Article  Google Scholar 

  31. Kasanen, J, Suvanto, M, Pakkanen, TT, “Self-Cleaning, Titanium Dioxide Based, Multilayer Coating Fabricated on Polymer and Glass Surfaces.” J. Appl. Polym. Sci., 111 2597–2606 (2009)

    Article  Google Scholar 

  32. Goddard, JM, Hotchkiss, JH, “Polymer Surface Modification for the Attachment of Bioactive Compounds.” Prog. Polym. Sci., 32 698–725 (2007)

    Article  Google Scholar 

  33. Wang, B, Ma, H, Liu, W, “Polyolefine Surface Oxidation.” Chem. Ind. Eng., 16 208–212 (1999)

    Google Scholar 

  34. Rasmussen, JR, Stedronsky, ER, Whitesides, GM, “Introduction, Modification, and Characterization of Functional Groups on the Surface of Low-density Polyethylene Film.” J. Am. Chem. Soc., 99 4736–4745 (1977)

    Article  Google Scholar 

  35. Janssen, LPBM, “On the Stability of Reactive Extrusion.” Polym. Eng. Sci., 38 2010–2019 (1998)

    Article  Google Scholar 

  36. Siddiqa, AJ, Chaudhury, K, Adhikari, B, “Letrozole Dispersed on Poly (vinyl alcohol) Anchored Maleic Anhydride Grafted Low Density Polyethylene: A Controlled Drug Delivery System for Treatment of Breast Cancer.” Colloids Surf. B Biointerfaces, 116 169–175 (2014)

    Article  Google Scholar 

  37. Jeong, E, Bae, T-S, Yun, S-M, Woo, S-W, Lee, Y-S, “Surface Characteristics of Low-Density Polyethylene Films Modified by Oxyfluorination-Assisted Graft Polymerization.” Colloids Surf. A Physicochem. Eng. Asp., 373 36–41 (2011)

    Article  Google Scholar 

  38. Yao, Z, Yin, J, Song, Y, Jiang, G, Song, Y, “Preparation and Properties of a Novel Nonionic Surfactant Grafted Linear Low Density Polyethylene.” J. Macromol. Sci. Part A Pure Appl. Chem., 44 963–968 (2007)

    Article  Google Scholar 

  39. Li, W, Yao, R, Lin, Y, Yao, Z, Liu, S, Li, L, “Preparation, Characterization and Properties of Reactive Type Drip** Agent Tween 60-IAH and Their Grafting Copolymer With Linear Low Density Polyethylene.” J. Macromol. Sci. Part A Pure Appl. Chem., 52 492–497 (2015)

    Article  Google Scholar 

  40. Li, W, Yao, R, Yao, Z, Liu, S, Li, L, “Pre-irradiation Grafting of Span 60-IAH onto Polyethylene to Improve Drip** Properties of Water on Polyethylene Films.” J. Macromol. Sci. Part A Pure Appl. Chem., 54 47–51 (2017)

    Article  Google Scholar 

  41. **n, ZR, Yan, SJ, Du, BB, Du, SS, Liu, C, Stagnaro, P, “On Properties of Graft Copolymers of LLDPE and Novel Fluorine Surfactants Obtained via Reactive Extrusion.” Des. Monomers Polym., 17 746–752 (2014)

    Article  Google Scholar 

  42. Hou, JZ, Zhang, WX, Kong, LW, Li, LL, “Preparation and Characterization of PEs Grafted with Acrylic-based Monomers.” Acta Polym. Sin., 9 1070–1077 (2015)

    Google Scholar 

  43. Li, W, Yao, Z, Jiang, G, Zheng, X, Li, L, Yin, J, “Preparation, Characterization, and Properties of Pre-irradiated Linear Low-Density Polyethylene Grafted Itaconic Anhydride by Reactive Extrusion.” J. Macromol. Sci. Part B Phys., 49 75–85 (2010)

    Article  Google Scholar 

  44. Ciolino, AE, Failla, MD, Vallés, EM, “Melt Grafting of N-carbamyl Maleamic Acid onto Linear Low-Density Polyethylene.” J. Polym. Sci. Part A Polym. Chem., 40 3950–3958 (2002)

    Article  Google Scholar 

  45. Jahani, Y, Valavi, A, Ziaee, F, “Reactive Melt Modification of Polyethylene by Ethyl Acrylate/Acrylic Acid Copolymers: Rheology.” Morphol. Therm. Behav. Iran. Polym. J., 24 1–10 (2015)

    Google Scholar 

  46. Yao, Z, Yin, J, Jiang, G, Song, Y, “Preparation and Properties of Polyether Pentaerythritol Mono-maleate Grafted Linear Low Density Polyethylene by Reactive Extrusion.” J. Macromol. Sci. Part A Pure Appl. Chem., 45 295–301 (2008)

    Article  Google Scholar 

  47. **ao Li, C, BingHai, L, “Grafting of LLDPE with Maleic Anhydride by Reactive Extrusion.” Plastics, 34 6–9 (2005)

    Google Scholar 

  48. Ding, S, Liu, M, “The Effect of Feed Composition of Styrene and Acrylic Acid on the Properties of Modified Low Density Polyethylene.” Macromol. Symp., 257 162–170 (2008)

    Article  Google Scholar 

  49. Saki, TA, “Reactive Melt Blending of Low-Density Polyethylene with Poly (Acrylic Acid).” Arab. J. Chem., 8 191–199 (2015)

    Article  Google Scholar 

  50. Hassan, MM, Koyama, K, “Thermal, Physico-mechanical, and Morphological Properties of HDPE Graft-Copolymerized with Polystyrene.” Polym. Adv. Technolog., 26 1285–1293 (2015)

    Article  Google Scholar 

  51. Wang, H, Xu, L, Li, R, Pang, L, Hu, J, Wang, M, Wu, G, “Highly Hydrophilic Ultra-High Molecular Weight Polyethylene Powder and Film Prepared by Radiation Grafting of Acrylic Acid.” Appl. Surf. Sci., 382 162–169 (2016)

    Article  Google Scholar 

  52. Kobayashi, M, Matsugi, T, Saito, J, Imuta, JI, Kashiwa, N, Takahara, A, “Direct Modification of Polyolefin Films by Surface-Initiated Polymerization of a Phosphobetaine Monomer.” Polym. Chem., 4 731–739 (2013)

    Article  Google Scholar 

  53. Shentu, BQ, Zhao, L, Weng, ZX, “Improvement of Antifogging of Low Density Polyethylene Film by Photografting Acrylic Acid.” China Plast., 16 51–54 (2002)

    Google Scholar 

  54. Pascual, M, Sanchis, R, Sanchez, L, Garcia, D, Balart, R, “Surface Modification of Low Density Polyethylene (LDPE) Film Using Corona Discharge Plasma for Technological Applications.” J. Adhes. Sci. Technol., 22 1425–1442 (2008)

    Article  Google Scholar 

  55. Karam, L, Casetta, M, Chihib, NE, Bentiss, F, Maschke, U, Jama, C, “Optimization of Cold Nitrogen Plasma Surface Modification Process for Setting up Antimicrobial Low Density Polyethylene Films.” J. Taiwan Inst. Chem. Eng., 64 299–305 (2016)

    Article  Google Scholar 

  56. Sanchis, MR, Blanes, V, Blanes, M, Garcia, D, Balart, R, “Surface Modification of Low Density Polyethylene (LDPE) Film by Low Pressure O2 Plasma Treatment.” Eur. Polym. J., 42 1558–1568 (2006)

    Article  Google Scholar 

  57. Aziz, G, Geyter, ND, Declercq, H, Cornelissen, R, Morent, R, “Incorporation of Amine Moieties onto Ultra-High Molecular Weight Polyethylene (UHMWPE) Surface via Plasma and UV Polymerization of Allylamine.” Surf. Coat. Technol., 271 39–47 (2015)

    Article  Google Scholar 

  58. Wang, P, Tan, KL, Kang, ET, Neoh, KG, “Surface Functionalization of Low Density Polyethylene Films with Grafted Poly(ethylene glycol) Derivatives.” J. Mater. Chem., 11 2951–2957 (2001)

    Article  Google Scholar 

  59. Wei, J, Luo, X, Lin, X, Zhang, H, “Impact of Monoolein on the Anti-Fogging Property of Polyethylene Greenhouse Film.” Polym. Mater. Sci. Eng., 29 71–73 (2013)

    Google Scholar 

  60. Dou, Y, Zhou, L, Dou, P, “Study on Glycerol Esters as Antifogging Agents.” Plast. Sci. Technol., 36 76–78 (2008)

    Google Scholar 

Download references

Acknowledgments

The authors gratefully acknowledge the support of the National Key Research and Development Program (2016YFB0302403) and Zhejiang University.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Li Wang or Haojie Yu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ren, S., Wang, L., Yu, H. et al. Recent progress in synthesis of antifogging agents and their application to agricultural films: a review. J Coat Technol Res 15, 445–455 (2018). https://doi.org/10.1007/s11998-018-0051-x

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11998-018-0051-x

Keywords

Navigation