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Hydrogen production by catalytic steam reforming of waste cooking oil over La-Ni/ZSM-5 catalyst

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Abstract

Ni/ZSM-5 catalyst is one of the promising catalysts to improve the catalytic steam reforming of waste cooking oil (WCO) for hydrogen production. Furthermore, the introduction of lanthanum (La) plays a huge role in inhibiting metal sintering and carbon deposition and improving the stability and activity of the catalyst. This study investigated the effects of reaction temperature (600–800 °C), steam to carbon molar ratio (S/C), n Ni/ZSM-5 (n=5, 10, and 15 wt%), and the addition of promoter (La) on the experimentally generated hydrogen yield and carbon deposition. Results showed that the experiment used 6 wt% La-10 wt% Ni/ZSM-5 at 0.1 MPa, 700 °C, space-time (τ)=0.56 gcatalyst/gWCO, and S/C=5.25, which obtained the yield of H2 was 154.12 mol/kg, carbon deposition was 5.38%. Therefore, Ni-modified catalyst added La to improve the catalyst coking resistance and prevent carbon formation. Moreover, La can further promote the dispersion of nickel on the surface of the carrier and improve the catalytic performance of the catalyst for steam reforming reaction.

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Acknowledgements

The authors express their great appreciation for the financial support of this project by the National Natural Science Foundation of China (51676081), Wuhan Enterprise Technology Innovation Projects (2019020702011359; 2020020602012150), and the 111 Project B17019. Additionally, the authors would like to thank the Shiyanjia Lab (https://www.shiyanjia.com) for the support of SEM and NH3-TPD tests.

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Authors and Affiliations

  1. Chemistry College, Central China of Normal University, Wuhan, 430079, China

    Na **ao, Rui Zhao, Yufei Liu, Wei Zhan, Yonghui Xu & Zhengshun Wu

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  1. Na **ao
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  2. Rui Zhao
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  3. Yufei Liu
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  4. Wei Zhan
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  5. Yonghui Xu
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  6. Zhengshun Wu
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Correspondence to Zhengshun Wu.

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**ao, N., Zhao, R., Liu, Y. et al. Hydrogen production by catalytic steam reforming of waste cooking oil over La-Ni/ZSM-5 catalyst. Korean J. Chem. Eng. 40, 2174–2186 (2023). https://doi.org/10.1007/s11814-023-1459-2

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