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Adsorption Capacity and Mechanism of MgO Nanomaterials Prepared by Ultrasonic Electrodeposition for Pb (II)

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Abstract

This study reports the successful preparation of MgO nanomaterials through ultrasonic electrodeposition. The capability and mechanism of nanomaterials in removing Pb (II) from industrial soil under varying ultrasonic powers of 100, 150, and 200 W were investigated. Scanning electron microscopy (SEM), Transmission electron microscope (TEM), and x-ray diffractometry (XRD) were employed to analyze the surface morphology and phase composition of the nanomaterials. The adsorption capacity of MgO nanomaterials for Pb (II) was significantly enhanced at an ultrasonic power of 150 W, reaching a maximum adsorption capacity of 68.9 mg g−1. The adsorption process of Pb (II) onto the surface of MgO nanomaterials was analyzed using pseudo-second-order kinetic and Langmuir models. The formation of strong chemical bonds between Pb (II) and atoms on the surface of MgO nanomaterials resulted in the unique monolayer adsorption and chemisorption characteristics observed for Pb (II), as confirmed through Fourier transform infrared spectroscopy (FTIR) analysis. MgO nanomaterials revealed distinctive monolayer adsorption and chemisorption properties for the adsorption of Pb (II). The adsorption capacity of MgO nanomaterials for Pb (II) was significantly affected by temperature, with the highest adsorption amount observed at 30 °C. Moreover, the Langmuir model effectively described the adsorption behavior of MgO for Pb (II), displaying a correlation coefficient exceeding 0.99. The results reveal the influence of ultrasonic power on the adsorption capabilities of MgO nanomaterials prepared via ultrasonic electrodeposition, with optimal adsorption performance observed for MgO nanomaterials prepared at 150 W. Moreover, the MgO nanomaterials fabricated with 150 W ultrasonic power demonstrate good pH adaptability.

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Acknowledgments

This paper was supported by the Liaoning Provincial Engineering Research Center for High-Value Utilization of Magnesite (Granted nos. LMNKY202310, LMNKZ202303 and LMNKY202309), Basic scientific research project of Liaoning Provincial Department of Education (Granted no. JYTMS20230067), General project of Education Department of Liaoning Province (Granted no. LJKZ1196), and Intercollegiate Cooperation (Collaborative Innovation) project of ordinary undergraduate colleges and universities in Liaoning Province (Granted no. L202161).

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  1. Liaoning Provincial Engineering Research Center for High-Value Utilization of Magnesite, Yingkou, 115014, China

    Quanqing Zhang, Zhiru Zhao, Lijie He, Guangle Tan, Lili Guo & Wei Zheng

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Zhang, Q., Zhao, Z., He, L. et al. Adsorption Capacity and Mechanism of MgO Nanomaterials Prepared by Ultrasonic Electrodeposition for Pb (II). J. of Materi Eng and Perform (2024). https://doi.org/10.1007/s11665-024-09556-7

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