Log in

Thermoelectric Properties of Y1−x Ag x BaCo4O7+δ Ceramics

  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

The thermoelectric properties of the Ag-doped ceramics Y1−x Ag x BaCo4O7+δ (x = 0.0, 0.05, 0.1, 0.15, and 0.2) were investigated from 373 K to 973 K. The results show that the do** of Ag can reduce the electrical resistivity. The Seebeck coefficients of the samples decrease when the Ag do** amount is small, but increase when the Ag do** amount is large. The activation energy of the electrical conductivity was calculated using Arrhenius plots, and it was found that the activation energy descends with increase of the Ag do** amount. According to the power factors, the optimum Ag do** amount is x = 0.15, which results in a higher power factor of 81 μW m−1 K−2 at 973 K, 72.7% higher than for the sample without Ag do**.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (United Kingdom)

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A.J. Minnich, M.S. Dresselhaus, Z.F. Ren, and G. Chen, Energy Environ. Sci. 2, 466 (2009).

    Article  CAS  Google Scholar 

  2. J. He, Y. Liu, and R. Funahashi, J. Mater. Res. 26, 1762 (2011).

    Article  CAS  Google Scholar 

  3. I. Terasaki, Y. Sasago, and K. Uchinokura, Phys. Rev. B 56, R12685 (1997).

    Article  CAS  Google Scholar 

  4. M. Valldor and M. Andersson, Solid State Sci. 4, 923 (2002).

    Article  CAS  Google Scholar 

  5. M. Valldor, Solid State Sci. 6, 251 (2004).

    Article  CAS  Google Scholar 

  6. A. Huq, J.F. Mitchell, H. Zheng, L.C. Chapon, P.G. Radaelli, K.S. Knight, and P.W. Stephens, J. Solid State Chem. 179, 1136 (2006).

    Article  CAS  Google Scholar 

  7. L.C. Chapon, P.G. Radaelli, H. Zheng, and J.F. Mitchell, Phys. Rev. B 74, 172401 (2006).

    Article  Google Scholar 

  8. B. Raveau, V. Caignaert, V. Pralong, D. Pelloquin, and A. Maignan, Chem. Mater. 20, 6295 (2008).

    Article  CAS  Google Scholar 

  9. V. Caignaert, A. Maignan, V. Pralong, S. Hebert, and D. Pelloquin, Solid State Sci. 8, 1160 (2006).

    Article  CAS  Google Scholar 

  10. V.B. Vert, J.M. Serra, and J.L. Jorda, Electrochem. Commun. 12, 278 (2010).

    Article  CAS  Google Scholar 

  11. K. Zhang, Z. Zhu, R. Ran, Z. Shao, W. **, and S. Liu, J. Alloy Compd. 492, 552 (2010).

    Article  CAS  Google Scholar 

  12. A. Maignan, V. Caignaert, D. Pelloquin, S. Hébert, V. Pralong, J. Hejtmanek, and D. Khomskii, Phys. Rev. B 74, 165110 (2006).

    Article  Google Scholar 

  13. H.S. Hao, C.Q. Chen, L.J. Pan, J.X. Gao, and X. Hu, Phys. B 387, 98 (2007).

    Article  CAS  Google Scholar 

  14. H.S. Hao, X.T. Zhang, Q.L. He, C.Q. Chen, and X. Hu, Solid State Commun. 141, 591 (2007).

    Article  CAS  Google Scholar 

  15. S. Wang, H. Hao, B. Zhu, J. Jia, and X. Hu, J. Mater. Sci. 43, 5385 (2008).

    Article  CAS  Google Scholar 

  16. N.V. Nong, N. Pryds, S. Linderoth, and M. Ohtaki, Adv. Mater. 23, 2484 (2011).

    Article  Google Scholar 

  17. L.H. Yin, R. Ang, B.C. Zhao, Y.N. Huang, Y. Liu, S.G. Tan, W.H. Song, and Y.P. Sun, Solid State Commun. 158, 16 (2013).

    Article  CAS  Google Scholar 

  18. S. Kolesnik, B. Dabrowski, O. Chmaissem, K. Wojciechowski, and K. Swierczek, J. Appl. Phys 111, 07D727 (2012).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to H. Z. Song.

Rights and permissions

Reprints and permissions

About this article

Cite this article

He, Q.L., Zhang, J., Gao, F. et al. Thermoelectric Properties of Y1−x Ag x BaCo4O7+δ Ceramics. J. Electron. Mater. 42, 2570–2573 (2013). https://doi.org/10.1007/s11664-013-2631-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-013-2631-y

Keywords

Navigation