Abstract
The thermoelectric properties of the Ag-doped ceramics Y1−x Ag x BaCo4O7+δ (x = 0.0, 0.05, 0.1, 0.15, and 0.2) were investigated from 373 K to 973 K. The results show that the do** of Ag can reduce the electrical resistivity. The Seebeck coefficients of the samples decrease when the Ag do** amount is small, but increase when the Ag do** amount is large. The activation energy of the electrical conductivity was calculated using Arrhenius plots, and it was found that the activation energy descends with increase of the Ag do** amount. According to the power factors, the optimum Ag do** amount is x = 0.15, which results in a higher power factor of 81 μW m−1 K−2 at 973 K, 72.7% higher than for the sample without Ag do**.
Similar content being viewed by others
References
A.J. Minnich, M.S. Dresselhaus, Z.F. Ren, and G. Chen, Energy Environ. Sci. 2, 466 (2009).
J. He, Y. Liu, and R. Funahashi, J. Mater. Res. 26, 1762 (2011).
I. Terasaki, Y. Sasago, and K. Uchinokura, Phys. Rev. B 56, R12685 (1997).
M. Valldor and M. Andersson, Solid State Sci. 4, 923 (2002).
M. Valldor, Solid State Sci. 6, 251 (2004).
A. Huq, J.F. Mitchell, H. Zheng, L.C. Chapon, P.G. Radaelli, K.S. Knight, and P.W. Stephens, J. Solid State Chem. 179, 1136 (2006).
L.C. Chapon, P.G. Radaelli, H. Zheng, and J.F. Mitchell, Phys. Rev. B 74, 172401 (2006).
B. Raveau, V. Caignaert, V. Pralong, D. Pelloquin, and A. Maignan, Chem. Mater. 20, 6295 (2008).
V. Caignaert, A. Maignan, V. Pralong, S. Hebert, and D. Pelloquin, Solid State Sci. 8, 1160 (2006).
V.B. Vert, J.M. Serra, and J.L. Jorda, Electrochem. Commun. 12, 278 (2010).
K. Zhang, Z. Zhu, R. Ran, Z. Shao, W. **, and S. Liu, J. Alloy Compd. 492, 552 (2010).
A. Maignan, V. Caignaert, D. Pelloquin, S. Hébert, V. Pralong, J. Hejtmanek, and D. Khomskii, Phys. Rev. B 74, 165110 (2006).
H.S. Hao, C.Q. Chen, L.J. Pan, J.X. Gao, and X. Hu, Phys. B 387, 98 (2007).
H.S. Hao, X.T. Zhang, Q.L. He, C.Q. Chen, and X. Hu, Solid State Commun. 141, 591 (2007).
S. Wang, H. Hao, B. Zhu, J. Jia, and X. Hu, J. Mater. Sci. 43, 5385 (2008).
N.V. Nong, N. Pryds, S. Linderoth, and M. Ohtaki, Adv. Mater. 23, 2484 (2011).
L.H. Yin, R. Ang, B.C. Zhao, Y.N. Huang, Y. Liu, S.G. Tan, W.H. Song, and Y.P. Sun, Solid State Commun. 158, 16 (2013).
S. Kolesnik, B. Dabrowski, O. Chmaissem, K. Wojciechowski, and K. Swierczek, J. Appl. Phys 111, 07D727 (2012).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
He, Q.L., Zhang, J., Gao, F. et al. Thermoelectric Properties of Y1−x Ag x BaCo4O7+δ Ceramics. J. Electron. Mater. 42, 2570–2573 (2013). https://doi.org/10.1007/s11664-013-2631-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11664-013-2631-y