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The Influence of Cu on Combustion Synthesis Mechanism of Ti–Al Intermetallic Compounds Produced From Ti and Al Elemental Powders

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Abstract

The influence of slight content of Cu as an additive on the reaction mechanism and microstructure of Ti–Al intermetallic compounds, during sintering process of Ti and Al elemental powders, was investigated. High-purity powders of Al, Ti, and Cu were used. The molar ratio of Ti/Al was equal to one. Considerable changes in reaction mechanism and heat of formation for different samples with different heating rates and different additive contents during combustion synthesis process were observed. The temperature was monitored by a data acquisition system or DAS. The samples were analyzed by XRD and SEM techniques. According to the experimental findings, complete formation of products was achieved at distinct additive content and heating rate. The initial reaction temperature and the samples’ porosities were lowered by the addition of Cu. The sample hardness varied depending on the heating rate and Cu content.

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Notes

  1. Data Acquisition System

  2. low heating rate

  3. high heating rate

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Authors and Affiliations

  1. School of Metallurgy and Materials Engineering, Iran University of Science and Technology, Narmak, Tehran, 1684613114, Iran

    Mohammad Jafarzadeh

  2. Iran University of Science and Technology (IUST), Tehran, 1684613114, Iran

    Mansour Soltanieh

  3. Birjand University of Technology, Birjand, 9717434765, Iran

    Razieh Khoshhal

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  1. Mohammad Jafarzadeh
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Jafarzadeh, M., Soltanieh, M. & Khoshhal, R. The Influence of Cu on Combustion Synthesis Mechanism of Ti–Al Intermetallic Compounds Produced From Ti and Al Elemental Powders. Metall Mater Trans A 54, 3537–3549 (2023). https://doi.org/10.1007/s11661-023-07111-y

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