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Application of beam irradiation in preparation of visible light responsive TiO2 films

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  • Published:
Frontiers of Chemistry in China

Abstract

TiO2 films were prepared by sol-gel method. In order to improve the utilization of light, the technologies of implantation of transition metal ions (V+ and Cr+) and electron beam irradiation to deposit noble metal particles (Ag and Pt) were used. A red shift was found in the spectrum of modified TiO2 films. The photocatalytic experiments showed that the photocatalytic ability under visible light irradiation could be improved dramatically by both the implantation of transition metal and the electron beam irradiation.

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References

  1. Fujishima A, Rao T N, Tryk D A. Titanium dioxide photoctalysis. J Photochem Photobiol C, 2000, 1(1): 1–21

    Article  CAS  Google Scholar 

  2. Carp O, Huisman C L, Reller A. Photoinduced reactivity of titanium dioxide. Prog Solid State Chem, 2004, 32(1–2): 33–177

    Article  CAS  Google Scholar 

  3. Youngmin C, Hyunsook K, Wonyong C. Visible light activity of TiO2 for the photoreduction of CCl4 and Cr(VI) in the presence of nonionic surfactant (Brij). Appl Catal B, 2004, 52(1): 23–32

    Article  Google Scholar 

  4. Arabatzis I M, Stergiopoulos T, Bernard M C, Labou D, Neophytides S G, Falaras P. Silver-modified titanium dioxide thin films for efficient photodegradation of methyl orange. Appl Catal B, 2003, 42(2): 187–201

    Article  CAS  Google Scholar 

  5. Li F B, Li X Z. The enhancement of photodegradation efficiency using Pt-TiO2 catalyst. Chemosphere, 2002, 48(10): 1,103–1,111

    Article  CAS  Google Scholar 

  6. Hou X G, Hao F H, Fan B, Gu X N, Wu X Y, Liu A D. Modification of TiO2 photocatalytic films by V+ ion implantation. Nucl Instrum Meth B, 2006, 243(1): 99–102

    Article  CAS  Google Scholar 

  7. Gu X N, Ye M, Wu X L, Wei L, Hu Y, Hou X G, Liu X G, Liu A D. Deposition of silver on titania films by electron beam irradiation. Nucl Instrum Meth B, 2006, 247(2): 279–284

    Article  CAS  Google Scholar 

  8. Yamashita H, Harada M, Misaka J, Takeuchi M, Ikeue K, Anpo M. Degradation of propanol diluted in water under visible light irradiation using metal ion-implanted titanium dioxide photocatalysts. J Photochem Photobio A, 2002, 148(1–3): 257–261

    Article  CAS  Google Scholar 

  9. Yamashita H, Harada M, Misaka J, Takeuchi M, Neppolian B, Anpo M. Photocatalytic degradation of organic compounds diluted in water using visible light-responsive metal ion-implanted TiO2 catalysts: Fe ion-implanted TiO2. Catal Today, 2003, 84(3–4): 191–196

    Article  CAS  Google Scholar 

  10. Liu A D, Zhang H X, Zhang T H. MEVVA ion source development and its industrial application at Bei**g Normal University. Surf Coat Tech, 2005, 193: 65–68

    Article  CAS  Google Scholar 

  11. Jun J, Dhayalb M, Shina J H, Kimc J C, Getoff N. Surface properties and photoactivity of TiO2 treated with electron beam. Radiat Phys Chem, 2006, 75(5): 583–589

    Article  CAS  Google Scholar 

  12. Sahyun M R V, Serpone N. Primary events in the photocatalytic deposition of silver on nanoparticulate TiO2. Langmuir, 1997, 13(19): 5,082–5,088

    Article  CAS  Google Scholar 

  13. Beydoun D, Amal R. Implications of heat treatment on the properties of a magnetic iron oxide-titanium dioxide photocatalyst. Mat Sci Eng B, 2002, 94(1): 71–81

    Article  Google Scholar 

  14. Michaelson H B. The work function of the elements and its periodicity. J Appl Phys, 1977, 48(11): 4,729–4,733

    Article  CAS  Google Scholar 

  15. Tan T T Y, Yip C K, Beydoun D, Amal R. Effects of nano-Ag particles loading on TiO2 photocatalytic reduction of selenate ions. Chem Eng J, 2003, 95(1–3): 179–186

    Article  CAS  Google Scholar 

  16. Liu S X, Qu Z P, Han X W, Sun C L, Bao X H. Chin J Catal, 2004, 25(2): 133–137 (in Chinese)

    CAS  Google Scholar 

  17. Nishikawa T, Nakajima T, Shinohara Y. An exploratory study on effect of the isomorphic replacement of Ti4+ ions by various metal ions on the light absorption character of TiO2. J Mol Struc-Theochem, 2001, 545: 67–74

    Article  CAS  Google Scholar 

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Correspondence to Liu Andong.

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Translated from Chinese Journal of Catalysis, 2007, 28(1): 39–44 [译自: 催化学报]

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Hou, X., Liu, A. Application of beam irradiation in preparation of visible light responsive TiO2 films. Front. Chem. China 2, 387–392 (2007). https://doi.org/10.1007/s11458-007-0073-x

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  • DOI: https://doi.org/10.1007/s11458-007-0073-x

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