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Mechanism of Pd(II) adsorption by nanoscale titanium dioxide loaded bamboo shoot shell biomass

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Abstract

Palladium (Pd) is widely used in catalyst, aerospace, and medical applications, but only 1% of its reserves are found in nature. So, the recovery of Pd(II) is very important. Natural fibers are a good adsorption material, and the abundant functional groups in bamboo shoot shell (BSS) fibers can form interactions with metal particles. However, few studies on Pd(II) adsorption using BSS fibers exist. In the present work, waste bamboo shoot shells were doped with titanium dioxide (TiO2) particles, and the surface activation of BSS-TiO2@CA by citric acid (CA) was carried out to prepare an efficient and recyclable adsorbent BSS-TiO2@CA for the adsorption of Pd(II). The adsorption performance, adsorption mechanism, and regeneration performance of BSS-TiO2@CA on Pd(II) were systematically analyzed by continuous adsorption experiments, characterization, and response surface method. It was found that the surface-activated waste bamboo shoot shells had an outstanding adsorption capacity of Pd(II), and the maximum adsorption rate of BSS-TiO2@CA reached 85% with a maximum adsorption capacity (Qm) of 175.74 mg/g. The functionalized use of waste bamboo shoot shells provides a new idea for the development of sustainable, cost-effective, and environmentally friendly adsorbents.

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Acknowledgements

This work is supported by the National Natural Science Foundation of China (Grant No. 51861006) and the Guangxi Natural Science Foundation (Grant No. 2022GXNSFAA035587). The foundation of the Engineering Research Center of Electronic Information Materials and Devices, Ministry of Education, Guilin University of Electronic Technology (Grant No. EIMD-AB202003).

Funding

This work is supported by the National Natural Science Foundation of China (Grant No. 51861006), and Guangxi Natural Science Foundation (Grant No. 2022GXNSFAA035587). The foundation of Engineering Research Center of Electronic Information Materials and Devices,Ministry of Education, Guilin University of Electronic Technology (Grant No. EIMD-AB202003).

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Yang Jie wrote the whole paper and the design and completion of the experiment, Liu Songlin and Long Qianxin completed the revision and review of the paper and guided the process of the experiment, Xu **aoxi and Pan Baiyang prepared the instruments and experimental supplies used for the whole experiment, and the rest of the authors supervised the process of the experiment, confirmed the experimental protocol, and gave the framework of the experiment. All authors reviewed the manuscript.

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Correspondence to Qianxin Long.

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Yang, J., Liu, S., Xu, X. et al. Mechanism of Pd(II) adsorption by nanoscale titanium dioxide loaded bamboo shoot shell biomass. Environ Sci Pollut Res 30, 113394–113408 (2023). https://doi.org/10.1007/s11356-023-30377-z

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