Log in

The Thermocatalytic Cracking Process for the Production of Light Olefins and Transportation Fuels from Gas Oils

  • Original Paper
  • Published:
Topics in Catalysis Aims and scope Submit manuscript

The thermocatalytic cracking (TCC) process, which can selectively produce light olefins (mostly, ethylene and propylene for the petrochemical industry) and transportation fuels (gasoline and diesel fuel), combines the effects of thermal and catalytic cracking reactions. The TCC catalysts consist mainly of mixed metal oxides supported on a high-surface area – thermally stabilized alumina. The best TCC catalyst formulation includes a co-catalyst, which provides the main catalyst component with active hydrogen species formed from hydrogen and other hydrocarbons, particularly methane, produced mainly by thermal cracking. The interparticular interactions of these hydrogen spilt-over species can occur because these species can be easily transferred from one particle to the other through the newly formed pore connections

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Chauvel and G. Lefebre, Petrochemical Processes, Vol.1, p 2 and ch. 2; Vol. 2, (Technip, Paris, 1989)

  2. R.A. Meyers (2004) Handbook of Petroleum Refining Processes EditionNumber3 McGraw-Hill New York

    Google Scholar 

  3. A.H. Tullo, Chem. Eng. News (2005) 25

  4. R. Le Van Mao, U.S. Pat.4732881 (1988)

  5. R. Le Van Mao (1999) Micropor. Mesopor. Mater. 28 9 Occurrence Handle1:CAS:528:DyaK1M**tlemsrk%3D Occurrence Handle10.1016/S1387-1811(98)00277-7

    Article  CAS  Google Scholar 

  6. R. Le Van Mao S. Melancon C. Gauthier-Campbell P. Kletnieks (2001) Catal. Lett. 73 IssueID2/4 181 Occurrence Handle1:CAS:528:DC%2BD3MXks1GqtL0%3D Occurrence Handle10.1023/A:1016685523095

    Article  CAS  Google Scholar 

  7. S. Melancon R. Le Mao P. Kletnieks D. Ohayon S. Intem M.A. Saberi D. McCann (2002) Catal. Lett. 80 IssueID3/4 103 Occurrence Handle1:CAS:528:DC%2BD38Xksl2htbw%3D Occurrence Handle10.1023/A:1015448106870

    Article  CAS  Google Scholar 

  8. N. Al-Yassir R. Le Mao F. Heng (2005) Catal. Lett. 100 IssueID1/2 1 Occurrence Handle1:CAS:528:DC%2BD2M**sVSitLs%3D Occurrence Handle10.1007/s10562-004-3078-9

    Article  CAS  Google Scholar 

  9. R. Le Mao N. Al-Yassir D.T.T. Nguyen (2005) Micropor. Mesopor. Mater. 85 176 Occurrence Handle10.1016/j.micromeso.2005.05.050

    Article  Google Scholar 

  10. E. Elaloui, R. Begag, B. Pommier and G.M. Pajonk, in: Studies in Surface Science and Catalysis, vol. 143, eds. E. Gaigneaux, D.E. De Vos, P. Grange, P.A. Jacobs, J.A. Martens, P. Ruiz and G. Poncelet (Elsevier, Amsterdam, 2002), p. 331

  11. R. Le Van Mao, Concordia University, Montreal (Canada), unpublished data (2005)

  12. S. **ao R. Le Mao G. Denes (1995) J. Mater. Chem. 5 1251 Occurrence Handle1:CAS:528:DyaK2MXnvVWisLs%3D Occurrence Handle10.1039/jm9950501251

    Article  CAS  Google Scholar 

  13. N. Zanier-Szydlowski, in: Analyse Physico-Chimique des Catalyseurs Industriels, ed. J. Lynch (Technip, Paris, 2001), p. 274

  14. S.J. Yanik, A.P. Humphries, M.F. Brady, D.K. Abner and M.C. Friedrich, in: Hydrocarbon Chem. FCC Naphtha Form. Proc. Symp. Div. Pet. Chem. (Am. Chem. Soc., USA, 1990) p. 73

  15. U.A. El-Nafaty R. Mann (1999) Chem. Eng. Sci. 54 3475 Occurrence Handle1:CAS:528:DyaK1MXksVSlurc%3D Occurrence Handle10.1016/S0009-2509(98)00388-1

    Article  CAS  Google Scholar 

  16. J.M. Parera, E.M. Traffano, J.C. Musso and C.L. Pieck, in: Spillover of Adsorbed Species, eds. G.M. Pajonk, S.J. Teichner and J.E. Germain (Elservier, Amsterdam, 1983), p. 101

  17. C. Henriques P. Dufresne C. Marcilly F. Ramoa Ribeiro (1986) Appl. Catal. 21 169 Occurrence Handle1:CAS:528:DyaL28Xhtlamtb8%3D Occurrence Handle10.1016/S0166-9834(00)81337-8

    Article  CAS  Google Scholar 

  18. G.M. Pajonk, in: Second Conference on Spillover, ed. K.H. Steinberg (Leipzig, 1989), p. 1

  19. W.C. Conner SuffixJr. J.L. Falconner (1995) Chem. Rev. 95 759 Occurrence Handle1:CAS:528:DyaK2MXltlyktbo%3D Occurrence Handle10.1021/cr00035a014

    Article  CAS  Google Scholar 

  20. B. Delmon, New aspects of spillover effect, in: Catalysis, eds. T. Inui, K. Fugimoto, T. Uchijima and M. Masai (Elsevier, Amsterdam, 1993), p. 1

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. Le Van Mao.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Van Mao, R.L., Vu, NT., Al-Yassir, N. et al. The Thermocatalytic Cracking Process for the Production of Light Olefins and Transportation Fuels from Gas Oils. Top Catal 37, 107–112 (2006). https://doi.org/10.1007/s11244-006-0011-z

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11244-006-0011-z

Keywords

Navigation