SpringerLink
Log in

Two oxamido-bridged binuclear Cu–M complexes (M = CoII, CuII): synthesis, crystal structures and magnetic studies

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Two novel oxamido-bridged macrocyclic complexes, [LCu(CH3OH)Co(phen)2](ClO4)2·CH3OH (1) and [LCu(CH3OH) Cu(phen)2](ClO4)2·CH3OH (2) (where H2L = 2,3-dioxo-5,6:13,14-dibenzo-7,10,12-trimethyl-1,4,8,11-tetraazacyclo-tetradeca-7,12-diene, phen = 1,10-phenanthroline), have been prepared by stepwise synthesis and characterized. In both complexes, each Cu(II) atom from the precursor ligand CuL is connected to a Co(II) (or Cu(II)) atom via the exo–cis oxygen atoms, resulting in a binuclear subunit. Magnetic susceptibility measurements in the 2–300 K temperature range have been taken for the two complexes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
EUR 32.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or Ebook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (Germany)

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Batten SR, Robson R (1998) Angew Chem Int Ed 37:1460–1494

    Article  Google Scholar 

  2. Moulton B, Zaworotko MJ (2001) Chem Rev 101:1629–1658

    Article  CAS  Google Scholar 

  3. Kim K (2002) Chem Soc Rev 31:96–107

    Article  CAS  Google Scholar 

  4. Kitagawa S, Kondo M (1998) Bull Chem Soc Jpn 71:1739–1753

    Article  CAS  Google Scholar 

  5. Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Kim J (2003) Nature 423:705–714

    Article  CAS  Google Scholar 

  6. James SL (2003) Chem Soc Rev 32:276–288

    Article  CAS  Google Scholar 

  7. Kahn O (1993) Molecular magnetism. VCH, New York

    Google Scholar 

  8. Miyasaka H, Matsumoto N, Okawa H, Re N, Gallo E, Floriani C (1996) J Am Chem Soc 118:981–994

    Article  CAS  Google Scholar 

  9. Coronado E, Galán-Mascarós JR, Gómez-García CJ, Laukhin V (2000) Nature 408:447–449

    Article  CAS  Google Scholar 

  10. Kato R, Kobayashi H, Kobayashi A (1989) J Am Chem Soc 111:5224–5232

    Article  CAS  Google Scholar 

  11. Lawrence DS, Jiang T, Levett M (1995) Chem Rev 95:2229–2260

    Article  CAS  Google Scholar 

  12. Blake AJ, Champness NR, Hubberste P, Li W-S, Withersby MA, Schröder M (1999) Coord Chem Rev 183:117–138

    Article  CAS  Google Scholar 

  13. Ruiz R, Faus J, Lloret F, Julve M, Journaux Y (1999) Coord Chem Rev 193:1069–1117

    Article  Google Scholar 

  14. Konar S, Manna SC, Zangrando E, Chaudhuri NR (2004) Inorg Chim Acta 357:1593–1597

    Article  CAS  Google Scholar 

  15. Ribas J, Diaz C, Costa R, Journaux Y, Mathoniere C, Kahn O, Gleizes A (1990) Inorg Chem 29:2042–2047

    Article  CAS  Google Scholar 

  16. Livermore JC, Willett RD, Gaura RM, Landee CP (1982) Inorg Chem 21:1403–1405

    Article  CAS  Google Scholar 

  17. Billson TS, Crane JD, Fox OD, Heath SL (2000) Inorg Chem Commun 3:718–720

    Article  CAS  Google Scholar 

  18. Zhang L, Wang S-B, Yang G-M, Tang J-K, Liao D-Z et al (2003) Inorg Chem 42:1462–1466

    Article  CAS  Google Scholar 

  19. Okawa H, Mitsumi M, Ohba M, Kodera M, Matsumoto N (1994) Bull Chem Soc Jpn 67:2139–2144

    Article  CAS  Google Scholar 

  20. Pei Y, Joumaux Y, Kahn O (1989) Inorg Chem 28:100–103

    Article  CAS  Google Scholar 

  21. Christodoulou D, Kanatzidis MG, Coucouvanis D (1990) Inorg Chem 29:191–201

    Article  CAS  Google Scholar 

  22. Burkholder E, Golub V, O’Connor CJ, Zubieta J (2003) Chem Commun 2128–2129

  23. Khan MI, Yohannes E, Nome RC, Ayesh S et al (2004) Chem Mater 16:5273–5279

    Article  CAS  Google Scholar 

  24. Reinoso S, Vitoria P, Gutiérrez-Zorrilla JM, Lezama L, Felices LS, Beitia JI (2005) Inorg Chem 44:9731–9742

    Article  CAS  Google Scholar 

  25. Miller JS, Epstein AJ, Reiff WM (1988) Chem Rev 88:201–220

    Article  CAS  Google Scholar 

  26. Black D, St C, Vanderzalm CHB, Hartshorn AJ (1976) Inorg Nucl Chem Lett 12:657–659

    Article  CAS  Google Scholar 

  27. Rigaku MSC (2005) CrystalClear, Rigaku/MSC Inc. The Woodlands, Texas

    Google Scholar 

  28. Sheldrick GM (1990) SHELXS-97, Program for the solution of crystal structures. University of Götingen, Germany

    Google Scholar 

  29. Sheldrick GM (1997) SHELXL-97, program for the refinement of crystal structures. University of Götingen, Germany

    Google Scholar 

  30. Loret F, Journaux Y, Julve M (1990) Inorg Chem 29:3967–3972

    Article  Google Scholar 

  31. Sinn E (1970) Coord Chem Rev 5:313–347

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Nos. 59973008 and 20571046) and Natural Science Foundation of Tian** (No. 013603711)

Author information

Authors and Affiliations

  1. Department of Chemistry, Nankai University, 300071, Tian**, People’s Republic of China

    Fan Yang, Yan-Hong Zhang, Qing-Lun Wang & Guang-Ming Yang

Authors
  1. Fan Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yan-Hong Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Qing-Lun Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Guang-Ming Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guang-Ming Yang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yang, F., Zhang, YH., Wang, QL. et al. Two oxamido-bridged binuclear Cu–M complexes (M = CoII, CuII): synthesis, crystal structures and magnetic studies. Transition Met Chem 34, 809–813 (2009). https://doi.org/10.1007/s11243-009-9267-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-009-9267-z

Keywords

Search

Navigation