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Chemoselective Photocatalytic Reduction of Furfural to Furfuryl Alcohol Under the Influence of Visible Light with the Participation of Nanocrystalline Carbon Nitride and Palladium Co-Catalysts

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Theoretical and Experimental Chemistry Aims and scope

It is established that crystalline graphite-like carbon nitride (CGCN) exhibits high photocatalytic activity in the process of chemoselective reduction of furfural to furfuryl alcohol in the presence of co-catalysts under the action of visible light by electron-donating substrates, such as methanol/water and ethanol/water, in an acidic medium. When palladium chloride additives are introduced into the reaction mixture, the rate of the process is higher than with the participation of the Pd/SiO2 co-catalyst. This phenomenon may be due to the in situ formation of the CGCN/Pd0 composite photocatalyst in the presence of PdCl2, where the photogenerated charges are better separated than in the CGCN-Pd/SiO2 system. The effective quantum yield of furfural reduction is 56% at λirr = 405 nm) under optimal conditions.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, NAS of Ukraine, Kyiv, Ukraine

    G. V. Korzhak, T. R. Stara, O. S. Kutsenko & S. Ya. Kuchmiy

  2. V. E. Lashkaryov Institute of Semiconductor Physics, NAS of Ukraine, Kyiv, Ukraine

    T. R. Stara

  3. Chuiko Institute of Surface Chemistry, NAS of Ukraine, Kyiv, Ukraine

    P. O. Kuzema

  4. L. M. Litvinenko Institute of Physical-Organic and Coal Chemistry, NAS of Ukraine, Kyiv, Ukraine

    V. M. Anishchenko

Authors
  1. G. V. Korzhak
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  2. T. R. Stara
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  3. O. S. Kutsenko
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  4. P. O. Kuzema
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  5. V. M. Anishchenko
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  6. S. Ya. Kuchmiy
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Correspondence to S. Ya. Kuchmiy.

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Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 59, No. 4, pp. 234-239, July-August, 2023.

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Korzhak, G.V., Stara, T.R., Kutsenko, O.S. et al. Chemoselective Photocatalytic Reduction of Furfural to Furfuryl Alcohol Under the Influence of Visible Light with the Participation of Nanocrystalline Carbon Nitride and Palladium Co-Catalysts. Theor Exp Chem 59, 268–275 (2023). https://doi.org/10.1007/s11237-024-09785-w

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  • DOI: https://doi.org/10.1007/s11237-024-09785-w

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